Golf balls including mechanically hybridized layers and methods of making same
View Patent ↗Golf balls having at least one layer that is formed from a mechanically hybridizing two or more materials. In particular, the mechanically hybridized layers of the invention improve performance and increase durability of the finished golf ball, as well increase adhesion between layers.
1. A golf ball comprising at least one mechanically hybridized component comprising:
a first layer formed of a first composition comprising at least one polyolefin polymer and a plurality of microballoons comprising a thermoplastic shell, wherein the first layer comprises a network of interconnecting pores; and
a second layer disposed thereon comprising a second composition, wherein the second composition fills the interconnecting pores to form the mechanically hybridized component.
2. The golf ball of claim 1 , wherein the thermoplastic shell comprises (meth)acrylonitrile, (meth)acrylates, styrenic monomers, vinyl halides, vinylidene halides, vinyl acetate, butadiene, vinylpyridine, chloroprene, and mixtures thereof.
3. The golf ball of claim 1 , wherein the microballoons have a diameter of about 30 μm to about 200 μm.
4. The golf ball of claim 1 , wherein a first percentage of microballoons have a diameter of about 10 μm to about 200 μm and a second percentage of microballoons have a diameter of about 500 μm to about 1000 μm.
5. The golf ball of claim 1 , wherein each microballoon comprises a blowing agent within the thermoplastic shell, and wherein the thermoplastic shell is expandable by about four to about five times the initial size.
6. The golf ball of claim 1 , wherein the interconnecting pores have a volume average diameter of about 0.02 microns to about 50 microns.
7. The golf ball of claim 1 , wherein the microballoons have diameters ranging from about 1 μm to about 1000 μm.
8. The golf ball of claim 1 , wherein the interconnecting pores comprise about 35 percent or more of the volume of the first layer.
9. The golf ball of claim 8 , wherein the interconnecting pores comprise about 60 percent or more of the volume of the first layer.
10. The golf ball of claim 1 , wherein at least about 20 percent of the interconnecting pores have a diameter of about 0.1 μm to about 300 μm.
11. A golf ball comprising:
a core; and
a mechanically hybridized component disposed about the core, wherein the mechanically hybridized component comprises:
a first layer comprising interconnecting pores and formed from a composition comprising a thermoplastic material and a plurality of porosity-generating agents selected from the group consisting of microballoons, nanotubes, macrospheres, or a combination thereof; and
a second layer formed from a castable reactive liquid material, wherein the castable reactive liquid material fills the interconnecting pores in the first layer.
12. The golf ball of claim 11 , wherein the thermoplastic material comprises a highly neutralized polymer having at least 80 percent of its acid groups neutralized.
13. The golf ball of claim 11 , wherein the porosity-generating agents are microballoons each having a diameter ranging from about 1 μm to about 1000 μm.
14. The golf ball of claim 11 , wherein the interconnecting pores comprise about 35 percent to about 95 percent of the volume of the first layer.
15. The golf ball of claim 11 , wherein at least about 50 percent of the interconnecting pores have a diameter of about 0.3 μm to about 200 μm.
16. A golf ball comprising a core and a cover, wherein the cover is formed of a mechanically hybridized component comprising:
a first layer comprising a first composition comprising a polymer component and a plurality of porosity-generating agents each comprising a blowing agent, wherein the porosity-generating agents comprise microballoons having a diameter ranging from about 1 μm to about 1000 μm, and wherein the first layer comprises a first network of interconnecting pores; and
a second layer comprising a second composition, wherein the second composition fills the first network of interconnecting pores to form the mechanically hybridized component.
17. The golf ball of claim 16 , wherein the second layer further comprises a plurality of porosity-generating agents selected from the group consisting of microballoons, nanotubes, or a mixture thereof, and wherein the second layer further comprises a second network of interconnected pores.
18. The golf ball of claim 17 , wherein the mechanically hybridized component further comprises a third layer disposed about the second layer, wherein the third layer is formed from a third composition, and wherein the third composition fills the second network of interconnected pores to form the mechanically hybridized component.
19. The golf ball of claim 16 , wherein at least about 20 percent of the interconnecting pores have a diameter of about 0.3 μm to about 200 μm.
20. The golf ball of claim 16 , wherein the interconnecting pores comprise about 60 percent or more of the volume of the first layer.