Organic metal complex and its use in organic electroluminescent device
Disclosed are an organic electroluminescent device (organic EL device) that is improved in luminous efficiency and fully assured of driving stability and has a simple structure and an organic metal complex suitable therefor. The organic metal complex is represented by the following general formula (I) wherein Ar 1 denotes an aromatic hydrocarbon group or a heteroaromatic group and may have substituents, Ar 2 and Ar 3 respectively denote an aromatic hydrocarbon group or a heteroaromatic group and may have substituents, M denotes a trivalent metal, and L denotes an arylate ligand containing a hetero ring having at least one nitrogen atom capable of coordinating M. This organic metal complex, along with a phosphorescent dopant, is suitable for a material constituting the light-emitting layer of an organic EL device.
1. An organic electroluminescent device containing an organic layer comprising an organic metal complex represented by the following general formula (I) for use in an organic EL device:
in general formula (I), Ar 1 denotes a divalent aromatic hydrocarbon group or a divalent heteroaromatic group and may have substituents;
Ar 2 and Ar 3 respectively denote an aromatic hydrocarbon group or a heteroaromatic group and may have substituents and Ar 2 and Ar 3 never link together to form a ring;
M denotes a trivalent metal; and L is a ligand represented by the following general formula (III):
in general formula (III), the groups R 1 to R 8 respectively denote a hydrogen atom or an arbitrary substituent, substituents located adjacently may link together to form a ring, and X denotes an oxygen or sulfur atom,
wherein the organic layer comprising the organic metal complex is a light emitting layer, wherein the organic metal complex is a host material and wherein the host material is doped with a phosphorescent dopant,
wherein the aromatic hydrocarbon group of Ar 2 and Ar 3 is each independently at least one selected from the group consisting of phenyl, naphthyl, acenaphthyl, and anthryl groups, and wherein the heteroaromatic group of Ar 2 and Ar 3 is each independently at least one selected from the group consisting of pyridyl, quinolyl, thienyl, carbozolyl, indolyl, and furyl groups, wherein the aromatic hydrocarbon group and the heteroaromatic group may be substituted with at least one unsubstituted substituent selected from the group consisting of lower alkyl group of 1 to 6 carbon atoms, lower alkoxy group of 1 to 6 carbon atoms, phenoxy group, methylphenyloxy group, benzyloxy group, phenyl group, naphthyl group, and dimethylamino group.
2. An organic electroluminescent device as described in claim 1 , wherein L is a ligand represented by the following general formula (IV):
in general formula (IV), the groups R 1 to R 8 individually denote a hydrogen atom, halogen atom, alkyl group, aralkyl group, alkenyl group, alkynyl group, cyano group, dialkylamino group, diarylamino group, diaralkylamino group, amino group, nitro group, acyl group, alkoxycarbonyl group, carboxyl group, alkoxyl group, alkylsulfonyl group, haloalkyl group, hydroxyl group, amide group, aromatic hydrocarbon group which may have substituents, or heteroaromatic group which may have substituents.
3. An organic electroluminescent device as described in any one of claims 1 and 2 wherein Ar 1 is represented by the following general formula (IX):
in general formula (IX), the groups R 9 to R 12 independently denote a hydrogen atom, halogen atom, alkyl group, aralkyl group, alkenyl group, alkynyl group, cyano group, dialkylamino group, diarylamino group, diaralkylamino group, amino group, nitro group, acyl group, alkoxycarbonyl group, carboxyl group, alkoxyl group, alkylsulfonyl group, haloalkyl group, hydroxyl group, amide group, aromatic hydrocarbon group which may have substituents, or heteroaromatic group which may have substituents, and substituents which are located adjacently may link together to form a ring.
4. An organic electroluminescent device as described in claim 1 , wherein the M is an aluminum, gallium or indium.