Coated article with low-E coating having absorbing layer designed for desirable bluish color at off-axis viewing angles
View Patent ↗An absorbing layer of a low-E coating is designed to cause the coating to have a more bluish color at normal and/or certain off-axis viewing angles. In certain example embodiments, the metallic or substantially metallic absorbing layer (e.g., NiCr) is located in the middle section of the layer stack and has been found to unexpectedly provide desirable bluish glass side reflective color for the coated article at certain off-axis viewing angles (e.g., at a 45 degree off-axis viewing angle). In certain example embodiments, the absorbing layer is provided between first and second nitride inclusive or based layers in order to reduce or prevent oxidation thereof during heat treatment thereby permitting predictable coloration to be achieved following the heat treatment. Coated articles according to certain example embodiments of this invention may be used in the context of insulating glass (IG) window units, vehicle windows, other types of windows, or in any other suitable application.
1. A coated article including a coating supported by a glass substrate, the coating comprising:
at least first and second infrared (IR) reflecting layers, wherein said IR reflecting layers are spaced apart from one another, and wherein the first IR reflecting layer is located closer to the glass substrate than is the second IR reflecting layer;
a substantially metallic absorbing layer located between the first and second IR reflecting layers, wherein the absorbing layer is sandwiched between and contacting first and second dielectric layers which are also located between the first and second IR reflecting layers, and wherein the absorbing layer is from about 80 to 130 Å thick and is located between the first and second IR reflecting layers so that no substantially metallic absorbing layer is located between the glass substrate and the first IR reflecting layer or above the second IR reflecting layer.
2. The coated article of claim 1 , wherein the substantially metallic absorbing layer is from about 3-25 angstroms (Å) thick.
3. The coated article of claim 1 , wherein the coated article is heat treated.
4. The coated article of claim 3 , wherein the coated article has a ΔE* (glass side reflective) due to heat treatment of no more than 2.5.
5. The coated article of claim 1 , wherein the substantially metallic absorbing layer is located in the coating so that the coated article has a glass side reflective a* color value of from about −2 to +4 at a 45 degree viewing angle from normal, and a glass side reflective b* color value of from about −10 to −4 at the 45 degree viewing angle from normal.
6. The coated article of claim 1 , wherein the first and second IR reflecting layers comprise silver.
7. The coated article of claim 1 , wherein the first and second dielectric layers comprise silicon nitride.
8. The coated article of claim 1 , wherein the substantially metallic absorbing layer is located in the coating so that the coated article has a glass side reflective a* color value of from about +0.5 to +1.5 at the 45 degree viewing angle from normal, and a glass side reflective b* color value of from about −9 to −5 at the 45 degree viewing angle from normal.
9. The coated article of claim 1 , wherein the substantially metallic absorbing layer is located in the coating so that the coated article has a glass side reflective a* color value of about +1 at the 45 degree viewing angle from normal, and/or a glass side reflective b* color value of about −7 at the 45 degree viewing angle from normal.
10. The coated article of claim 1 , wherein the substantially metallic absorbing layer is located in the coating so that the coated article has a glass side reflective b* color value of from about −8 to −6 at the 45 degree viewing angle from normal.
11. The coated article of claim 1 , wherein said second dielectric layer comprises silicon nitride and is located over the absorbing layer, and wherein a layer comprising zinc oxide is located on and contacting the second dielectric layer comprising silicon nitride, and wherein the layer comprising zinc oxide is located under and contacting the second IR reflecting layer, and wherein the first and second IR reflecting layers comprise silver.
12. The coated article of claim 1 , wherein at least a layer comprising silicon nitride and a layer comprising zinc oxide are located between the first IR reflecting layer and the glass substrate.
13. The coated article of claim 1 , wherein the coated article comprises an IG window unit and the glass side reflective a* and b* color values are measured in the context of the IG window unit.
14. The coated article of claim 1 , wherein the glass side reflective a* and b* color values are measured monolithically following heat treatment.
15. The coated article of claim 1 , wherein the substantially metallic absorbing layer is from about 90-125 angstroms (Å) thick.
16. The coated article of claim 1 , wherein said coated article has a visible transmission of from about 52-58% or 63-70%, measured monolithically.
17. The coated article of claim 1 , wherein said coated article is an IG window unit having a visible transmission of from about 40-65% and has an SHGC of no greater than 0.30.