Process for preparing high molecular weight polyesters
View Patent ↗A process for producing higher molecular weight polyester includes heating a polyester to form a melt, and applying and maintaining a vacuum of between about 5 mm and about 85 mm of mercury to the melt while passing bubbles of gas through the melt until molecular weight has increased. The process may involve esterification of a diacid component and a diol component at elevated temperature. After the acid functional groups have essentially reacted, a vacuum of about 5 mm of mercury or less was applied and excess diol stripped off during transesterification, thereby increasing molecular weight.
1. A process for producing a higher molecular weight polyester comprising:
providing a stirred tank reactor vessel;
heating a polyester in the stirred tank reactor vessel to form a melt;
adding a catalyst to the stirred tank reactor vessel; and
applying and maintaining a vacuum of between about 5 mm and about 85 mm of mercury to the melt contained in the stirred tank reactor vessel while passing bubbles of gas through the melt until molecular weight has increased, wherein the bubbles of gas are introduced to the melt from near the bottom of the melt.
2. The process of claim 1 , wherein the vacuum is between about 25 mm and 50 mm of mercury.
3. The process of claim 1 , wherein the melt viscosity is monitored as the gas bubbles pass through the melt.
4. The process of claim 3 , wherein the process is stopped when the polyester attains a target melt viscosity,
5. The process of claim 3 , wherein the melt viscosity is monitored with a melt viscosity monitoring device comprising a stirrer equipped with a torque readout.
6. The process of claim 4 , therein the target melt viscosity is a delta torque value.
7. The process of claim 1 , wherein the gas is ambient air.
8. The process of claim 1 , wherein the gas is nitrogen.
9. The process of claim 1 , wherein the gas is dry air.
10. The process of claim 6 , wherein the delta torque is greater than 10.
11. The process of claim 10 , wherein the delta torque is greater than 15.
12. The process of claim 1 , wherein the melt comprises a polyester comprising a diacid component and a diol component.
13. The process of claim 12 , wherein the melt comprises a polyester comprising a slight mole excess of the diacid component.
14. The process of claim 1 , wherein the melt comprises a polyester comprising a diacid component, a diester component and a diol component.
15. A process for producing a higher molecular weight polyester comprising:
providing a stirred tank reactor vessel;
heating a polyester in the stirred tank reactor vessel to form a melt; and
applying and maintaining a vacuum of between about 5 mm and about 85 mm of mercury to the melt contained in the stirred tank reactor vessel while passing bubbles of ambient air through the melt until molecular weight has increased, wherein the bubbles of ambient air are introduced to the melt from near the bottom of the melt.
16. The process of claim 15 , wherein the vacuum is between about 25 mm and 50 mm of mercury.
17. The process of claim 15 , wherein the melt viscosity is monitored as the ambient air bubbles pass through the melt.
18. The process of claim 15 , wherein the process is stopped when the polyester attains a target melt viscosity.
19. The process of claim 15 , wherein the melt viscosity is monitored with a melt viscosity monitoring device comprising a stirrer equipped with a torque readout.
20. The process of claim 19 , therein the target melt viscosity is a delta torque value.
21. The process of claim 15 , wherein the melt comprises a polyester comprising a diacid component and a diol component.
22. The process of claim 15 , wherein the melt comprises a polyester comprising a slight mole excess of the diacid component.
23. The process of claim 15 , wherein the melt comprises a polyester comprising a diacid component, a diester component and a diol component.
24. The process of claim 1 , wherein the stirred tank reactor vessel holds 100 gallons.
25. The process of claim 15 , wherein the stirred tank reactor vessel holds 100 gallons.