IP Library Granted Patent US 8,076,381
Granted Patent B2
US 8,076,381 · App. 11/911,552 · Granted Dec 13, 2011

Polyhydroxyalkanoate-based resin foamed particle, molded article comprising the same and process for producing the same

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Quick Facts
Patent No.
US 8,076,381
App. No.
11/911,552
Granted
Dec 13, 2011
Kind
B2
Abstract

The object is to provide a molded product of foamed particles obtained by charging biodegradable resin foamed particles which are of vegetable origin and excellent in environmental compatibility into a mold, followed by heat molding, which molded product is not accompanied by post shrinkage after the molding with a wide range of variation of processing in the molding. Further, P3HA resin foamed particles being composed of a resin composition that comprises an isocyanate compound, and a polymer, poly(3-hydroxyalkanoate), having a recurring unit represented by the general formula (1): [—O—CHR—CH 2 —CO—]  (1) (wherein R represents an alkyl group represented by C n H 2n+1 , wherein n is an integer of from 1 to 15) produced by a microorganism are provided.

Claims (8)

1. Poly(3-hydroxyalkanoate) resin foamed particles being composed of a resin composition that comprises an isocyanate compound, and a polymer, poly(3-hydroxyalkanoate), having a recurring unit represented by the general formula (1):

[—O—CHR—CH 2 —CO—]  (1)

wherein R represents an alkyl group represented by C n H 2n+1 , wherein n is an integer of from 1 to 15, produced by a microorganism,

wherein the poly(3-hydroxyalkanoate) is poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) and the 3-hydroxyhexanoate is included in an amount of 1 to 20% by mole in the composition of copolymerizing components of the poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)

wherein the amount of the isocyanate compound is 0.5 to 4 parts by weight per 100 parts by weight of the poly(3-hydroxyalkanoate).

2. A molded product of the poly(3-hydroxyalkanoate) resin foamed particles obtained by charging the resin foamed particles according to claim 1 into a mold, followed by heat molding.

3. A method of producing the poly(3-hydroxyalkanoate) resin foamed particles according to claim 1 comprising: allowing a substrate resin comprising a resin composition comprising poly(3-hydroxyalkanoate) and an isocyanate compound to be dispersed in an aqueous dispersion medium in an airtight container together with a dispersant; then introducing a foaming agent into the airtight container; heating them to not lower than the softening temperature of the substrate resin; and thereafter opening one end of the airtight container so as to release the substrate resin and the aqueous dispersion medium to an atmosphere with a pressure lower than the pressure in the airtight container, thereby allowing the substrate resin to be foamed.

4. A process of production of a molded article, comprising charging the foamed particles according to claim 1 into a mold, followed by heat molding to obtain the molded article.

Assignments (14)
SECURITY INTEREST Recorded Dec 17, 2024
From: DANIMER SCIENTIFIC, INC.; MEREDIAN HOLDINGS GROUP, INC.; DANIMER SCIENTIFIC HOLDINGS, LLC; MEREDIAN, INC.; DANIMER SCIENTIFIC, L.L.C.; DANIMER BIOPLASTICS, INC.; DANIMER IPCO, LLC; DANIMER IPHOLDCO, LLC; NOVOMER, INC.
To: JEFFERIES CAPITAL SERVICES, LLC; RIVA RIDGE MASTER FUND, LTD.; BPI CREDIT 6, L.L.C.
Reel/Frame 069888/0715 →
SECURITY INTEREST Recorded Mar 22, 2023
From: DANIMER SCIENTIFIC, INC.; MEREDIAN HOLDINGS GROUP, INC.; DANIMER SCIENTIFIC HOLDINGS, LLC; DANIMER SCIENTIFIC MANUFACTURING, INC.; MEREDIAN, INC.; DANIMER SCIENTIFIC, L.L.C.; DANIMER SCIENTIFIC KENTUCKY, INC.; DANIMER BIOPLASTICS, INC.; DANIMER IPCO, LLC; NOVOMER, INC.; DANIMER IPHOLDCO, LLC
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 063146/0091 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 17, 2023
From: MEREDIAN, INC.
To: DANIMER IPCO, LLC
Reel/Frame 063113/0383 →
RELEASE OF SECURITY INTEREST Recorded Mar 16, 2023
From: SOUTHEAST COMMUNITY DEVELOPMENT FUND X, L.L.C.
To: DANIMER BIOPLASTICS, INC.; MEREDIAN, INC.; MEREDIAN BIOPLASTICS, INC.; DANIMER SCIENTIFIC, L.L.C.
Reel/Frame 063006/0860 →
RELEASE OF SECURITY INTEREST Recorded Jan 20, 2023
From: WHITE OAK GLOBAL ADVISORS, LLC
To: DANIMER BIOPLASTICS, INC.; MEREDIAN, INC.; MEREDIAN BIOPLASTICS, INC.,; DANIMER SCIENTIFIC, L.L.C.
Reel/Frame 062440/0763 →
RELEASE OF SECURITY INTEREST Recorded Aug 5, 2022
From: TRUIST BANK
To: DANIMER SCIENTIFIC, L.L.C.; DANIMER BIOPLASTICS, INC.; MEREDIAN, INC.; MEREDIAN BIOPLASTICS, INC.
Reel/Frame 061088/0018 →
SECURITY INTEREST Recorded May 3, 2021
From: DANIMER SCIENTIFIC, L.L.C.; DANIMER BIOPLASTICS, INC.; MEREDIAN, INC.; MEREDIAN BIOPLASTICS, INC.
To: TRUIST BANK
Reel/Frame 056122/0473 →
RELEASE OF SECURITY INTEREST Recorded Feb 5, 2021
From: WHITE OAK GLOBAL ADVISORS, LLC
To: DANIMER BIOPLASTICS, INC.; MEREDIAN, INC.; MEREDIAN BIOPLASTICS, INC.; DANIMER SCIENTIFIC, L.L.C.
Reel/Frame 055225/0196 →
SECURITY INTEREST Recorded Mar 19, 2019
From: DANIMER BIOPLASTICS, INC.; MEREDIAN, INC.; MEREDIAN BIOPLASTICS, INC.; DANIMER SCIENTIFIC, L.L.C.
To: SOUTHEAST COMMUNITY DEVELOPMENT FUND X, L.L.C.
Reel/Frame 048639/0606 →
SECURITY INTEREST Recorded Mar 15, 2019
From: DANIMER BIOPLASTICS, INC.; MEREDIAN, INC.; MEREDIAN BIOPLASTICS, INC.; DANIMER SCIENTIFIC, L.L.C.
To: WHITE OAK GLOBAL ADVISORS, LLC
Reel/Frame 048612/0195 →
RELEASE OF SECURITY INTEREST Recorded Feb 4, 2019
From: UNITED NATIONAL BANK
To: MEREDIAN, INC.
Reel/Frame 048234/0522 →
CORRECTIVE ASSIGNMENT TO CORRECT THE SECURITY INTEREST AGREEMENT BY REMOVING TWO U.S. PATENTS ERRONEOUSLY INCLUDED ON THE THE SAME PREVIOUSLY RECORDED ON REEL 027175 FRAME 0614. ASSIGNOR(S) HEREBY CONFIRMS THE TWO U.S. PATENTS TO BE REMOVED FROM THE SEC. INT AGREEMENT ARE U.S. PATENT NOS. 7,226,765 AND 7,378,266. Recorded Dec 19, 2014
From: MEREDIAN, INC.
To: UNITED NATIONAL BANK
Reel/Frame 034687/0718 →
CORRECTIVE ASSIGNMENT TO CORRECT THE CORRECTIVE ASSIGNMENT TO REMOVE TWO U.S. PATENTS ERRONEOUSLY INCLUDED ON THE SECURITY ASSIGNMENT PREVIOUSLY RECORDED ON REEL 027175 FRAME 0614. ASSIGNOR(S) HEREBY CONFIRMS THE TWO U.S. PATENTS TO BE REMOVED FROM THE SECURITY AGREEMENT ARE U.S. PATENT NO. 7,226,765 AND U.S. PATENT NO. 7,378,266. Recorded Mar 21, 2014
From: MEREDIAN, INC.
To: UNITED NATIONAL BANK
Reel/Frame 032503/0923 →
CHANGE OF ADDRESS Recorded Jan 15, 2014
From: KANEKA CORPORATION
To: KANEKA CORPORATION
Reel/Frame 032019/0901 →