Thermoplastic compositions, method of manufacture, and articles therefrom
View Patent ↗A thermoplastic composition comprising, based on the total weight of the thermoplastic composition, from 0.1 to 30 weight percent of an inorganic filler composition comprising an inorganic filler-polyorganosiloxane composite; up to 80 weight percent of a polycarbonate; and from 1 to 25 weight percent of an impact modifier. Methods of preparing the compositions and articles comprising the compositions are described.
1. A thermoplastic composition comprising, based on the total weight of the thermoplastic composition,
from 0.1 to 30 weight percent of an inorganic filler composition comprising
an inorganic filler-polyorganosiloxane composite formed by treating an inorganic filler with a liquid, reactive polyorganosiloxane having a terminal silanol group and a molecular weight of 100 to 5,000, in an amount from 0.1 to 25 weight percent of the polyorganosiloxane, based on the total weight of the filler and the polyorganosiloxane, and
an optional inorganic filler;
up to 80 weight percent of a polycarbonate; and
from 1 to 25 weight percent of an impact modifier.
2. The thermoplastic composition of claim 1 , wherein the inorganic filler prior to treatment contains reactive surface hydroxyl groups.
3. The thermoplastic composition of claim 1 , wherein the inorganic filler comprises talc, mica, clay, or a combination comprising at least one of the foregoing inorganic fillers.
4. The thermoplastic composition of claim 3 , wherein the inorganic filler is talc.
5. The thermoplastic composition of claim 1 , wherein the reactive polyorganosiloxane has the formula
wherein F has an average value of 5 to 50; each R 7 is independently a C 1-13 monovalent organic group or a C 1-13 divalent organic group comprising a group reactive with the inorganic filler, and each R 8 is independently a C 1-13 monovalent organic group, a C 1-13 divalent organic group comprising a group reactive with the inorganic filler, or a group reactive with the inorganic filler, provided that at least one R 8 is a hydroxyl group.
6. The thermoplastic composition of claim 5 , wherein
each R 7 is independently a C 1 -C 13 alkyl, C 1 -C 13 alkoxy, C 2 -C 13 alkenyl, C 2 -C 13 alkenyloxy, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkoxy, C 6 -C 10 aryl, C 6 -C 10 aryloxy, C 7 -C 13 aralkyl, C 7 -C 13 aralkoxy, C 7 -C 13 alkaryl, or C 7 -C 13 alkaryloxy group, and
each R 8 is independently a primary amino group, secondary amino group, carboxylic acid group, sulfhydryl group, hydroxy group, or a C 1 -C 13 alkylene, C 2 -C 13 alkenylene, C 6 -C 10 arylene, C 7 -C 13 arylalkylene, or a C 7 -C 13 alkylarylene comprising a primary amino group, secondary amino group, carboxylic acid group, sulfhydryl group, or a hydroxy groups, provided that at least one R 8 is a hydroxyl group.
7. The thermoplastic composition of claim 1 , wherein the reactive polyorganosiloxane is a silanol-terminated poly(trifluoropropylmethylsiloxane), a silanol-terminated poly(dimethylsiloxane), a silanol-terminated poly(diphenylsiloxane-dimethylsiloxane) copolymer, or a combination comprising at least one of the foregoing siloxanes.
8. The thermoplastic composition of claim 1 , further comprising an acid present in a weight ratio of acid to total filler of 0.01:1 to 0.1:1.
9. The thermoplastic composition of claim 1 , wherein the composition retains 90% or more of its initial weight average molecular weight after extrusion and molding.
10. The thermoplastic composition of claim 1 , wherein a 3.2 mm thick bar comprising the composition has a Notched Izod impact of greater than or equal to 50 kJ/m 2 , measured at 23° C. in accordance with ISO 180:2000.
11. The thermoplastic composition of claim 1 , wherein a 3.2 mm thick bar comprising the composition has a Notched Izod impact of greater than or equal to 15 kJ/m 2 , measured at −30° C. in accordance with ISO 180:2000.
12. The thermoplastic composition of claim 1 , wherein a sample comprising the composition has a Young's modulus of greater than 3.5 GPa.
13. The thermoplastic composition of claim 1 , having an MVR measured at 260° C., 5 kg, of greater than 8.0.
14. The thermoplastic composition of claim 1 , having a melt viscosity at 300° C./5000 sec −1 of less than 70 Pascal-seconds, measured in accordance with ISO 11443.
15. The thermoplastic composition of claim 1 , wherein a sample comprising the composition has 100% ductility in a multi-axial impact, measured at −30° C., in accordance with ISO 6603-2:2000.
16. A thermoplastic composition comprising, based on the total weight of the thermoplastic composition,
from 1 to 25 weight percent of an inorganic filler composition comprising
a talc-polyorganosiloxane composite derived by the treatment of talc with a liquid polyorganosiloxane of the formula
wherein F has an average value from 5 to 50, each R 7 is methyl, a mixture of methyl and trifluoropropyl, or a mixture of methyl and phenyl, and each R 8 is a hydroxyl group, and
an optional inorganic filler;
from 50 to 80 weight percent of a polycarbonate comprising units derived from bisphenol A;
from 1 to 15 weight percent of a methacrylate-butadiene-styrene impact modifier; and
from 1 to 15 weight percent of a styrene-acrylonitrile rigid copolymer.
17. The thermoplastic composition of claim 16 , wherein the inorganic acid is present in a weight ratio of acid to total filler of 0.001:1 to 0.1:1.
18. An article comprising the composition of claim 1 .
19. The thermoplastic composition of claim 16 , wherein the inorganic filler-polyorganosiloxane composite is formed by treating an inorganic filler with the liquid polyorganosiloxane having a molecular weight of 100 to 5,000, in an amount from 0.1 to 25 weight percent of the polyorganosiloxane, based on the total weight of the filler and the polyorganosiloxane.
20. The thermoplastic composition of claim 16 , wherein the composition retains 90% or more of its initial weight average molecular weight after extrusion and molding.
21. The thermoplastic composition of claim 16 , wherein a 3.2 mm thick bar comprising the composition has a Notched Izod impact of greater than or equal to 50 kJ/m 2 , measured at 23° C. in accordance with ISO 180:2000.
22. The thermoplastic composition of claim 16 , wherein a 3.2 mm thick bar comprising the composition has a Notched Izod impact of greater than or equal to 15 kJ/m 2 , measured at −30° C. in accordance with ISO 180:2000.
23. The thermoplastic composition of claim 16 , wherein a sample comprising the composition has a Young's modulus of greater than 3.5 GPa.
24. The thermoplastic composition of claim 16 , having an MVR measured at 260° C., 5 kg, of greater than 8.0.
25. The thermoplastic composition of claim 16 , having a melt viscosity at 300° C./5000 sec −1 of less than 70 Pascal-seconds, measured in accordance with ISO 11443.
26. The thermoplastic composition of claim 16 , wherein a sample comprising the composition has 100% ductility in a multi-axial impact, measured at −30° C., in accordance with ISO 6603-2:2000.
27. An article comprising the composition of claim 16 .