(Meth) acrylic polymer and vinyl chloride resin composition containing the same
View Patent ↗The present invention provides a (meth)acrylic polymer containing 15 to 65 parts by weight of a polymer (A) having a specific viscosity of 0.90 to 2.00 and containing 70 to 100 weight percent of methyl methacrylate, 0 to 30 weight percent of a (meth)acrylic ester other than methyl methacrylate, and 0 to 10 weight percent of another monomer copolymerizable with these; 20 to 75 parts by weight of a polymer (B) having a specific viscosity of 0.40 or more and less than 0.90 and containing 70 to 100 weight percent of methyl methacrylate, 0 to 30 weight percent of a (meth)acrylic ester other than methyl methacrylate, and 0 to 10 weight percent of another monomer copolymerizable with these; and 1 to 30 parts by weight of a polymer (C) having a specific viscosity of 0.80 to 2.00 and containing 0 to 60 weight percent of methyl methacrylate, 40 to 100 weight percent of a (meth)acrylic ester other than methyl methacrylate, and 0 to 20 weight percent of another monomer copolymerizable with these (the total of the polymer (A), the polymer (B), and the polymer (C) is 100 parts by weight).
1. A (meth)acrylic polymer comprising
15 to 65 parts by weight of a polymer (A) having a specific viscosity of 0.90 to 2.00 and containing 70 to 100 weight percent of methyl methacrylate, 0 to 30 weight percent of a (meth)acrylic ester other than methyl methacrylate, and 0 to 10 weight percent of another monomer copolymerizable with these;
20 to 75 parts by weight of a polymer (B) having a specific viscosity of 0.40 or more and less than 0.90 and containing 70 to 100 weight percent of methyl methacrylate, 0 to 30 weight percent of a (meth)acrylic ester other than methyl methacrylate, and 0 to 10 weight percent of another monomer copolymerizable with these; and
1 to 30 parts by weight of a polymer (C) having a specific viscosity of 0.80 to 2.00 and containing 1 to 40 weight percent of methyl methacrylate, 40 to 100 weight percent of a (meth)acrylic ester other than methyl methacrylate, and 0 to 20 weight percent of another monomer copolymerizable with these (the total of the polymer (A), the polymer (B), and the polymer (C) is 100 parts by weight),
wherein when the specific viscosity of the polymer (A) is represented as a and the specific viscosity of the polymer (B) is represented as b, a/b is 1.2 to 3.2, and
the another monomer does not comprise an aromatic vinyl compound.
2. The (meth)acrylic polymer according to claim 1 , wherein the (meth)acrylic polymer is a multistage polymer comprising the polymer (A), the polymer (B), and the polymer (C).
3. The (meth)acrylic polymer according to claim 2 , wherein the multistage polymer is prepared by multistage polymerization in the order of the polymer (A), the polymer (B), and the polymer (C).
4. The (meth)acrylic polymer according to claim 2 , wherein the multistage polymer is prepared by multistage polymerization in the order of the polymer (B), the polymer (A), and the polymer (C).
5. A vinyl chloride-based resin composition comprising 100 parts by weight of a vinyl chloride-based resin and 0.1 to 20 parts by weight of the (meth)acrylic polymer according to claim 1 .
6. A vinyl chloride-based resin composition comprising 100 parts by weight of a vinyl chloride-based resin and 0.1 to 20 parts by weight of the (meth)acrylic polymer according to claim 2 .
7. A vinyl chloride-based resin composition comprising 100 parts by weight of a vinyl chloride-based resin and 0.1 to 20 parts by weight of the (meth)acrylic polymer according to claim 3 .
8. A vinyl chloride-based resin composition comprising 100 parts by weight of a vinyl chloride-based resin and 0.1 to 20 parts by weight of the (meth)acrylic polymer according to claim 4 .