Organic polyurethane shape memory material and a preparation method thereof
View Patent ↗An organic polyurethane shape memory material includes a C10 chain or C18 chain and consists of hard segment and soft segment. The material is produced by reacting the single-chain type dendrimer with diethylenetriamine to produce dendrimer. Then dendrimer reacts with N-(3-aminopropyl)diethanolamine to produce dendritic diols. Next, polymer HO(C 6 H 10 O 2 )xC 2 H 4 OC 2 H 4 (C 6 H 10 O 2 ) y OH, where x+y=25˜26, reacts with methylenedi-p-phenyl diisocyanate, and at least one type of dendritic diols is added to produce the organic polyurethane shape memory material.
1. An organic polyurethane shape memory material comprising:
wherein R1 is (C 13 H 10 );
R2 is (C 5 H 10 COO) x C 2 H 4 OC 2 H 4 (OOCC 5 H 10 ) y , where x+y=25˜26; and
R3 is selected from the group consisting of: