Direct liquid-phase collection and processing of fullerenic materials
View Patent ↗An in-situ method and system of collecting, in a liquid, non-agglomerated fullerenic material from a gaseous suspension is provided. The method and system collects non-agglomerated fullerenic material by contacting a gaseous suspension comprising fullerenic material with a suspension liquid, so as to capture the fullerenic material in the suspension liquid; and collecting the liquid suspension as a suspension liquid containing the fullerenic material. This method and system may be particularly useful for collecting fullerenes or nanotubes and maintaining them in solution in non-agglomerated states.
1. A method of collecting non-agglomerated fullerenic material comprising:
generating fullerenic material in a reactor as gaseous dispersion of fullerenic material in a non-agglomerated state;
introducing the fullerenic material in a non-agglomerated state into an entrainment chamber;
contacting the fullerenic material with a fluid in the entrainment chamber, wherein the fullerenic material is captured by the fluid and is substantially non-agglomerated within the fluid; and
collecting the fluid containing the non-agglomerated, captured fullerenic material, wherein the fluid is in a liquid form during said collecting and the fullerenic material is not collected as a powder.
2. The method of claim 1 , wherein the fullerenic material prior to said contacting is at least one member selected from the group consisting of a condensable gas, a condensed solid, and solid particulates.
3. The method of claim 1 , wherein the fullerenic material comprises fullerenes.
4. The method of claim 1 , wherein the fullerenic material comprises nanotubes.
5. The method of claim 4 , wherein the nanotubes are produced in a flame combustion process in the presence of a catalyst.
6. The method of claim 1 , wherein:
said gaseous suspension comprising fullerenic materials is generated by combusting an unsaturated hydrocarbon fuel and oxygen in a burner chamber at sub-atmospheric pressures.
7. The method of claim 1 , wherein the gaseous suspension of fullerenic material further comprises a diluent gas.
8. The method of claim 7 , wherein the diluent gas is at least one member selected from the group consisting of an inert gas, a reactive gas, gas vapor, nitrogen, a noble gas, carbon dioxide, steam, flue gases, and mixtures thereof.
9. The method of claim 1 , wherein the fluid comprises an organic solvent or an aqueous solvent.
10. The method of claim 1 , wherein the fluid comprises an additive.
11. The method of claim 10 , wherein the additive is at least one member selected from the group consisting of oxidation agents, acids, bases, surfactants, radical scavengers, chemical quenching agents, and chemical stabilization agents.
12. The method of claim 9 , wherein the organic solvent is at least one member selected from the group consisting of substituted aromatic molecules, alkyl substituted aromatics, halogenated substituted molecules, halogenated alkanes, partially hydrogenated aromatics, alkylamines, cyclic ethers, ortho-dichlorobenzene, xylene, benzene, dimethylformamide, ethylene chloride, chloroform, 1,2,4 trimethylbenzene, 1,2,3,4 tetramethylbenzene, tetrahydrofuran, 1,2 dibromobenzene, 1,1 ,2,2, tetrachloroethane, 1,2,3,4 tetrahydronapthalene, octadecylamine, acetone, and mixtures thereof.
13. The method of claim 9 , wherein the aqueous solvent comprises a surfactant, said surfactant is at least one member selected from the group consisting of sodium cholate, NaDDBS (C 12 H 25 C 6 H 4 SO 3 Na), sodium octylbenzene sulfonate (NaOBS; C 8 H 11 C 6 H 4 SO 3 Na), sodium butylbenzene sulfonate (NaBBS; C 4 H 9 C 6 H 4 SO 3 Na), sodium benzoate (C 6 H 5 CO 2 Na), sodium dodecyl sulfate (SDS; CH 3 (CH 2 ) 11 —OSO 3 Na) (TX100; C 8 H 17 C 6 H 4 (OCH 2 CH 2 )n-OH; n=10), dodecyltrimethylammonium bromide (DTAB; CH3(CH 2 ) 11 N(CH 3 ) 3 Br), dextrin, and poly(styrene)-poly-(ethylene oxide) (PS-PEO) diblock copolymer.
14. The method of claim 1 , further comprising liquid-phase processing of the fullerenic material.
15. The method of claim 14 , wherein said liquid-phase processing is at least one member selected from the group consisting of:
extracting a class of fullerenic material from the suspension, acid extraction of catalyst particles, oxidation treatment of catalyst particles, oxidative opening of fullerenic materials; shortening nanotubes, exfoliating and dispersing nanotube bundles, exfoliating and dispersing nanotube ropes, exfoliating and dispersing nanotube rafts, dispersing nanotubes, and derivatizing the fullerenic material.
16. The method of claim 1 , wherein said contacting the gaseous suspension with the fluid comprises:
creating a stream of the fluid, said stream comprising a gas, vapor, or liquid droplets of the fluid;
contacting the stream with the gaseous suspension of fullerenic material in an entrainment zone so as to entrain the fullerenic material in the stream; and
wherein said collecting the fluid containing the non-agglomerated, captured fullerenic material in a liquid form comprises condensing said fluid to a bulk liquid of the fluid.
17. The method of claim 16 , wherein the gaseous suspension is contacted with the fluid in an entrainment zone having a controlled temperature.
18. The method of claim 17 , wherein the controlled temperature prevents the fluid from condensing in the entrainment zone.
19. The method of claim 16 , wherein contacting the stream with the gaseous suspension of fullerenic material further comprises injecting the stream to intersect with the gaseous suspension of fullerenic material.
20. The method of claim 16 , further comprising directing a portion of the bulk liquid for use in providing a subsequent stream of the fluid.
21. The method of claim 1 , wherein contacting the gaseous suspension with the fluid comprises bubbling the gaseous suspension through the fluid that is in a bulk liquid form.
22. The method of claim 1 , wherein the fullerenic material is generated using a combustion reactor.