Easy to disperse, high durability TiO
View Patent ↗The present invention relates to a TiO 2 pigment coated sequentially in a wet treatment process with hydrous silica and hydrous alumina both in the presence of citric acid wherein the resulting pigment is coated with from 1 to 4% amorphous alumina based on the weight of the untreated TiO 2 ; from 3 to 6% silica glass based on the weight of the untreated TiO 2 .
1. A method for making titanium dioxide particles surface coated with silica and alumina, comprising the steps in order:
A. (1) heating a slurry of raw titanium dioxide particles to a temperature of from 85 to 100° C.,
(2) adding citric acid as a solution in water to the slurry to form a mixture,
(3) adjusting the pH of the mixture to 10 or more,
(4) adding sufficient sodium silicate as a water solution to the mixture to deposit silica on the surface of the particles of from 1 to 6% based on the weight of the titanium dioxide particles in the slurry,
(5) neutralizing the slurry by addition of a mineral acid over the course of one hour, thereby forming a slurry of silica coated titanium dioxide particles;
B. (1) adjusting the temperature of the slurry of silica coated titanium dioxide particles to a temperature of from 55 to 90° C.,
(2) adding sufficient sodium aluminate as a water solution to the slurry in step B(1) and adjusting the pH of the mixture formed to from 5 to 9 by addition of a strong mineral acid to deposit alumina as Al 2 O 3 of from 1 to 4% by weight based on the weight of titanium dioxide particles present in the slurry of step A(1) on the surface of the silica coated particles, and digesting the resulting mixture for from 15 to 30 minutes to form the titanium dioxide particles surface coated sequentially with amorphous silica and amorphous alumina; and
C. dispersing the surface coated titanium dioxide into a resin to form a coating formulation.
2. The method of claim 1 wherein the resin is an alkyd resin.
3. The method of claim 1 wherein in step A(1) the slurry is heated to a temperature of from 90 to 95° C.
4. The method of claim 1 wherein the citric acid is added to the slurry to a concentration based on the weight of the titanium dioxide particles of from 0.1 to 2%.
5. The method of claim 1 wherein the strong mineral acid is selected from the group consisting of nitric, hydrochloric and sulfuric acids.
6. The method of claim 1 wherein in step B(2) the addition of sodium aluminate solution and the pH adjustment by addition of mineral acid is done simultaneously.