Method for manufacturing nickel alloy
View Patent ↗A nickel alloy having an excellent corrosion resistance (hereinafter referred to as “nickel alloy”) used for pipes, structural materials and structural members, such as bolts or the like, in a nuclear power plant or in a chemical plant, and a manufacturing method for the same are provided. In the nickel alloy according to the present invention, an excellent corrosion resistance, in particular an excellent resistance against the IGSCC, is obtained by specifying the low angle boundary rate of 4% or more in the grain boundaries, along with the restriction of the chemical composition in the alloy, thereby making it possible to provide a nickel alloy which is most suitably used for pipes, structural materials and structural members, such as bolts or the like. Accordingly, the nickel alloy according to the present invention is widely applicable to structural members used in a nuclear station or in a chemical plant.
1. A method for manufacturing a nickel alloy consisting of, by mass %, C: 0.01-0.04%; Si: 0.05-1%; Mn: 0.07-1%; P: 0.015% or less; S: 0.015% or less; Cr: 28-31%; Ni: 50-70%; Al: 0.5% or less; Ti: 0.01-0.5%; and the balance Fe and impurities, said method comprising a step of cold working the alloy, wherein a final reduction pass in the step of cold working is carried out at an area reduction rate of 70% or more, followed by solution heat treating the cold worked alloy at 900° C. or more to form the nickel alloy, wherein a crystal structure of the nickel alloy has a low angle boundary rate of 4% more as for grain boundaries and the nickel alloy has excellent resistance to intergranular stress corrosion cracking.
2. A method for manufacturing a nickel alloy according to claim 1 , wherein the cold working applied to the nickel alloy is cold rolling.
3. A method for manufacturing a nickel alloy according to claim 1 , wherein a heat treatment for precipitating carbides at the grain boundaries is applied after the solution heat treatment.