Method for the distillative purification of slow-evaporating fluids
View Patent ↗The present invention relates to a method for removing volatile compounds from sparingly volatile fluids by means of rectification using an auxiliary and also to separation methods and chemical reactions in which sparingly volatile fluids are used, the purification of which is effected by means of rectification and using an auxiliary.
1. A method for separating mixtures of substances using one or more ionic liquids and/or polymers as a selective additive, wherein the one or more ionic liquids and/or polymers are freed from one or more volatile components by multistage rectification in a distillation unit, wherein
(i) at least one volatile auxiliary is used;
(ii) the at least one volatile auxiliary used in the bottom of the distillation unit contributes a significant proportion of at least 50% to the pressure owing to its partial pressure;
(iii) the pressure in the bottom of the distillation unit minus the partial pressure of the at least one volatile auxiliary which prevails there does not exceed 10 mbar;
(iv) the at least one volatile auxiliary used leaves the distillation unit for the most part together with the ionic liquids and/or polymers at the bottom;
(v) the at least one volatile auxiliary has a partition coefficient which is higher than that of the ionic liquids and/or polymers but lower than the partition coefficient of the one or more volatile components; and
(vi) the auxiliary is reused together with the one or more ionic liquids and/or polymers and is substantially circulated without removing the auxiliary.