Process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst
View Patent ↗A process for treating a carrier, or a precursor thereof, to at least partly remove impurities comprising contacting the carrier, or the precursor thereof, with a treatment solution comprising a salt; a process for preparing a catalyst; the catalyst; a process for preparing an olefin oxide by reacting an olefin with oxygen in the presence of the catalyst; and a process for preparing a 1,2-diol, a 1,2-diol ether or an alkanolamine.
1. A process for treating a carrier, or a precursor thereof, to at least partly remove impurities from the carrier, or the precursor thereof, comprising:
contacting the carrier, or the precursor thereof, with a treatment solution consisting essentially of a salt in a concentration of at least 0.001 molar and less than 0.015molar at a temperature of greater than 40° C., wherein the salt comprises a cation selected from the group consisting of Group IIA metals, ammonium, phosphonium, organic cations and combinations thereof, and an anion selected from halides, organic anions, inorganic carboxylates, oxyanions of elements from Groups IIIB to VIIB, Group IIIA, and Groups VA to VIIA of the Periodic Table of Elements, cyanate, isocyanate, cyanide, and combinations thereof; and
separating at least part of the treatment solution from the carrier, or the precursor thereof.
2. The process as claimed in claim 1 , wherein the oxyanion is of elements from Group IIIA and Groups VA to VIIA of the Periodic Table of Elements.
3. The process as claimed in claim 1 , wherein the salt comprises one or more nitrate, nitrite or acetate anions.
4. The process as claimed in claim 1 , wherein the salt comprises a nitrate anion.
5. The process as claimed in claim 1 , wherein the concentration of the salt is less than 0.007 molar.
6. The process as claimed in claim 1 , wherein the concentration of the salt is at most 0.004 molar.
7. The process as claimed in claim 1 , wherein the concentration of the salt is at least 0.002 molar.
8. The process as claimed in claim 1 , wherein the concentration of the salt is from 0.001 to 0.006 molar.
9. The process as claimed in claim 1 , wherein the concentration of the salt is from 0.0015 to 0.0045 molar.
10. The process as claimed in claim 1 , wherein the concentration of the salt is from 0.002 to 0.004 molar.