Process for grinding cellulose ether
View Patent ↗The invention relates to a process for grinding cellulose ether comprising the steps of: a) grinding a cellulose ether comprising 20 to 90 wt % of water, based on the total weight of cellulose ether and water, and a cationic surfactant in a mill; and b) optionally drying the mixture while grinding, prior to or following the step of grinding.
1. A process for grinding a moist cellulose ether mixture comprising the steps of:
a) grinding a moist cellulose ether mixture comprising 20 to 90 wt % of water, based on the total weight of cellulose ether and water, and a cationic surfactant in a mill; and
b) optionally drying the mixture while grinding, prior to or following the step of grinding
wherein the cellulose ether is a non-ionic cellulose ether selected from the group consisting of methyl cellulose, hydroxyethyl cellulose, methyl hydroxyethyl cellulose, ethyl hydroxyethyl cellulose, methyl ethyl hydroxyethyl cellulose, hydroxypropyl hydroxyethyl cellulose, methyl hydroxypropyl hydroxyethyl cellulose, hydroxypropyl cellulose, methyl hydroxypropyl cellulose, and ethyl hydroxypropyl cellulose; and
wherein the cationic surfactant is a quaternary ammonium salt, and
wherein the mean particle size of the cellulose ether after grinding is between 0.05 and 1 mm.
2. A process according to claim 1 wherein the cationic surfactant is a quaternary ammonium salt comprising at least one hydrocarbon group comprising 8 to 22 carbon atoms.
3. A process according to claim 1 wherein the cationic surfactant is present in an amount of 0.001 to 2 wt %, based on the total weight of the mixture.
4. A process according to claim 1 wherein the cationic surfactant is present in an amount of 0.01 to 0.5 wt %, based on the total weight of the mixture.
5. A process according to claim 1 , wherein the cationic surfactant is present in an amount of 0.001 to 0.1 wt %, based on the total weight of the dry cellulose ether.
6. A process according to claim 5 , wherein the cellulose ether mixture comprises 40 to 85 wt % of water, based on the total weight of cellulose ether and water.
7. A process according to claim 6 , wherein the cationic surfactant is a quaternary ammonium salt having two methyl groups and two hydrocarbon groups comprising 8 to 22 carbon atoms all bonded to a N atom.
8. A process according to claim 7 , wherein the cationic surfactant is didecyl dimethyl ammonium chloride.
9. A process according to claim 1 , wherein the process comprises simultaneously grinding and drying the cellulose ether.
10. A process according to claim 1 wherein the cellulose ether mixture consists essentially of a mixture of cellulose ether, 20 to 90 wt % of water, based on the total weight of cellulose ether and water, and a cationic surfactant.
11. A process according to claim 1 wherein the cellulose ether mixture consists of a mixture of cellulose ether, 20 to 90 wt % of water, based on the total weight of cellulose ether and water, and a cationic surfactant.
12. A process for grinding a composition comprising cellulose ether/water lumps, the lumps comprising 20 to 90 wt % of water, based on the total weight of cellulose ether and water, the process comprising the steps of:
a) combining the composition comprising cellulose ether/water lumps with an amount of a cationic surfactant;
b) grinding the combined composition of step (a) in a mill; and
c) optionally drying the combined composition while grinding, prior to or following the step of grinding
wherein the cellulose ether is a non-ionic cellulose ether selected from the group consisting of methyl cellulose, hydroxyethyl cellulose, methyl hydroxyethyl cellulose, ethyl hydroxyethyl cellulose, methyl ethyl hydroxyethyl cellulose, hydroxypropyl hydroxyethyl cellulose, methyl hydroxypropyl hydroxyethyl cellulose, hydroxypropyl cellulose, methyl hydroxypropyl cellulose, and ethyl hydroxypropyl cellulose; and
wherein the cationic surfactant is a quaternary ammonium salt, and
wherein the mean particle size of the cellulose ether after grinding is between 0.05 and 1 mm.
13. The process of claim 12 , wherein the cellulose ether lumps comprise 40-85 wt % water, based on the total weight of the cellulose ether and water.