Method for manufacturing pressure-resistant container liner and liquid crystal resin liner
View Patent ↗A resin composition formed by mixing 99 to 70 weight % of specific whole aromatic polyesteramide liquid crystal resin (A) with 1 to 30 weight % of epoxy modified polyolefin-base resin (B) and by melting and kneading both of the resins, wherein the resin composition having a melt viscosity of 60 to 4000 Pa·s at a shear rate of 1000/second at a temperature which is 20° C. higher than the melting point and having a melt tension of 20 mN or more at a take-over speed of 14.8 m/minute, is melt within a temperature range of a melting point to the melting point +40° C., a parison (P) is formed by extruding it with an extrusion speed equal to or higher than 0.3 kg/minute and lower than 5 kg/minute, a pair of moldings placed so as to sandwich the parison (P) are closed at a predetermined mold closing pressure, and air is blown into the parison (P).
1. A method for manufacturing a pressure-resistant container liner by a blow molding, comprising:
a resin composition melting step of mixing 99 to 70 weight % of specific whole aromatic polyesteramide liquid crystal resin (A), the whole aromatic polyesteramide liquid crystal resin comprising repeating polymerization units of:
(I) 1 to 15 mol % of 6-hydroxy-2-naphthoic acid residue,
(II) 40 to 70 mol % of 4-hydroxy benzoic acid residue,
(III) 5 to 28.5 mol % of aromatic diol residue,
(IV) 1 to 20 mol % of 4-aminophenol residue, and
(V) 6 to 29.5 mol % of aromatic dicarboxylic acid residue, with
1 to 30 weight % of epoxy modified polyolefin-base resin (B), with a total of the whole aromatic polyesteramide liquid crystal resin (A) and epoxy modified polyolefin-base resin (B) being 100 weight % of the resin composition, to form a resin composition by melting and kneading the whole aromatic polyesteramide liquid crystal resin and epoxy modified polyolefin-base resin, and of heating and melting the resin composition within a temperature range of a melting point to the melting point +40° C., the resin composition having a melt viscosity of 60 to 4000 Pas at a shear rate of 1000/second at a temperature which is 20° C. higher than the melting point and having a melt tension of 20 mN or more at a take-over speed of 14.8 m/minute;
a parison forming step of extruding and forming a cylindrical parison with an extrusion speed equal to or higher than 0.3 kg/minute and lower than 5 kg/minute by using the specific resin composition melt in the resin composition melting step;
a mold closing step of placing the parison formed in the parison forming step between a pair of molds forming a cylindrical cavity and of closing the molds, the pair of molds each comprising half of a two-stage pinch section provided in a wall of each mold such that when the pair of molds are closed there is formed at least one two-stage pinch section, comprising two pinch sections and a space between the two pinch sections, within one wall of the closed pair of molds; and
a forming step of blowing gas into the parison in the molds closed in the mold closing step to form a liner.
2. A method for manufacturing a pressure-resistant container liner by a blow molding, comprising:
a resin composition melting step of mixing 99 to 70 weight % of specific whole aromatic polyesteramide liquid crystal resin (A), the whole aromatic polyesteramide liquid crystal resin comprising repeating polymerization units of:
(I) 1 to 15 mol % of 6-hydroxy-2-naphthoic acid residue,
(II) 40 to 70 mol % of 4-hydroxy benzoic acid residue,
(III) 5 to 28.5 mol % of aromatic diol residue,
(IV) 1 to 20 mol % of 4-aminophenol residue, and
(V) 6 to 29.5 mol % of aromatic dicarboxylic acid residue, with
1 to 30 weight % of epoxy modified polyolefin-base resin (B), with a total of the whole aromatic polyesteramide liquid crystal resin (A) and the epoxy modified polyolefin-base resin (B) being 100 weight % of the resin composition, to form a resin composition by melting and kneading the whole aromatic polyesteramide liquid crystal resin and epoxy modified polyolefin-base resin, and of heating and melting the resin composition within a temperature range of a melting point to the melting point +40° C., the resin composition having a melt viscosity of 60 to 4000 Pas at a shear rate of 1000/second at a temperature which is 20° C. higher than the melting point and having a melt tension of 20 mN or more at a take-over speed of 14.8 m/minute;
a parison forming step of extruding and forming a cylindrical parison with a shear rate equal to or higher than 50/second and lower than 1000/second by using the specific resin composition melt in the resin composition melting step;
a mold closing step of placing the parison formed in the parison forming step between a pair of molds forming a cylindrical cavity and of closing the molds, the pair of molds each comprising half of a two-stage pinch section provided in a wall of each mold such that when the pair of molds are closed there is formed at least one two-stage pinch section, comprising two pinch sections and a space between the two pinch sections, within one wall of the closed pair of molds; and
a forming step of blowing gas into the parison in the molds closed in the mold closing step to form a liner.
3. The method for manufacturing the pressure-resistant container liner as claimed in claim 1 or 2 , wherein:
a resin composition in which an increase rate of a melt tension at a twice take-over speed (29.6 m/minute) to the melt tension at the take-over speed of 14.8 m/minute is 1.05 or more, is used.
4. The method for manufacturing the pressure-resistant container liner as claimed in claim 1 or 2 , wherein:
when the mold closing step is performed, a value obtained by dividing a mold closing pressure by a thickness of a pinch-off section is of 3.5 MPa/cm or more.
5. The method for manufacturing the pressure-resistant container liner as claimed in claim 1 or 2 , further comprising:
forming the liner with a trunk section having a tensile breaking elongation in all directions of 2% or more, and with a pinch-off section having a tensile breaking elongation in all directions of 1% or more.
6. The method for manufacturing the pressure-resistant container liner as claimed in claim 5 , further comprising:
forming the liner with a pinch-off section having a thickness of 2 mm or more.
7. A method for manufacturing a pressure-resistant container liner by a blow molding, comprising:
a resin composition melting step of mixing a resin that consists essentially of a whole aromatic polyesteramide liquid crystal resin (A), and an epoxy modified polyolefin-base resin (B), by mixing 99 to 70 weight % of the resin (A), with 1 to 30 weight % of the resin (B);
the resin (A) comprising repeating polymerization units of:
(I) 1 to 15 mol % of 6-hydroxy-2-naphthoic acid residue,
(II) 40 to 70 mol % of 4-hydroxy benzoic acid residue,
(III) 5 to 28.5 mol % of aromatic diol residue,
(IV) 1 to 20 mol % of 4-aminophenol residue, and
(V) 6 to 29.5 mol % of aromatic dicarboxylic acid residue, wherein
the resin composition is formed by melting and kneading the resin (A) and resin (B), and heating and melting the resin composition within a temperature range from a melting point to the melting point +40° C., the resin composition having a melt viscosity of 60 to 4000 Pas at a shear rate of 1000/second at a temperature which is 20° C. higher than the melting point and having a melt tension of 20 mN or more at a take-over speed of 14.8 m/minute;
a parison forming step of extruding and forming a cylindrical parison, using the specific resin composition melt in the resin composition melting step, with either: an extrusion speed equal to or higher than 0.3 kg/minute and lower than 5 kg/minute, or a shear rate equal to or higher than 50/second and lower than 1000/second;
a mold closing step of placing the parison formed in the parison forming step between a pair of molds forming a cylindrical cavity and of closing the molds, the pair of molds each comprising half of a two-stage pinch section provided in a wall of each mold such that when the pair of molds are closed there is formed at least one two-stage pinch section, comprising two pinch sections and a space between the two inch sections within one wall of the closed pair of molds; and
a forming step of blowing gas into the parison in the molds closed in the mold closing step to form a liner.
8. The method for manufacturing the pressure-resistant container liner as claimed in claim 1 , 2 or 7 , wherein:
the pair of molds each comprise two or more halves of a two-stage pinch section such that when the pair of molds are closed there is formed two or more two-stage pinch sections.
9. The method for manufacturing the pressure-resistant container liner as claimed in claim 1 , 2 or 7 , wherein:
the resin composition has a melt viscosity of 80 to 4000 Pas.
10. The method for manufacturing the pressure-resistant container liner as claimed in claim 9 , wherein:
the resin composition has a melt viscosity of 299 to 4000 Pas.