Organic electroluminescence element
View Patent ↗Disclosed is an organic electroluminescent device having a longer drive life. Specifically disclosed is an organic electroluminescent device ( 100 ) comprising an organic material layer ( 16 ), which is composed of a hole transporting layer ( 164 ), a light-emitting layer ( 166 ) and an electron transporting layer ( 167 ), between a pair of electrodes, namely a cathode ( 18 ) and an anode ( 12 ). The light-emitting layer ( 166 ) (having a film thickness (dM) of 5-3000 nm) contains a luminescent dye and a host material. The first oxidation potential (ED+) of the luminescent dye is lower than the first oxidation potential (EH+) of the host material, while the first reduction potential (ED−) of the luminescent dye is lower than the first reduction potential (EH−) of the host material. The film thickness (dE: 5-3000 nm) of the electron transporting layer ( 167 ) and the film thickness (dH: 5-3000 nm) of the hole transporting layer ( 164 ) satisfy the following relation: dH≦dE.
1. An organic electroluminescence element comprising with respect to the layers between a pair of electrodes of anode and cathode;
a luminescence layer;
a hole transport layer provided on an anode side of the luminescence layer, the hole transport layer having a hole transport layer thickness (“dH”) of 5 nm to 3000 nm and comprising a plurality of layers; and
an electron transport layer provided on a cathode side of the luminescence layer, the electron transport layer having an electron transport layer thickness (“dE”) of 5 nm to 3000 nm and comprising a plurality of layers,
wherein the luminescence layer has a thickness of 5 nm to 3000 nm and contains a luminescence pigment and a host material, the luminescence pigment containing an organo-metalic complex compound,
a first oxidation potential (“ED+”) of the luminescence pigment is lower than a first oxidation potential (“EH+”) of the host material, and a first reduction potential (“ED−”) of the luminescence pigment is lower than a first reduction potential (“EH−”) of the host material,
a relation between dE and dH is dH≦dE,
a relation between a total number of layers of the hole transport layer (“NH”) and a total number of layers of the electron transport layer (“NE”) is set to NH≦NE, and
a first layer adjacent to the luminescence layer of the electron transport layer comprises an electron transport material and the electron transport material has a wide band gap and a first oxidation potential greater than an electron transport material of another layer of the electron transport layer,
wherein the organo-metalic complex compound is a compound represented by the following formula (Chemical formula 2):
in the formula, M represents metal and m+n represents valence number of the metal, and the metal is selected from the group consisting of ruthenium, rhodium, palladium, silver, rhenium, osmium, iridium, platinum, and gold,
m is an integral number of not less than 0, and n is an integral number of not less than 1, L represents monovalent bidentate ligand, and
ring a and ring b represent aromatic hydrocarbon group that may have substitutional group, and
wherein the host material is a compound represented by any one of the following formulas (Chemical formulas 9 to 12):
2. The organic electroluminescence element according to claim 1 ,
wherein a hole injection layer is provided between the anode and the hole transport layer.
3. The organic electroluminescence element according to claim 2 ,
wherein the hole injection layer includes an electron acceptor and film thickness (“dB”) thereof is 5 nm to 3000 nm.
4. The organic electroluminescence element according to claim 1 ,
wherein the organo-metalic complex compound is Ir (ppy) 3 represented by the following Chemical formula 3: