Compositional and structural gradients for fuel cell electrode materials
View Patent ↗A fuel cell includes at least one electrode operatively disposed in the fuel cell, and having a catalytically active surface. The present invention further includes a mechanism for maintaining a substantially uniform maximum catalytic activity over the surface of the electrode.
1. A method for making a fuel cell anode, comprising the steps of:
depositing a first film on a first end region of a substrate, wherein the first film is preferentially catalytically active toward substantially unreformed hydrocarbon fuel;
depositing a second film on a second end region of the substrate, the second end region opposed to the first end region, wherein the second film is preferentially catalytically active toward at least one of substantially reformed or partially reformed hydrocarbon fuel, byproducts thereof, and mixtures thereof;
depositing an intermediate film on a region of the substrate intermediate the first end region and the second end region, wherein the intermediate film is preferentially catalytically active toward at least one of substantially unreformed or partially reformed hydrocarbon fuel, byproducts thereof, and mixtures thereof; and
biasing inclusion of nickel toward the second film, wherein each of the first, intermediate, and second films has as a main component thereof a nickel-samaria doped ceria cermet.
2. A method for making a fuel cell anode, comprising the steps of:
depositing a first film on a first end region of a substrate, wherein the first film is preferentially catalytically active toward substantially unreformed hydrocarbon fuel;
depositing a second film on a second end region of the substrate, the second end region opposed to the first end region, wherein the second film is preferentially catalytically active toward at least one of substantially reformed or partially reformed hydrocarbon fuel, byproducts thereof, and mixtures thereof; and
depositing an intermediate film on a region of the substrate intermediate the first end region and the second end region, wherein the intermediate film is preferentially catalytically active toward at least one of substantially unreformed or partially reformed hydrocarbon fuel, byproducts thereof, and mixtures thereof;
wherein the first film has as a main component thereof LaCr(Ni)O 3 , wherein the intermediate film has as a main component thereof La(Sr)CrO 3 , and wherein the second film has as a main component thereof La(Sr)Cr(Mn)O 3 .
3. The method as defined in claim 1 wherein the second film comprises pores, wherein the intermediate film comprises pores smaller than the second film pores, and wherein the first film comprises pores smaller than the intermediate film pores.
4. A fuel cell anode formed by the process of claim 1 .
5. A method of using a fuel cell, comprising the step of:
operatively connecting the fuel cell to at least one of an electrical load and an electrical storage device, the fuel cell comprising: a flow passage having a gas stream flowing therethrough; and at least one anode formed by the process of claim 1 operatively disposed in the flow passage.
6. The method as defined in claim 2 wherein the second film comprises pores, wherein the intermediate film comprises pores smaller than the second film pores, and wherein the first film comprises pores smaller than the intermediate film pores.
7. A fuel cell anode formed by the process of claim 2 .
8. A method of using a fuel cell, comprising the step of:
operatively connecting the fuel cell to at least one of an electrical load and an electrical storage device, the fuel cell comprising: a flow passage having a gas stream flowing therethrough; and at least one anode formed by the process of claim 2 operatively disposed in the flow passage.
9. The method as defined in claim 1 wherein biasing inclusion of the nickel toward the second film includes adjusting an amount of nickel that is deposited in each of the films such that the amount of the nickel in the intermediate film is greater than the amount of the nickel in the first film, and the amount of the nickel in the second film is greater than the amount of the nickel in the intermediate film.