Agrochemical compositions containing naphthalene sulfonate derivatives and nitrogen-containing surfactants
View Patent ↗The present invention relates to a composition comprising a) an anionic compound having wetting and dispersing properties selected from the group of a1) an alkyl naphthalene sulfonate, a2) a naphthalene sulfonate-formaldehyde condensate that may optionally be alkyl substituted and mixtures thereof, and b) a nitrogen-containing surfactant selected from the group consisting of alkylamine alkoxylates, alkylamidoamine alkoxylates, alkanolamides and their alkoxylates, alkylamidopropylamines, betaines, amino acids, or any mixtures thereof, wherein <the weight ratio between a) and b) is between 99.99:0.01 and 40:60 while> the molar amount of anionic sulfonate and, if any are present, carboxylate groups in the composition is in excess of the molar amount of nitrogen-containing groups. These compositions exhibit synergistic wetting properties as compared to the surface-active components taken alone. Further, the compositions also exhibit an increased rainfastness. The compositions can be used as a wetting agent and/or as an agent for increasing rainfastness in cleaning or agrocultural formulations. The invention also relates to an agrocultural formulation per se.
1. A composition comprising
a) a naphthalene sulfonate-formaldehyde condensate that may optionally be alkyl substituted, and mixtures thereof, and
b) a nitrogen-containing surfactant selected from the group consisting of alkylamine alkoxylates, alkylamidoamine alkoxylates, alkanolamides and their alkoxylates, alkylamido propylamines, betaines, amino acids, or any mixtures thereof,
wherein the weight ratio between a) and b) is between 99.99:0.01 and 85:15, provided that the molar amount of anionic sulfonate and, if any are present, carboxylate groups in the composition is in excess of the molar amount of nitrogen-containing groups.
2. A composition according to claim 1 wherein b) is an alkylamine alkoxylate, an alkylamidoamine alkoxylate, an alkanolamide, and/or an alkanolamide alkoxylate having the following formula
wherein R is a hydrocarbyl or an acyl group having 8-18 carbon atoms, X is a hydrocarbyl group having 8-18 carbon atoms, hydrogen, (AO) x H or the group
Y is hydrogen or (AO) x H, n is 0-3, AO is an alkyleneoxy group with 2 or 3 carbon atoms, for ethyleneoxy groups the sum of x is 1-30, for propyleneoxy groups the sum of x is 0-10.
3. A composition according to claim 2 wherein b) is an alkanolamide or an alkoxylated alkanolamide according to the formula
wherein R 1 C(═O)— is an acyl group with 8-16 carbon atoms, Y is H or the group (EO) q (PO) r H, where EO is an ethylene oxide group, each q is, independently, a number of 1-10 and the sum of all q is 1-20, each r is, independently, 0-5 and the sum of all r is 0-10.
4. A composition according to claim 1 wherein b) is a betaine having the formula
wherein R 2 is a hydrocarbyl group with 8-18 carbon atoms or the group R 3 —C(═O)—NH—CH 2 —CH 2 —CH 2 —, wherein R 3 —C(═O)— is an acyl group having 8-18 carbon atoms, R 4 and R 5 are a C 1 -C 4 -alkyl group or the group (EO) S H, where EO is an ethylene oxide group and s is a number of 1-10.
5. A composition according to claim 1 wherein b) is an amino acid according to the formula
wherein R 6 is a hydrocarbyl or acyl group with 8-18 carbon atoms, n is a number of 0-3 , A is a group —(CH 2 ) t —CO 2 − M + , hydrogen or the group
and B is a group —(CH 2 ) t —CO 2 − M + or H, provided that when R 6 is an acyl group, n is at least 1 and the group A situated on the nitrogen atom bonded directly to the acyl group is hydrogen, t is a number 1-2, and M + is a monovalent cation, at least one of the groups A and B is —(CH 2 ) t —CO 2 − M + .
6. A composition according to claim 1 wherein b) is an alkylamido propylamine having the formula
wherein R 7 (C═O)—is an acyl group having 8-18 carbon atoms and R 8 and R 9 are, independently, an alkyl group with 1-4 carbon atoms.
7. A composition according to claim 1 further comprising an agrochemical pesticide or another crop production chemical.
8. A composition according to claim 7 wherein the agrochemical pesticide or other crop production chemical is selected from the group consisting of herbicides, fungicides, insecticides, and fertilizers.
9. A wetting agent which comprises the composition of claim 1 .
10. A cleaning composition comprising an effective amount of the composition of claim 1 .
11. A composition according to claim 1 wherein the naphthalene sulfonate-formaldehyde condensate or optionally substituted alkyl naphthalene-sulfonate formaldehyde condensate has a mean molecular weight of 300-2,000, and wherein the alkyl group contains 1-3 carbon atoms.
12. A method for increasing the rainfastness of an agricultural formulation which comprises adding an effective amount therefor of the composition of claim 1 to said formulation.