Integrated fuel line to support CPOX and SMR reactions in SOFC systems
View Patent ↗A fuel cell system comprises at least one fuel cell stack, a CPOX reactor, and a conduit for providing a fuel stream to the at least one fuel cell stack through the CPOX reactor during both a start up and a steady state modes of operation of the system.
1. A method of operating a fuel cell system comprising at least one fuel cell stack, a catalytic partial oxidizing (CPOX) reactor and a fuel reformer located downstream of the CPOX reactor, said method comprising:
providing a fuel inlet stream to the fuel cell stack through the CPOX reactor and the fuel reformer during both a start-up and a steady state mode of operation of the system;
providing air into the CPOX reactor during the start-up mode; and
regulating air provided to the CPOX reactor as the system nears steady state conditions by controlling air flow into the CPOX reactor with an air blower by shutting off the air blower once the system approaches steady state,
wherein all fuel provided to the at least one fuel cell stack always passes through the CPOX reactor and the fuel reformer throughout both start-up and steady state modes; and
wherein the CPOX reactor is located outside a hot box and the fuel reformer and the fuel cell stack are located inside the hot box.
2. The method of claim 1 , wherein the step of regulating air provided to the CPOX reactor as the system nears steady state conditions by controlling air flow into the CPOX reactor with an air blower further comprises controlling the air blower to provide continuously less air to the CPOX reactor as the system nears steady state prior to shutting off the air blower.
3. The method of claim 1 , wherein said fuel cell system comprises a fuel inlet conduit connecting a fresh fuel source to the at least one fuel cell stack through a CPOX reactor.
4. The method of claim 3 , further comprising mixing an anode exhaust stream with steam to generate a humidified anode exhaust stream and combining the fuel inlet stream with the humidified anode exhaust stream.
5. The method of claim 1 , wherein the CPOX reactor does not catalyze a fuel reaction during the steady state mode.
6. The method of claim 1 , wherein the step of providing the fuel inlet stream to the fuel cell stack through the CPOX reactor comprises flowing a liquid fuel inlet stream in sufficient proximity to the CPOX reactor such that heat from the CPOX reactor vaporizes at least a portion of the liquid fuel to form a vaporized fuel followed by providing the vaporized fuel into the CPOX reactor.