High strength spring-use heat treated steel
View Patent ↗The present invention provides spring use heat treated steel which is cold coiled, can achieve both sufficient atmospheric strength and coilability, has a tensile strength of 2000 MPa or more, and can improve the performance as a spring by heat treatment after spring fabrication, that is, high strength spring-use heat treated steel characterized by containing, by mass %, C: 0.45 to 0.9%, Si: 1.7 to 3.0%, and Mn: 0.1 to 2.0%, restricting N: to 0.007% or less, having a balance of Fe and unavoidable impurities, and satisfying, in terms of the analyzed value of the extracted residue after heat treatment, [amount of Fe in residue on 0.2 μm filter/[steel electrolysis amount]×100≦1.1.
1. A high-strength, heat treated steel for use in automobile springs, wherein the chemical composition of said steel consisting of, by mass %,
C: 0.4 to 0.74%,
Si: 1.7 to 3.0%,
Mn: 0.1 to 2.0%,
restricting
N: to 0.005% or less,
P: to 0.015% or less,
S: to 0.015% or less,
O: to 0.0002 to 0.01%, and
Al: to 0.005% or less; and
at least one of
Ti: 0.001 to less than 0.05%,
W: 0.05 to 0.5%, and
Ta: 0.001 to 0.5%; and
optionally at least one of
Cr: 0.51 to 2.5%,
V: 0.02 to 0.1%,
Nb: 0.001 to less than 0.05%,
Mo: 0.05 to 0.5%,
Ni: 0.05 to 3.0%,
Cu: 0.05 to 0.5%,
Co: 0.05 to 3.0%,
B: 0.0005 to 0.006%,
Te: 0.0002 to 0.01%,
Sb: 0.0002 to 0.01%,
Mg: 0.0001 to 0.0005%,
Zr: 0.0001 to 0.0005%,
Ca: 0.0002 to 0.01%, and
Hf: 0.0002 to 0.01%; and
a balance of Fe and unavoidable impurities, and
wherein said steel is formed into said spring; then subsequently tempered at a temperature less than 450° C.; and subsequent to tempering, said steel is stress-relief annealed and nitrided;
wherein said nitrided steel has suppressed formation of coarse cementite precipitates, the presence of said coarse cementite precipitates measured in terms of an analyzed value of the extracted residue resulting from electrolysis
[amount of Fe in residue on 0.2 μm filter]/[steel electrolysis amount]×100≦1.1,
and wherein said nitrided steel has a prior austenite grain size number of #10 or more, a residual austenite in an amount of 15 mass % or less, and has a tensile drawing ratio of 40.0 to 44.7.
2. High strength spring-use heat treated steel as set forth in claim 1 , wherein the C is present in an amount of 0.4 to 0.7%.
3. High strength spring-use heat treated steel as set forth in claim 1 , wherein the C is present in an amount of 0.4 to 0.65%.
4. High strength spring-use heat treated steel as set forth in claim 1 , wherein the N is present in an amount of 0.004% or less.
5. High strength spring-use heat treated steel as set forth in claim 1 , wherein the Al is present in an amount of 0.003% or less.
6. High strength spring-use heat treated steel as set forth in claim 1 , wherein the Cr is present in an amount of 1.1% or more.
7. High strength spring-use heat treated steel as set forth in claim 1 , wherein the Cr is present in an amount of 1.2% or more.