IP Library Granted Patent US 8,147,644
Granted Patent B2
US 8,147,644 · App. 11/922,545 · Granted Apr 3, 2012

Method of manufacturing thermoplastic membrane articles and methods of use

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Quick Facts
Patent No.
US 8,147,644
App. No.
11/922,545
Granted
Apr 3, 2012
Kind
B2
Abstract

A release liner web has thermoplastic membranes coated on opposite sides of the release liner web that are thermoplastically fused proximally to an edge of the release liner web, nearly doubling the width of thermoplastic membranes that can be prepared using conventional equipment. Also described are geomembranes prepared from an amorphous or semi-crystalline thermoplastic sheet material and having a high gloss surface, and methods of manufacture and use of same.

Claims (39)

1. A method of manufacturing a wide, fused thermoplastic membrane, comprising:

drawing a release liner web into a throat between parallel, spaced apart first and second nip rollers of a membrane extruder, the release liner web having first and second sides and first and second opposed edges;

simultaneously extruding a molten first thermoplastic and a molten second thermoplastic that are compatible and fusible with each other into the throat of the two rollers, wherein the first thermoplastic is extruded between the first side of the release liner web and the first roller, and wherein the-molten second thermoplastic is extruded into the throat of the two rollers between the second side of the release liner web and the second roller, the resulting first and second thermoplastic membranes being wider than the release liner web and thereby fusing the first thermoplastic and the second thermoplastic proximally to the first and second edges of the release liner web to encapsulate the release liner web and to form a thermoplastic/release liner web composite; and

slitting an edge of the resulting thermoplastic/release liner web composite to provide the first thermoplastic membrane coated on the first side of the release liner and the second thermoplastic membrane coated on the second side of the release liner, wherein the first thermoplastic membrane and the second thermoplastic membrane are fused proximally to the second edge of the release liner web.

2. A method of simultaneously manufacturing a plurality of thermoplastic membranes, comprising:

drawing a release liner web into a throat between parallel, spaced apart first and second nip rollers of a membrane extruder, the release liner web having first and second sides and first and second opposed edges;

simultaneously extruding a molten first thermoplastic and a molten second thermoplastic into the throat of the two rollers, wherein the first thermoplastic is extruded between the first side of the release liner web and the first roller, and wherein the molten second thermoplastic is extruded into the throat of the two rollers between the second side of the release liner web and the second roller, the resulting first and second thermoplastic membranes being wider than the release liner web, to form a thermoplastic/release liner web composite; and

slitting both edges of the resulting thermoplastic/release liner web composite to provide the first thermoplastic membrane coated on the first side of the release liner and the second thermoplastic membrane coated on the second side of the release liner, the first thermoplastic membrane not being fused to the second thermoplastic membrane.

3. The method of claim 2 further comprising winding the first thermoplastic membrane, the release liner and the second thermoplastic membrane together in a single roll.

4. The method of claim 2 further comprising removing the release liner from said first and second thermoplastic membranes and winding the first thermoplastic membrane and the second thermoplastic membrane in separate rolls.

5. A method of manufacturing a fused thermoplastic membrane tube, comprising:

drawing a release liner web into a throat between parallel, spaced apart first and second nip rollers of a membrane extruder, the release liner web having first and second sides and first and second opposed edges;

simultaneously extruding a molten first thermoplastic and a molten second thermoplastic that are compatible and fusible with each other into the throat of the two rollers, wherein the first thermoplastic is extruded between the first side of the release liner web and the first roller, and wherein the molten second thermoplastic is extruded into the throat of the two rollers between the second side of the release liner web and the second roller, the resulting first and second thermoplastic extrudates being wider than the release liner web and thereby fusing the first thermoplastic and the second thermoplastic extrudates proximally to the first and second edges of the release liner web to encapsulate the release liner web and to form a composite that comprises said extrudates and said release liner web; and

cutting said composite in a cross machine direction to provide a thermoplastic/release liner tube.

6. The method of claim 5 further comprising removing the release liner.

7. A method of manufacturing a fused thermoplastic membrane bladder, comprising:

drawing a release liner web having a predetermined length into a throat between parallel, spaced apart first and second nip rollers of a membrane extruder, the release liner web having first and second sides and first and second opposed side edges and front and back edges;

simultaneously extruding a molten first thermoplastic and a molten second thermoplastic that are compatible and fusible with each other into the throat of the two rollers, wherein the first thermoplastic is extruded between the first side of the release liner web and the first roller, and wherein the molten second thermoplastic is extruded into the throat of the two rollers between the second side of the release liner web and the second roller, the resulting first and second thermoplastic membranes being wider and longer than the release liner web and thereby fusing the first thermoplastic and the second thermoplastic proximally to the first and second side edges and the front and back edges of the release liner web to encapsulate the release liner web and to form a thermoplastic/release liner web composite; and

cutting the resulting thermoplastic/release liner web composite in a cross machine direction at a location that does not correspond to the release liner to provide a thermoplastic/release liner bladder.

8. The method of claim 7 further comprising introducing a gas or liquid in the thermoplastic/release liner bladder.

9. The method of claim 1 , wherein the first thermoplastic and the second thermoplastic are substantially the same material.

10. The method of claim 1 , wherein the first thermoplastic and the second thermoplastic comprise resins selected from polyvinyl chloride, polyethylene, linear polyethylene, polybutenes, polypropylene, co-polymers of polyolefins, ethylene-propylene rubber, ethylene-propylene copolymer, ethylene propylene diene monomer polymer, acrylonitrile-butadiene-styrene polymer, thermoplastic polyester, urethane and polyvinyl plastics, or mixtures thereof.

11. The method of claim 1 , wherein the first thermoplastic and the second thermoplastic comprise polyvinyl chloride.

12. The method of claim 1 , wherein the first thermoplastic membrane and the second thermoplastic membrane have thicknesses of from about 1 to about 100 mils.

13. The method of claim 1 , wherein the total width of the fused thermoplastic membrane is greater than about 20 feet.

14. The method of claim 1 , wherein the total width of the fused thermoplastic membrane is greater than about 24 feet.

15. The method of claim 1 , wherein the thermoplastic/release liner web composite comprises two release liner webs.

16. The method of claim 2 wherein the first thermoplastic and the second thermoplastic are substantially the same material.

17. The method of claim 2 wherein each of the first thermoplastic and the second thermoplastic comprises resins selected from polyvinyl chloride, polyethylene, linear polyethylene, polybutenes, polypropylene, co-polymers of polyolefins, ethylene-propylene rubber, ethylene-propylene copolymer, ethylene propylene diene monomer polymer, acrylonitrile-butadiene-styrene polymer, thermoplastic polyester, urethane and polyvinyl plastics, or mixtures thereof.

18. The method of claim 2 wherein each of the first thermoplastic and the second thermoplastic comprises polyvinyl chloride.

19. The method of claim 2 wherein each of the first and second thermoplastic membranes has a thickness of from about 1 to about 100 mils.

20. The method of claim 7 wherein the first thermoplastic and the second thermoplastic are substantially the same material.

21. The method of claim 7 wherein each of the first thermoplastic and the second thermoplastic comprises resins selected from polyvinyl chloride, polyethylene, linear polyethylene, polybutenes, polypropylene, co-polymers of polyolefins, ethylene-propylene rubber, ethylene-propylene copolymer, ethylene propylene diene monomer polymer, acrylonitrile-butadiene-styrene polymer, thermoplastic polyester, urethane and polyvinyl plastics, or mixtures thereof.

22. The method of claim 7 wherein each of the first thermoplastic and the second thermoplastic comprises polyvinyl chloride.

23. The method of claim 7 wherein each of the first and second thermoplastic membranes has a thickness of from about 1 to about 100 mils.

24. The method of claim 5 wherein the first thermoplastic and the second thermoplastic are substantially the same material.

25. The method of claim 5 wherein each of the first thermoplastic and the second thermoplastic comprises resins selected from polyvinyl chloride, polyethylene, linear polyethylene, polybutenes, polypropylene, co-polymers of polyolefins, ethylene-propylene rubber, ethylene-propylene copolymer, ethylene propylene diene monomer polymer, acrylonitrile-butadiene-styrene polymer, thermoplastic polyester, urethane and polyvinyl plastics, or mixtures thereof.

26. The method of claim 5 wherein each of the first thermoplastic and the second thermoplastic comprises polyvinyl chloride.

27. The method of claim 5 wherein each of the first and second thermoplastic extrudates has a thickness of from about 1 to about 100 mils.

Assignments (10)
RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY COLLATERAL Recorded Apr 1, 2020
From: JPMORGAN CHASE BANK, N.A.
To: OMNOVA SOLUTIONS INC.
Reel/Frame 052286/0971 →
CORRECTIVE ASSIGNMENT TO CORRECT THE INCORRECT APPL. NO. 13/389,145 PREVIOUSLY RECORDED AT REEL: 027501 FRAME: 0322. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jan 15, 2018
From: FIRESTONE DIVERSIFIED PRODUCTS, LLC
To: FIRESTONE BUILDING PRODUCTS COMPANY, LLC
Reel/Frame 045071/0576 →
RELEASE OF SECURITY INTEREST Recorded Feb 10, 2012
From: JPMORGAN CHASE BANK, N.A.
To: OMNOVA SOLUTIONS INC.
Reel/Frame 027687/0968 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 9, 2012
From: BFS DIVERSIFIED PRODUCTS, LLC
To: FIRESTONE BUILDING PRODUCTS COMPANY, LLC
Reel/Frame 027501/0736 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 9, 2012
From: FIRESTONE DIVERSIFIED PRODUCTS, LLC
To: FIRESTONE BUILDING PRODUCTS COMPANY, LLC
Reel/Frame 027501/0318 →
CORRECTIVE RELEASE OF SECURITY INTEREST Recorded Nov 23, 2011
From: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
To: OMNOVA SOLUTIONS INC.
Reel/Frame 027280/0783 →
SECURITY AGREEMENT Recorded Jan 4, 2011
From: OMNOVA SOLUTIONS INC.
To: JPMORGAN CHASE BANK, N.A., AS AGENT
Reel/Frame 025577/0152 →
SECURITY AGREEMENT Recorded Dec 16, 2010
From: OMNOVA SOLUTIONS INC.; ELIOKEM, INC.
To: DEUTSCHE BANK TRUST COMPANY AMERICAS
Reel/Frame 025495/0754 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 9, 2009
From: OMNOVA SOLUTIONS INC.
To: BFS DIVERSIFIED PRODUCTS, LLC
Reel/Frame 023351/0883 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 23, 2009
From: TIPPINS, WILLIAM D.
To: FIRESTONE DIVERSIFIED PRODUCTS, LLC
Reel/Frame 022296/0781 →