Layer system for a component comprising a thermal barrier coating and metallic erosion-resistant layer, production process and method for operating a steam turbine
View Patent ↗There are described components of a steam turbine, comprising a thermally insulating layer and a metallic anti-erosion layer on said thermally insulating layer. The anti-erosion layer is provided with the same material as the metallic connecting layer.
1. A layer system for a component, comprising:
a substrate;
a metallic bonding layer, an erosion-resistant layer; wherein the metallic bonding layer is selected from the group consisting of:
9%-31% nickel (in wt %),
27%-29% chromium (in wt %),
7%-8% aluminum (in wt %),
0.5%-0.7% yttrium (in wt %),
0.3%-0.7% silicon (in wt %),
remainder cobalt,
11%-13% cobalt (in wt %),
20%-22% chromium (in wt %),
10.5%-11.5% aluminum (in wt %),
0.3%-0.5% yttrium (in wt %),
1.5%-2.5% rhenium (in wt %),
remainder nickel,
24%-26% cobalt (in wt %),
16%-18% chromium (in wt %),
9.5%-11% aluminum (in wt %),
0.3%-0.5% yttrium (in wt %),
1.0%-1.8% rhenium (in wt %),
remainder nickel,
11.5%-20% chromium (in wt %),
0.3%-1.5% silicon (in wt %),
0%-1% aluminum (in wt %),
0%-4% yttrium (in wt %),
remainder iron, and
12.5%-14% chromium (in wt %),
0.5%-1.0% silicon (in wt %),
0.1%-0.5% aluminum (in wt %),
0%-4% yttrium (in wt %),
remainder iron,
wherein the bonding layer and the erosion-resistant layer have a similar composition;
a thermal barrier coating on the metallic bonding layer; and
an outer metallic erosion-resistant layer on the thermal barrier coating.
2. The layer system as claimed in claim 1 , wherein the bonding layer and the erosion-resistant layer have an identical composition.
3. The layer system as claimed in claim 1 , wherein the component is a component of a steam turbine.
4. The layer system as claimed in claim 1 , wherein the thermal barrier coating is a ceramic thermal barrier coating.
5. The layer system as claimed in claim 1 , wherein the material of the bonding layer and of the erosion-resistant layer is an MCrAlX alloy.
6. The layer system as claimed in claim 1 , wherein the erosion-resistant layer and the bonding layer consist of an alloy selected from the group consisting of an iron-base alloy, a nickel-base alloy, a chromium-base alloy, a cobalt-base alloy, and NiCr80/20.
7. The layer system as claimed in claim 1 , wherein the erosion-resistant layer and the bonding layer consist of a nickel-chromium alloy with an admixture or of a nickel-aluminum alloy, wherein the admixture is selected from the group consisting of silicon, boron and a combination thereof.
8. The layer system as claimed in claim 1 , wherein the erosion-resistant layer has a lower porosity than the thermal barrier coating, and wherein a difference in density is at least 1%.
9. The layer system as claimed in claim 1 , wherein the erosion-resistant layer has a density of at least 96% of the theoretical density of the erosion-resistant layer.
10. The layer system as claimed in claim 1 , wherein the density of the thermal barrier coating is 80-95% of the theoretical density of the thermal barrier coating, and wherein the thermal barrier coating is at least partially porous.
11. The layer system as claimed in claim 10 , wherein the thermal barrier coating has a porosity gradient.
12. The layer system as claimed in claim 1 , wherein the material of the metallic erosion-resistant layer has a high ductility, and wherein the material of the metallic erosion-resistant layer has an elongation at break of 5%.
13. The layer system as claimed in claim 1 , wherein the layer system is a housing part of a gas or steam turbine.
14. The layer system as claimed in claim 1 , wherein the layer system is a turbine blade or vane.
15. The layer system as claimed in claim 1 , wherein the erosion-resistant layer is present on the component where the angle at which eroding particles impinge on the component is between 60°-120°, and wherein the thermal barrier coating is selected from the group consisting of zirconium oxide and titanium oxide.
16. The layer system as claimed in claim 1 , wherein the layer system is applied in the inflow region and in the bladed region of a steam turbine.
17. The layer system as claimed in claim 1 , wherein the bonding layer, the thermal barrier coating and the erosion-resistant layer are applied to refurbished components.
18. A method for producing a component with a layer system, comprising
providing a substrate;
providing a metallic bonding layer, an erosion-resistant layer; wherein the metallic bonding layer is selected from the group consisting of:
9%-31% nickel (in wt %),
27%-29% chromium (in wt %),
7%-8% aluminum (in wt %),
0.5%-0.7% yttrium (in wt %),
0.3%-0.7% silicon (in wt %),
remainder cobalt,
11%-13% cobalt (in wt %),
20%-22% chromium (in wt %),
10.5%-11.5% aluminum (in wt %),
0.3%-0.5% yttrium (in wt %),
1.5%-2.5% rhenium (in wt %),
remainder nickel,
24%-26% cobalt (in wt %),
16%-18% chromium (in wt %),
9.5%-11% aluminum (in wt %),
0.3%-0.5% yttrium (in wt %),
1.0%-1.8% rhenium (in wt %),
remainder nickel,
11.5%-20% chromium (in wt %),
0.3%-1.5% silicon (in wt %),
0%-1% aluminum (in wt %),
0%-4% yttrium (in wt %),
remainder iron, and
12.5%-14% chromium (in wt %),
0.5%-1.0% silicon (in wt %),
0.1%-0.5% aluminum (in wt %),
0%-4% yttrium (in wt %),
remainder iron,
wherein the bonding layer and the erosion-resistant layer have a similar composition,
a thermal barrier coating on the metallic bonding layer, and
an outer metallic erosion-resistant layer on the thermal barrier coating; and
densifying the erosion-resistant layer after application to the thermal barrier coating.
19. A method for operating a steam turbine, comprising:
providing a steam containing eroding particles flowing within the steam turbine, wherein the eroding particles impinge on inner surfaces of the steam turbine at an angle of 60°-120°, and wherein at least the inner surfaces of the steam turbine have a layer system having:
a substrate,
a metallic bonding layer, an erosion-resistant layer; wherein the metallic bonding layer is selected from the group consisting of:
9%-31% nickel (in wt %),
27%-29% chromium (in wt %),
7%-8% aluminum (in wt %),
0.5%-0.7% yttrium (in wt %),
0.3%-0.7% silicon (in wt %),
remainder cobalt,
11%-13% cobalt (in wt %),
20%-22% chromium (in wt %),
10.5%-11.5% aluminum (in wt %),
0.3%-0.5% yttrium (in wt %),
1.5%-2.5% rhenium (in wt %),
remainder nickel,
24%-26% cobalt (in wt %),
16%-18% chromium (in wt %),
9.5%-11% aluminum (in wt %),
0.3%-0.5% yttrium (in wt %),
1.0%-1.8% rhenium (in wt %),
remainder nickel,
11.5%-20% chromium (in wt %),
0.3%-1.5% silicon (in wt %),
0%-1% aluminum (in wt %),
0%-4% yttrium (in wt %),
remainder iron, and
12.5%-14% chromium (in wt %),
0.5%-1.0% silicon (in wt %),
0.1%-0.5% aluminum (in wt %),
0%-4% yttrium (in wt %),
remainder iron,
wherein the bonding layer and the erosion-resistant layer have a similar composition,
a thermal barrier coating on the metallic bonding layer, and
an outer metallic erosion-resistant layer on the thermal barrier coating.
20. The method as claimed in claim 19 , wherein the inner surfaces of the steam turbine are provided with a layer system on which the particles impinge at an angle of 80°-100°.