Open-cell polyurethane foam and process for its manufacture
View Patent ↗There is provided a predominantly open-cell polyurethane foam obtained from a predominantly open-cell polyurethane foam-forming reaction medium which comprises: a) at least one polyol; b) at least one polyisocyanate; c) at least one catalyst; d) water; e) a predominantly open-cell polyurethane foam-forming amount of at least one surfactant which is a balanced, substantially linear polyether-polysiloxane ABA′ block copolymer; and, f) optionally, at least one additional component selected from the group consisting of other polymer and/or copolymer, chain extender, crosslinker, non-aqueous blowing agent, filler, reinforcement, pigment, tint, dye, colorant, flame retardant, antioxidant, antiozonant, UV stabilizer, anti-static agent, biocide and biostat.
1. A predominantly open-cell rigid, stable polyurethane foam obtained from a predominantly open-cell rigid polyurethane foam-forming reaction medium which comprises:
a) at least one polyol;
b) at least one polyisocyanate;
c) at least one catalyst;
d) water;
e) a predominantly open-cell rigid, stable polyurethane foam-forming amount of at least one surfactant which is a balanced, substantially linear polyether-polysiloxane ABA′ block copolymer represented by the general formula:
wherein:
each R 6 independently is alkyl or aryl of up to 18 carbon atoms; and,
each R 7 independently is a non-hydrolyzable, hydroxyl-terminated polyether moiety of either random or blocked structure —CHR 1 CHR 2 CR 3 R 4 R 5 p O C 2 H 4 O) x (C y R 8 2y O) z H in which R 1 , R 2 , R 3 and R 4 each independently is hydrogen or a monovalent hydrocarbon group of up to 8 carbon atoms which is free of aliphatic carbon-to-carbon multiple bonds, R 5 is a divalent hydrocarbon group of up to 12 carbon atoms which is free of aliphatic carbon-to-carbon multiple bonds and p has a value of 0 or 1, each R 8 independently is hydrogen, alkyl of up to 18 carbon atoms, phenyl or alkyl-substituted phenyl in which the alkyl substituent(s) independently contain up to 4 carbon atoms, x is from 5 to 50, y is from 2 to 6, z is from 0 to 25, and x+z is from 5 to 50, and,
m is from 10 to 40; and,
f) optionally, at least one additional component selected from the group consisting of other polymer and/or copolymer, chain extender, crosslinker, non-aqueous blowing agent, filler, reinforcement, pigment, tint, dye, colorant, flame retardant, antioxidant, antiozonant, UV stabilizer, anti-static agent, biocide and biostat.
2. The predominantly open-cell rigid, stable polyurethane foam of claim 1 wherein:
each R 6 independently is alkyl of up to 3 carbon atoms; and,
independently in each polyether moiety R 7 ,
R 1 is hydrogen;
R 2 is hydrogen or alkyl of up to 3 carbon atoms;
R 3 is hydrogen or alkyl of up to 3 carbon atoms;
R 4 is hydrogen or alkyl of up to 3 carbon atoms;
each R 8 independently is hydrogen or alkyl of up to 3 carbon atoms;
p is 0;
x is from 6 to 40;
y is from 2 to 4;
z is from 0 to 20;
x+z is from 6 to 40;
x/(x+z) is at least 0.57; and,
m is from 10 to 30.
3. The predominantly open-cell rigid polyurethane foam of claim 1 wherein:
each R 6 is methyl; and,
independently in each polyether moiety R 7 ,
R 1 is hydrogen;
R 2 is hydrogen or methyl;
R 3 is hydrogen;
R 4 is hydrogen;
each R 8 independently is hydrogen or methyl;
p is 0;
x is from 6 to 30;
y is 2;
z is from 0 to 15;
x+z is from 6 to 35;
x/(x+z) is greater than 0.7; and,
m is from 10 to 30.
4. The predominantly open-cell rigid, stable polyurethane foam of claim 1 wherein balanced, substantially linear ABA′ block copolymer surfactant (e) includes a spacer group between the A and B blocks and/or the B and A′ blocks.
5. The predominantly open-cell rigid, stable polyurethane foam of claim 1 wherein in balanced, substantially linear ABA′ block copolymer surfactant (e), polyether blocks A and A′ are derived entirely from ethylene oxide.
6. The predominantly open-cell rigid, stable polyurethane foam of claim 1 wherein in balanced, substantially linear ABA′ block copolymer surfactant (e), polyether blocks A and A′ are derived for at least half the weight thereof from ethylene oxide, the remaining portions of the alkyleneoxy chains constituting polyether blocks A and A′ being independently derived from one or more other alkylene oxides and/or strained oxygen-containing rings.
7. The predominantly open-cell rigid, stable polyurethane foam of claim 6 wherein blocks A and A′ are derived for at least 70 percent of the weight thereof from ethylene oxide.
8. The predominantly open-cell rigid, stable polyurethane foam of claim 6 wherein the remaining portions of the alkyleneoxy chains constituting polyether blocks A and A′ are derived from propylene oxide.
9. The predominantly open-cell rigid, stable polyurethane foam of claim 7 wherein the remaining portions of the alkyleneoxy chains constituting polyether blocks A and A′ are derived from propylene oxide.
10. A process for manufacturing a predominantly open-cell rigid polyurethane foam from a predominantly rigid, stable open-cell polyurethane foam-forming reaction medium containing at least one polyol (a), at least one polyisocyanate (b), at least one catalyst (c), water (d), at least one polyether-polysiloxane surfactant (e) represented by the general formula:
wherein:
each R 6 independently is alkyl or aryl of up to 18 carbon atoms; and,
each R 7 independently is a non-hydrolyzable, hydroxyl-terminated polyether moiety of either random or blocked structure —CHR 1 CHR 2 CR 3 R 4 R 5 p O C 2 H 4 O) x (C y R 8 2y O) z H in which R 1 , R 2 , R 3 , and R 4 each independently is hydrogen or a monovalent hydrocarbon group of up to 8 carbon atoms which is free of aliphatic carbon-to-carbon multiple bonds, R 5 is a divalent hydrocarbon group of up to 12 carbon atoms which is free of aliphatic carbon-to-carbon multiple bonds and p has a value of 0 or 1, each R 8 independently is hydrogen, alkyl of up to 18 carbon atoms, phenyl or alkyl-substituted phenyl in which the alkyl substituent(s) independently contain up to 4 carbon atoms, x is from 5 to 50, y is from 2 to 6, z is from 0 to 25, and x+z is from 5 to 50; and, m is from 10 to 40 and, optionally, at least one additional component (f) selected from the group consisting of other polymer and/or copolymer, chain extender, crosslinker, non-aqueous blowing agent, filler, reinforcement, pigment, tint, dye, colorant, flame retardant, antioxidant, antiozonant, UV stabilizer, anti-static agent, biocide and biostat.
11. The process of claim 10 wherein:
each R 6 independently is alkyl of up to 3 carbon atoms; and,
independently in each polyether moiety R 7 ,
R 1 is hydrogen;
R 2 is hydrogen or alkyl of up to 3 carbon atoms;
R 3 is hydrogen or alkyl of up to 3 carbon atoms;
R 4 is hydrogen or alkyl of up to 3 carbon atoms;
each R 8 independently is hydrogen or alkyl of up to 3 carbon atoms;
p is 0;
x is from 6 to 40;
y is from 2 to 4;
z is from 0 to 20;
x+z is from 6 to 40;
x/(x+z) is at least 0.57; and,
m is from 10 to 30.
12. The process of claim 10 wherein:
each R 6 is methyl; and,
independently in each polyether moiety R 7 ,
R 1 is hydrogen;
R 2 is hydrogen or methyl;
R 3 is hydrogen;
R 4 is hydrogen;
each R 8 independently is hydrogen or methyl;
p is 0;
x is from 6 to 30;
y is 2;
z is from 0 to 15;
x+z is from 6 to 35;
x/(x+z) is greater than 0.7; and,
m is from 10 to 30.
13. The process of claim 10 wherein balanced substantially linear ABA′ block copolymer surfactant (e) includes a spacer group between the A and B blocks and/or the B and A′ blocks.
14. The process of claim 10 wherein in balanced substantially linear ABA′ block copolymer surfactant (e), polyether blocks A and A′ are derived entirely from ethylene oxide.
15. The process of claim 10 wherein in balanced substantially linear ABA′ block copolymer surfactant (e), polyether blocks A and A′ are derived for at least half the weight thereof from ethylene oxide, the remaining portions of the alkyleneoxy chains constituting polyether blocks A and A′ being independently derived from one or more other alkylene oxides and/or strained oxygen-containing rings.
16. The process of claim 15 wherein blocks A and A′ are derived for at least 70 percent of the weight thereof from ethylene oxide.
17. The process of claim 15 wherein the remaining portions of the alkyleneoxy chains constituting polyether blocks A and A′ are derived from propylene oxide.
18. The process of claim 16 wherein the remaining portions of the alkyleneoxy chains constituting polyether blocks A and A′ are derived from propylene oxide.
19. The predominantly open-cell rigid, stable polyurethane foam of claim 1 wherein substantially linear ABA′ block copolymer surfactant(s) (e) is present in the foam-forming reaction medium at a level of from 0.1 to 10 parts per hundred parts of polyol(s) (a).
20. The process of claim 10 wherein substantially linear ABA′ block copolymer surfactant(s) (e) is present in the foam-forming reaction medium at a level of from 0.1 to 10 parts per hundred parts of polyol(s) (a).
21. The predominantly open-cell rigid, stable polyurethane foam of claim 1 wherein in ABA′ block copolymer surfactant(s)(e), the B block is provided by a polysiloxane reactant which possesses an Mn value of from 350 to 3,2000 and the A and A′ blocks are provided by polyether reactant(s) which possess Mn values of from 200 to 3,000.
22. The process of claim 10 wherein in ABA′ block copolymer surfactant(s)(e), the B block is provided by a polysiloxane reactant which possesses an Mn value of from 350 to 3,2000 and the A and A′ blocks are provided by polyether reactant(s) which possess Mn values of from 200 to 3,000.
23. The predominantly open-cell rigid, stable polyurethane foam of claim 19 wherein in ABA′ block copolymer surfactant(s)(e), the B block is provided by a polysiloxane reactant which possesses an Mn value of from 350 to 3,2000 and the A and N blocks are provided by polyether reactant(s) which possess Mn values of from 200 to 3,000.
24. The process of claim 20 wherein in ABA′ block copolymer surfactant(s)(e), the B block is provided by a polysiloxane reactant which possesses an Mn value of from 350 to 3,2000 and the A and A′ blocks are provided by polyether reactant(s) which possess Mn values of from 200 to 3,000.
25. The predominantly open-cell rigid, stable polyurethane foam of claim 1 wherein x/(x+z) is greater than 0.7 and the cell structure ranges from fine to medium.
26. The process of claim 10 wherein x/(x+z) is greater than 0.7 and the cell structure ranges from fine to medium.
27. The predominantly open-cell rigid, stable polyurethane foam of claim 1 wherein the foam-forming reaction medium contains 0.1 to 10 parts by weight of ABA′ block copolymer surfactant(s) (e) per 100 parts by weight of polyol(s) (a).
28. The process of claim 10 wherein the foam-forming reaction medium contains 0.1 to 10 parts by weight of ABA′ block copolymer surfactant(s) (c) per 100 parts by weight of polyol(s) (a).