Electrode and battery
View Patent ↗A battery realizing the superior cycle characteristics is provided. An electrode includes a current collector including an active-material-layer-formation region and a flat and smooth region having a surface roughness smaller than that of the active-material-layer-formation region, and an active material layer provided in the active-material-layer-formation region of the current collector. An electrode lead is connected to the flat and smooth region.
1. An electrode comprising:
a current collector including a surface comprising an active-material-layer-formation region and a flat and smooth region, the flat and smooth region of the surface having a surface roughness smaller than that of the active-material-layer-formation region of the surface; and
an active material layer provided in the active-material-layer-formation region of the surface; and
an electrode lead provided on the flat and smooth region having a surface roughness smaller than that of the active-material-layer-formation region of the surface,
wherein the active material layer contains silicon.
2. The electrode according to claim 1 , wherein the active-material-layer-formation region of the surface has a particulate projection.
3. The electrode according to claim 2 , wherein the particulate projection is formed by electrolytic deposition method.
4. The electrode according to claim 2 , wherein an average diameter of the particulate projection ranges from 50 nm to 5 μm.
5. The electrode according to claim 1 , wherein ten point height of roughness profile Rz in the active-material-layer-formation region of the surface is from 1.8 μm to 10.0 μm, and
ten point height of roughness profile Rz in the flat and smooth region of the surface is 1.7 μm or less.
6. The electrode according to claim 1 , wherein the electrode lead is made of a metal material containing nickel.
7. The electrode according to claim 1 , wherein the current collector contains copper or a copper alloy.
8. The electrode according to claim 1 , wherein the active material layer is formed on both faces of the current collector.
9. The electrode according to claim 1 , wherein the current collector and the active material layer are alloyed in at least part of an interface thereof.
10. The electrode according to claim 1 , wherein the active material layer contains a mixture of a conductive particle containing silicon and a binder.
11. The electrode according to claim 10 , wherein an average particle diameter of the conductive particle in the active material layer is from 0.5 μM to 5.0 μm.
12. The electrode according to claim 10 , wherein the active material layer contains at least one of a thermoplastic resin and a thermosetting resin as the binder.
13. The electrode according to claim 10 , wherein the active material layer contains a thermoplastic resin with hydrogen bonding and at least one thermosetting resin selected from the group consisting of an epoxy resin, a phenol resin, polyimide, polyurethane, a melamine resin, and a urea resin as the binder.
14. The electrode according to claim 1 , wherein the active material layer does not exist in the flat and smooth region of the surface.
15. The electrode according to claim 1 , wherein the electrode lead is formed of a metal material selected from the group consisting of aluminum, copper, nickel and stainless steel.
16. The electrode according to claim 1 , wherein the flat and smooth region of the surface includes a first projection, and the active-material-layer-formation region of the surface includes a second projection, and a height of the first projection is less than a height of the second projection.
17. A battery comprising a cathode, an anode, and an electrolyte,
wherein at least one of the cathode and the anode includes:
a current collector including a surface comprising an active-material-layer-formation region and a flat and smooth region, the flat and smooth region of the surface having a surface roughness smaller than that of the active-material-layer-formation region of the surface; and
an active material layer provided in the active-material-layer-formation region of the surface, and
an electrode lead provided on the flat and smooth region having a surface roughness smaller than that of the active-material-layer-formation region of the surface, and
wherein the active material layer contains silicon.
18. The battery according to claim 17 , wherein the active-material-layer-formation region of the surface has a particulate projection.
19. The battery according to claim 18 , wherein the particulate projection is formed by electrolytic deposition method.
20. The battery according to claim 17 , wherein ten point height of roughness profile Rz in the active-material-layer-formation region of the surface is from 1.8 μm to 10.0 μm, and
ten point height of roughness profile Rz in the flat and smooth region of the surface is 1.7 μm or less.
21. The battery according to claim 17 , wherein the electrode lead is made of a metal material containing nickel.
22. The battery according to claim 17 , wherein the current collector contains copper or a copper alloy.
23. The battery according to claim 17 , wherein the active material layer is formed on both faces of the current collector.
24. The battery according to claim 17 , wherein the current collector and the active material layer are alloyed in at least part of an interface thereof.
25. The battery according to claim 17 , wherein the active material layer contains a mixture of a conductive particle containing silicon and a binder.
26. The battery according to claim 25 , wherein an average particle diameter of the conductive particle in the active material layer is from 0.5 μm to 5.0 μm.
27. The battery according to claim 25 , wherein the active material layer contains at least one of a thermoplastic resin and a thermosetting resin as the binder.
28. The battery according to claim 25 , wherein the active material layer contains a thermoplastic resin with hydrogen bonding and at least one thermosetting resin selected from the group consisting of an epoxy resin, a phenol resin, polyimide, polyurethane, a melamine resin, and a urea resin as the binder.
29. The battery according to claim 17 , wherein the electrolyte contains a solvent containing at least one of chain ester carbonate and cyclic ester carbonate.
30. The battery according to claim 29 , wherein the chain ester carbonate includes at least one of fluoromethyl methyl carbonate, bis(fluoromethyl) carbonate, and difluoromethyl methyl carbonate, and
the cyclic ester carbonate contains at least one of 4-fluoro-1,3-dioxolane-2-one and 4,5-difluoro-1,3-dioxolane-2-one.
31. The battery according to claim 17 , wherein the active material layer does not exist in the flat and smooth region of the surface.
32. The battery according to claim 17 , wherein the electrode lead is formed of a metal material selected from the group consisting of aluminum, copper, nickel and stainless steel.