Self-Adhesive Addition-Crosslinking Silicon Rubber Blends, A Method For The Production Thereof, Methods For Producing Composite Moulded Parts And The Use Thereof
The invention relates to self-adhesive addition cross linking silicon-rubber blends to a method for the production thereof and to a method for producing composite moulded parts and by means of the inventive blends.
1 . An addition-crosslinking silicone rubber blend comprising:
a) at least one linear or branched organopolysiloxane having at least two alkenyl groups, with a viscosity of 0.01 to 30 000 Pa·s (25° C.),
b1) at least one organohydrogensiloxane having in each case on average at least 20 SiH units per molecule and having at least one organic radical containing at least one constituent selected from aromatic groups, halogen atoms, pseudohalogen groups, polyether groups, aminoalkyl groups, and ammonioalkyl groups,
b2) if desired, one or more organohydrogenpolysiloxanes which have on average at least two SiH groups per molecule and in which the organic radicals are selected from the following: saturated and unsaturated aliphatic hydrocarbon radicals,
c) at least one hydrosilylation catalyst,
d) at least one constituent selected from the group consisting of the following: alkoxysilanes and/or alkoxysiloxanes each having at least one epoxy group, acryl- and methacryloyloxyalkyltrialkoxysilanes, and condensation products of the aforementioned compounds through reaction with water, alcohols, silanols and/or siloxanediols,
e) if desired, at least one inhibitor,
f) if desired, at least one filler with or without surface modification,
g) if desired, at least one auxiliary.
2 . The addition-crosslinking silicone rubber blend of claim 1 , characterized in that the organopolysiloxane a) is a linear or branched polysiloxane which can have the following siloxy units:
in which the substituents R can be identical or different and are selected from the group consisting of
a linear, branched or cyclic alkyl radical having up to 12 carbon atoms, which if desired can be substituted by at least one substituent selected from the group consisting of phenyl and halogen,
a linear, branched or cyclic alkenyl radical having up to 12 carbon atoms,
a phenyl radical,
hydroxyl, and
a linear, branched or cyclic alkoxy radical having up to 6 carbon atoms, or two substituents R from different siloxy units together form a linear, branched or cyclic alkanediyl radical having 2 to 12 carbon atoms between two silicon atoms, with the proviso that at least two substituents R per molecule represent the stated alkenyl radical, which can be identical or different.
3 . The addition-crosslinking silicone rubber blend of claim 1 , wherein component b1) are selected from linear, branched or cyclic polysiloxanes which can have the following siloxy units:
in which R 1 can be identical or different and is selected from the group consisting of
hydrogen
a linear, branched or cyclic alkyl radical having up to 12 carbon atoms, which if desired can be substituted by at least one substituent selected from the group consisting of phenyl and halogen,
a linear, branched or cyclic alkenyl radical having up to 12 carbon atoms,
an aromatic group, and
a linear, branched or cyclic alkoxy radical having up to 6 carbon atoms, or two groups R 1 from different siloxy units together form a linear, branched or cyclic alkanediyl radical having 2 to 12 carbon atoms between two silicon atoms.
4 . The addition-crosslinking silicone rubber blend of claim 1 , wherein the organohydrogensiloxane b1) has on average in each case at least 23 SiH units per molecule.
5 . The addition-crosslinking silicone rubber blend of claim 1 , wherein the Si—H content of the organohydroxysiloxane b1), defined as the proportion of the silicon-bonded H atoms relative to the sum of the silicon-bonded H atoms and the silicon-bonded organic groups, is more than 36 mol %.
6 . The addition-crosslinking silicone rubber blend of claim 1 , wherein the organohydrogensiloxane b1) has at least one unsubstituted or substituted aromatic group.
7 . The addition-crosslinking silicone rubber blend of claim 1 , wherein the organohydrogensiloxane b1) is a linear triorganosiloxy- and/or diorganohydrogensiloxy-endstopped organohydrogensiloxane, wherein the triorganosiloxy end groups are selected from the group consisting of trimethylsiloxy, triphenylsiloxy, diphenylmethylsiloxy, phenyldimethylsiloxy, phenylethyldimethylsiloxy, and phenylpropyldimethoxysiloxy, the diorganohydrogensiloxy end group is preferably a dimethylhydrogensiloxy group, and that has on average 20 to 1000 methylhydrogensiloxy units, on average less than 500 dimethylsiloxy groups, on average less than 360 (methyl)(phenyl)siloxy units, and on average less than 180 diphenylsiloxy units.
8 . The addition-crosslinking silicone rubber blend of claim 1 , characterized in that the alkoxysilanes of component d) are selected from glycidyloxypropyltrialkoxysilane, 2-(3,4-epoxycyclohexyl)-ethyltrialkoxysilane, and methacryloyloxypropyltrialkoxysilane.
9 . A method of producing the addition-crosslinking silicone rubber blend of claim 1 , characterized in that it comprises mixing components a) to d) and optionally components e) to g).
10 . The method of claim 9 , characterized in that it includes the production of at least one partial mixture which comprises more than one, but not all, of components a) to g).
11 . The method of claim 9 , characterized in that a first partial mixture is prepared by combining
at least one organopolysiloxane a),
if desired, at least one filler f),
if desired, at least one auxiliary g),
at least one catalyst c), and
if desired, at least one alkoxysilane and/or alkoxysiloxane d),
a second partial mixture is prepared by combining
if desired, an organopolysiloxane a),
at least one organohydrogensiloxane b1),
if desired, at least one organohydrogenpolysiloxane b2),
if desired, at least one filler f),
if desired, at least one alkoxysilane and/or alkoxysiloxane d),
if desired, at least one inhibitor e), and
if desired, at least one auxiliary g),
and the two partial mixtures are subsequently mixed.
12 . An addition-crosslinked silicone rubber blend obtained by crosslinking the compositions of claim 1 .
13 . A method of producing composite moldings, characterized in that at least one addition-crosslinking silicone rubber blend of claim 1 is crosslinked on a substrate.
14 . The method of claim 13 , wherein the substrate is selected from mineral, metallic, thermoset and/or thermoplastic substrates.
15 . The method of claim 13 , characterized in that the silicone rubber blend is applied to the surface of a pre-produced thermoset or thermoplastic molding, where appropriate with spreading, casting, calendering, knife coating, and rolling, and then is crosslinked at temperatures of 0 to 300° C., in the course of which it is adhered.
16 . The method of claim 13 , characterized in that the silicone rubber blend is vulcanized at temperatures of 50-300° C. on the surface of a thermoset or thermoplastic molding which has been injection-molded beforehand in an injection mold, and in the course of this vulcanization is adhered.
17 . The method of claim 13 , characterized in that the thermoplastic material is selected from polybutylene terephthalate, polyamide or polyphenylene sulfide.
18 . (canceled)
18 . (canceled)
19 . A composite molding comprising a mineral, metallic, thermoset and/or thermoplastic substrate and an addition-crosslinked silicone rubber blend of claim 12 .
20 . The composite molding of claim 19 , which is a sealing and/or damping mounting element, handle, keyboard, plug with elastomeric seals, switch, showerhead, lamp socket or other fixing.
21 . An organohydrogenpolysiloxane b1) characterized in that it has on average at least 20 hydrogensiloxy units in the molecule, in that it includes Si-bonded monovalent organic radicals which contain aromatic groups, and the amount of the monovalent organic radicals which contain aromatic groups is less than 12 mol %.
22 . The method of 13, wherein the addition-crosslinking silicone rubber blend is produced by mixing partial mixtures as described in claim 10 .
23 . A component set consisting of at least two storage-stable components which when combined produce the addition-crosslinking composition of claim 1 .