Organic electroluminescence element

1. An organic electroluminescence element, comprising electrodes, a light emitting layer, a hole transport layer for transporting holes to the light emitting layer, and an electron transport layer for transporting electrons to the light emitting layer,

wherein said light emitting layer, said hole transport layer and said electron transport layer are formed between the electrodes, while the light emitting layer is formed between said hole transport layer and said electron transport layer, and

wherein the light emitting layer has a first region, and a second region,

said first region being formed at the side of the hole transport layer, said first region containing light emitting layer host material and a compound functioning as an electron accepting dopant, and

said second region being formed at the side of the electron transport layer, said second region containing light emitting layer host material and a compound functioning as a light emitting dopant,

wherein said compound functioning as an electron accepting dopant differs from material forming the hole transport layer.

2. The organic electroluminescence element of claim 1 , wherein said compound functioning as an electron accepting dopant is capable of oxidizing organic matter chemically like a Lewis acid.

3. The organic electroluminescence element of claim 1 , wherein said compound functioning as an electron accepting dopant is selected from the group including: metal oxide such as vanadium oxide, molybdenum oxide, rhenium oxide, and tungsten oxide; inorganic compound such as ferric chloride, ferric bromide, ferric iodide, aluminum iodide, gallium chloride, gallium bromide, gallium iodide, indium chloride, indium bromide, indium iodide, and antimony pentachloride, arsenic pentafluoride, boron trifluoride; and organic compound such as DDQ (dicyano-dichloroquinone), TNF (trinitrofluorenone), TCNQ (tetracyanoquinodimethane), and 4F-TCNQ (tetrafluoro-tetracyanoquinodimethane).

4. The organic electroluminescence element of claim 2 , wherein material forming the hole transport layer is selected from the group including: aromatic diamine compound such as N,N′-bis (3-methylphenyl)-(1,1′-biphenyl)-4,4′ diamine (TPD) and 4,4′-bis (N-(naphthyl)-N-phenyl-amino) biphenyl (α-NPD); and high molecular material such as stilbene derivative and pyrazoline derivative and polyarylalkane and 4,4′,4″-tris (N-(3-methylphenyl) N-phenylamino) triphenylamine (m-MTDATA) and 2,2′,7,7′-tetrakis-(N,N-diphenylamino)-9, 9′-spirobifluorene and polyvinylcarbazole.

5. The organic electroluminescence element of claim 3 , wherein material forming the hole transport layer is selected from the group including: aromatic diamine compound such as N,N′-bis (3-methylphenyl)-(1,1′-biphenyl)-4,4′ diamine (TPD) and 4,4′-bis (N-(naphthyl)-N-phenyl-amino) biphenyl (α-NPD); and high molecular material such as stilbene derivative and pyrazoline derivative and polyarylalkane and 4,4′,4″-tris (N-(3-methylphenyl) N-phenylamino) triphenylamine (m-MTDATA) and 2,2′,7,7′-tetrakis-(N,N-diphenylamino)-9, 9′-spirobifluorene and polyvinylcarbazole.

6. An organic electroluminescence element, comprising electrodes, a light emitting layer, a hole transport layer for transporting holes to the light emitting layer, and an electron transport layer for transporting electrons to the light emitting layer,

wherein said light emitting layer, said hole transport layer and said electron transport layer are formed between the electrodes, while the light emitting layer is formed between said hole transport layer and said electron transport layer,

wherein the light emitting layer has a first region, a second region, and a third region,

said first region being formed at the side of the hole transport layer, said first region containing light emitting layer host material and a compound functioning as an electron accepting dopant,

said second region being formed at the side of the electron transport layer, said second region containing light emitting layer host material and a compound functioning as a light emitting dopant, and

said third region being disposed between the first and second regions, said third region only consisting of light emitting layer host material, and

wherein said compound functioning as an electron accepting dopant differs from material forming the hole transport layer.

7. The organic electroluminescence element of claim 6 , wherein said compound functioning as an electron accepting dopant is capable of oxidizing organic matter chemically like a Lewis acid.

8. The organic electroluminescence element of claim 6 , wherein said compound functioning as an electron accepting dopant is selected from the group including: metal oxide such as vanadium oxide, molybdenum oxide, rhenium oxide, and tungsten oxide; inorganic compound such as ferric chloride, ferric bromide, ferric iodide, aluminum iodide, gallium chloride, gallium bromide, gallium iodide, indium chloride, indium bromide, indium iodide, and antimony pentachloride, arsenic pentafluoride, boron trifluoride; and organic compound such as DDQ (dicyano-dichloroquinone), TNF (trinitrofluorenone), TCNQ (tetracyanoquinodimethane), and 4F-TCNQ (tetrafluoro-tetracyanoquinodimethane).

9. The organic electroluminescence element of claim 7 , wherein material forming the hole transport layer is selected from the group including: aromatic diamine compound such as N,N′-bis (3-methylphenyl)-(1,1′-biphenyl)-4,4′ diamine (TPD) and 4,4′-bis (N-(naphthyl)-N-phenyl-amino) biphenyl (α-NPD); and high molecular material such as stilbene derivative and pyrazoline derivative and polyarylalkane and 4,4′,4″-tris (N-(3-methylphenyl) N-phenylamino) triphenylamine (m-MTDATA) and 2,2′,7,7′-tetrakis-(N,N-diphenylamino)-9,9′-spirobifluorene and polyvinylcarbazole.

10. The organic electroluminescence element of claim 8 , wherein material forming the hole transport layer is selected from the group including: aromatic diamine compound such as N,N′-bis (3-methylphenyl)-(1,1′-biphenyl)-4,4′ diamine (TPD) and 4, 4′-bis (N-(naphthyl)-N-phenyl-amino) biphenyl (α-NPD); and high molecular material such as stilbene derivative and pyrazoline derivative and polyarylalkane and 4,4′,4″-tris (N-(3-methylphenyl) N-phenylamino) triphenylamine (m-MTDATA) and 2,2′,7,7′-tetrakis-(N,N-diphenylamino)-9,9′-spirobifluorene and polyvinylcarbazole.

11. An organic electroluminescence element, comprising electrodes, a light emitting layer, and a hole transport layer for transporting holes to the light emitting layer, and an electron transport layer for transporting electrons to the light emitting layer,

wherein said light emitting layer, said hole transport layer and said electron transport layer are formed between the electrodes, while the light emitting layer is formed between said hole transport layer and said electron transport layer, and

wherein the light emitting layer has a first region, a second region, and a third region,

said first region being formed at the side of the hole transport layer, said first region containing light emitting layer host material and a compound functioning as a light emitting dopant,

said second region being formed at the side of the electron transport layer, said second region containing light emitting layer host material and a substance functioning as an electron donating dopant, and

said third region being disposed between the first and second regions, said third region only consisting of light emitting layer host material,

wherein said substance functioning as an electron donating dopant differs from material forming the electron transport layer.

12. The organic electroluminescence element of claim 11 , wherein said substance functioning as an electron donating dopant has reduction property with respect to organic matter.

13. The organic electroluminescence element of claim 11 , wherein said substance functioning as an electron donating dopant is at least one kind of substance selected from the group consisting of alkali metal, alkaline earth metal, rare earth metal, oxide of alkali metal, halogenide of alkali metal, oxide of alkaline earth metal, halogenide of alkaline earth metal, oxide of rare earth metal, halogenide of rare earth metal, and carbonate of alkali metal.

14. The organic electroluminescence element of claim 11 , wherein material forming the electron transport layer is metal complex where aromatic compound coordinates with alkali metal.

15. The organic electroluminescence element of claim 12 ,

wherein material forming the electron transport layer is selected from the group including: fluorene, bathophenanthroline, bathocuproin, anthraquinodimethane, diphenoquinone, oxazole, oxadiazole, triazole, imidazole, and 4, 4′-N,N′-dicarbazolebiphenyl (CBP); compound of them; metal complex compound; and nitrogen-containing five-membered ring derivative,

wherein the metal complex compound is tris (8-hydroxyquinolinate) aluminum; tri(2-methyl-8-hydroxyquinolinate) aluminum; tris (8-hydroxyquinolinate) gallium; bis (10-hydroxybenzo[h]quinolinate) beryllium; bis (10-hydroxybenzo[h]quinolinato) zinc; bis (2-methyl-8-quinolinate) (o-cresolate) gallium; bis (2-methyl-8-quinolinate) (1-naphtholate) aluminum; or bis (2-methl-8-quinolinate)-4-phenylphenolate,

wherein the nitrogen-containing five-membered ring derivative is oxazole, thiazole, oxadiazole, thiadiazole, or triazole derivative,

wherein the triazole derivative is: 2,5-bis (1-phenyl)-1,3,4-oxazole; 2,5-bis (1-phenyl)-1,3,4-thiazole; 2,5-bis (1-phenyl)-1,3,4-oxadiazole; 2-(4′-tert-butylphenyl)-5-(4″-biphenyl) 1, 3,4-oxadiazole; 2,5-bis (1-naphthyl)-1,3,4-oxadiazole; 1,4-bis[2-(5-phenylthiadiazolyl)]benzene; 2,5-bis (1-naphthyl)-1,3,4-triazole; or 3-(4-biphenylil)-4-phenyl-5-(4-t-butylphenyl)-1,2,4-triazole.

16. The organic electroluminescence element of claim 13 ,

wherein material forming the electron transport layer is selected from the group including: fluorene, bathophenanthroline, bathocuproin, anthraquinodimethane, diphenoquinone, oxazole, oxadiazole, triazole, imidazole, and 4,4′-N,N′-dicarbazolebiphenyl (CBP); compound of them; metal complex compound; and nitrogen-containing five-membered ring derivative,

wherein the metal complex compound is tris (8-hydroxyquinolinate) aluminum; tri (2-methl-8-hydroxyquinolinate) aluminum; tris (8-hydroxyquinolinate) gallium; bis (10-hydroxybenzo[h]quinolinate) beryllium; bis (10-hydroxybenzo[h]quinolinato) zinc; bis (2-methyl-8-quinolinate) (o-cresolate) gallium; bis (2-methyl-8-quinolinate) (1-naphtholate) aluminum; or bis (2-methyl-8-quinolinate)-4-phenylphenolate,

wherein the nitrogen-containing five-membered ring derivative is oxazole, thiazole, oxadiazole, thiadiazole, or triazole derivative,

wherein the triazole derivative is: 2,5-bis (1-phenyl)-1,3,4-oxazole; 2, 5-bis (1-phenyl)-1,3,4-thiazole; 2,5-bis (1-phenyl)-1,3,4-oxadiazole; 2-(4′-tert-butylphenyl)-5-(4″-biphenyl) 1, 3,4-oxadiazole; 2,5-bis (1-naphthyl)-1,3,4-oxadiazole; 1,4-bis[2-(5-phenylthiadiazolyl)]benzene; 2,5-bis (1-naphthyl)-1,3,4-triazole; or 3-(4-biphenylil)-4-phenyl-5-(4-t-butylphenyl)-1,2,4-triazole.

17. The organic electroluminescence element of claim 14 ,

wherein material forming the electron transport layer is selected from the group including: fluorene, bathophenanthroline, bathocuproin, anthraquinodimethane, diphenoquinone, oxazole, oxadiazole, triazole, imidazole, and 4,4′-N,N′-dicarbazolebiphenyl (CBP); compound of them; and nitrogen-containing five-membered ring derivative,

wherein the nitrogen-containing five-membered ring derivative is oxazole, thiazole, oxadiazole, thiadiazole, or triazole derivative,

wherein the triazole derivative is: 2,5-bis (1-phenyl)-1,3,4-oxazole; 2,5-bis (1-phenyl)-1,3,4-thiazole; 2,5-bis (1-phenyl)-1,3,4-oxadiazole; 2-(4′-tert-butylphenyl)-5-(4″-biphenyl) 1, 3,4-oxadiazole; 2,5-bis (1-naphthyl)-1,3,4-oxadiazole; 1,4-bis[2-(5-phenylthiadiazolyl)]benzene; 2,5-bis (1-naphthyl)-1,3,4-triazole; or 3-(4-biphenylil)-4-phenyl-5-(4-t-butylphenyl)-1,2,4-triazole.