OLED device with fluoranthene electron transport materials

1. An OLED device comprising a cathode, an anode, and having there between a light-emitting layer, further comprising, between the cathode and the light emitting layer, a non-luminescent electron transporting layer containing a compound with a 7,10-diaryl substituted fluoranthene nucleus having no aromatic rings annulated to the fluoranthene nucleus, the fluoranthene compound having the following Formula (IIIa) or (IIIb):

wherein:

R 2 and R 4 are independently hydrogen or an aromatic group containing 6 to 24 carbon atoms with the proviso that R 2 and R 4 cannot both be hydrogen nor can R 2 be joined with R to form a ring;

R is hydrogen or an optional substituent; and

n and m are independently 1-5.

2. The OLED device of claim 1 wherein the non-luminescent electron transporting layer contains an organic lithium material according to Formula (V):

wherein:

Z and the dashed arc represent two to four atoms and the bonds necessary to complete a 5- to 7-membered ring with the lithium cation;

each A represents hydrogen or a substituent and each B represents hydrogen or an independently selected substituent on the Z atoms, provided that two or more substituents may combine to form a fused ring or a fused ring system; and

j is 0-3 and k is 1 or 2; and

m and n are independently selected integers selected to provide a neutral charge on the complex.

3. A method of emitting light comprising applying an electric potential across the device of claim 1 .

4. A display comprising the device of claim 1 .

5. The OLED device of claim 1 wherein the non-luminescent electron transporting layer contains a polyaromatic hydrocarbon as an additional electron transporting material.

6. The OLED device of claim 5 wherein the non-luminescent electron transporting layer contains an anthracene derivative according to formula (P) as an additional electron transporting material:

wherein R 1 -R 10 are independently chosen from hydrogen, alkyl groups from 1-24 carbon atoms or aromatic groups from 1-24 carbon atoms.

7. An OLED device comprising a cathode, an anode, and having therebetween a light emitting layer,

(a) comprising, between the cathode and the light emitting layer, a non-luminescent electron transporting layer containing a compound with a 7,10-diaryl-fluoranthene nucleus having no aromatic rings annulated to the nucleus; and

(b) comprising still further an additional layer, containing an organic alkali metal compound, located between the cathode and the electron transporting layer,

wherein the fluoranthene compound has the following Formula (IIIa) or (IIIb):

R 2 and R 4 are independently hydrogen or an aromatic group containing 6 to 24 carbon atoms with the proviso that R 2 and R 4 cannot both be hydrogen nor can R 2 be joined with R to form a ring;

R is hydrogen or an optional substituent; and

n and m are independently 1-5.

8. The OLED device of claim 7 wherein the non-luminescent electron transporting layer comprises an additional electron transporting material and the additional electron transporting material is an anthracene derivative according to formula (P):

wherein

R 1 -R 10 are independently chosen from hydrogen, alkyl groups from 1-24 carbon atoms or aromatic groups from 1-24 carbon atoms.

9. The OLED device of claim 7 wherein the non-luminescent electron transporting layer contains at least one additional organic lithium material according to Formula (V):

wherein:

Z and the dashed arc represent two to four atoms and the bonds necessary to complete a 5- to 7-membered ring with the lithium cation;

each A represents hydrogen or a substituent and each B represents hydrogen or an independently selected substituent on the Z atoms, provided that two or more substituents may combine to form a fused ring or a fused ring system; and

j is 0-3 and k is 1 or 2; and

m and n are independently selected integers selected to provide a neutral charge on the complex.

10. An OLED device of claim 7 wherein the organic alkali metal compound is an organic lithium compound.

11. An OLED device of claim 10 wherein the organic lithium compound is according to Formula (IV):

(Li + ) m (Q) n   Formula (IV)

wherein:

Q is an anionic organic ligand; and

m and n are independently selected integers selected to provide a neutral charge on the complex.

12. An OLED device of claim 10 wherein the organic lithium compound is according to Formula (V):

wherein:

Z and the dashed arc represent two to four atoms and the bonds necessary to complete a 5- to 7-membered ring with the lithium cation;

each A represents hydrogen or a substituent and each B represents hydrogen or an independently selected substituent on the Z atoms, provided that two or more substituents may combine to form a fused ring or a fused ring system; and

j is 0-3 and k is 1 or 2; and

m and n are independently selected integers selected to provide a neutral charge on the complex.

13. The OLED device of claim 12 wherein the A and B substituents of Formula (V) together form an additional ring system.

14. The OLED device of claim 13 wherein the ring formed between the A and B substituents contains at least one heteroatom in addition to the nitrogen that is attached to A.

15. The OLED device of claim 12 where the organic lithium compound is chosen from the group consisting of:

16. An OLED device comprising a cathode, an anode, and having therebetween a light emitting layer,

(a) comprising, between the cathode and the light emitting layer, a non-luminescent electron transporting layer containing a compound with a 7,10-diaryl substituted fluoranthene nucleus having no aromatic rings annulated to the fluoranthene nucleus; and

(b) comprising further an additional layer, containing a phenanthroline compound and an alkali or alkaline earth metal, located between the cathode and the electron transporting layer,

wherein the fluoranthene compound has the following Formula (IIIa) or (IIIb):

R 2 and R 4 are independently hydrogen or an aromatic group containing 6 to 24 carbon atoms with the proviso that R 2 and R 4 cannot both be hydrogen nor can R 2 be joined with R to form a ring:,

R is hydrogen or an optional substituent; and

n and m are independently 1-5.

17. The device of claim 16 wherein the metal is lithium.

18. An OLED device of claim 16 wherein the phenanthroline compound is according to formula (R):

wherein

R 1 -R 8 are independently hydrogen, alkyl group, aryl or substituted aryl group, and at least one of R 1 -R 8 is aryl group or substituted aryl group.