Biodegradable resin composition and molded article produced from the same
View Patent ↗Disclosed is a resin composition excellent in molding processability which comprises a plant-derived biodegradable plastic produced by actively fixing carbon dioxide present in the earth. A resin composition excellent in molding processability, comprising (A) a biodegradable (3-hydroxyalkanoate) copolymer having a recurring unit represented by the formula (1): [—CHR—CH 2 —CO—O—] (wherein R represents an alkyl group represented by the formula C n H 2n+1 and n is an integer of 1 to 15) and 0.1 to 100 parts by weight, based on 100 parts by weight of (A) the biodegradable (3-hydroxyalkanoate) copolymer, of (B) an acrylic modifier having a weight average molecular weight (Mw) of 500,000 to 10,000,000.
1. A resin composition comprising (A) a biodegradable (3-hydroxyalkanoate) copolymer having a recurring unit represented by the formula (1): [—CHR—CH 2 —CO—O—] (wherein R represents an alkyl group represented by C n H 2n+1 ; and n is an integer of 1 to 15), and 0.1 to 20 parts by weight, based on 100 parts by weight of (A) the biodegradable (3-hydroxyalkanoate) copolymer, of (B) an acrylic modifier having an weight average molecular weight Mw of 500,000 to 10,000,000,
wherein the biodegradable (3-hydroxyalkanoate) copolymer (A) has a weight average molecular weight Mw of 300,000 to 3,000,000 and is a poly[(3-hydroxybutyrate)-co-(3-hydroxyhexanoate)] comprising a (3-hydroxybutyrate) recurring unit and a (3-hydroxyhexanoate) recurring unit, and the constituent ratio of the recurring units in the poly[(3-hydroxybutyrate)-co-(3-hydroxyhexanoate)] is represented by (3-hydroxybutyrate) unit/(3-hydroxyhexanoate) unit=99/1 to 80/20 (mol/mol), and
the acrylic modifier (B) is a copolymer of predominantly an acrylic ester and a methacrylic ester.
2. The resin composition according to claim 1 which is prepared by compounding using a master batch such that the acrylic modifier (B) accounts for 0.1 to 100 parts by weight based on 100 parts by weight of the biodegradable (3-hydroxyalkanoate) copolymer (A) in the resin composition,
wherein the master batch comprises 5 to 400 parts by weight of the acrylic modifier (B) based on 100 parts by weight of the biodegradable (3-hydroxyalkanoate) copolymer (A).
3. The resin composition according to claim 2 , wherein the master batch comprises 5 to 200 parts by weight of the acrylic modifier (B) based on 100 parts by weight of the biodegradable (3-hydroxyalkanoate) copolymer (A).
4. The resin composition according to claim 1 which further comprises a core-shell type graft copolymer (C).
5. The resin composition according to claim 1 , wherein the difference in refractive indices between the acrylic modifier (B) and the (3-hydroxyalkanoate) copolymer (A) is equal to or less than 0.02.
6. The resin composition according to claim 4 wherein a core layer of the core-shell type graft copolymer (C) predominantly comprises an acrylic ester, while a shell layer thereof predominantly comprises a methacrylic acid alkyl ester.
7. The resin composition according to claim 1 , wherein the acrylic modifier (B) comprises a copolymer of predominantly butyl acrylate and methyl methacrylate.
8. The resin composition according to claim 1 further comprising 0.1 to 10 parts by weight of at least one selected from a higher fatty acid amide, an urea derivative and a sorbitol-based compound as a nucleating agent based on 100 parts by weight of total amount of the biodegradable (3-hydroxyalkanoate) copolymer (A) and the acrylic modifier (B).
9. The resin composition according to claim 1 further comprising 0.1 to 100 parts by weight of a filler based on 100 parts by weight of total amount of the biodegradable (3-hydroxyalkanoate) copolymer (A) and the acrylic modifier (B).