IP Library Granted Patent US 7,922,890
Granted Patent B2
US 7,922,890 · App. 11/946,772 · Granted Apr 12, 2011

Low maintenance on-site generator

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Quick Facts
Patent No.
US 7,922,890
App. No.
11/946,772
Granted
Apr 12, 2011
Kind
B2
Abstract

Method and apparatus for a low maintenance, high reliability on-site electrolytic generator incorporating automatic cell monitoring for contaminant film buildup, as well as automatically removing or cleaning the contaminant film. This method and apparatus preferably does not require human intervention to clean.

Claims (40)

1. A method for operating an electrolytic cell, the method comprising the steps of:

supplying brine to an electrolytic cell;

producing one or more oxidants in the electrolytic cell;

automatically cleaning the electrolytic cell, thereby reducing contaminants in the electrolytic cell; and

subsequently automatically continuing to produce the one or more oxidants.

2. The method of claim 1 wherein the cleaning step comprises:

providing brine to an acid generating electrolytic cell;

generating an acid in the acid generating electrolytic cell; and

introducing the acid from the acid generating electrolytic cell into the electrolytic cell.

3. The method of claim 2 wherein the acid comprises muriatic acid or hydrochloric acid.

4. The method of claim 1 further comprising the step of diluting the brine.

5. The method of claim 1 wherein the detecting step comprises utilizing a carbonate detector.

6. The method of claim 1 wherein the detecting step comprises measuring a rate of brine consumption in the electrolytic cell.

7. The method of claim 6 comprising measuring a quantity selected from the group consisting of flow meter output, temperature of the electrolytic cell, brine pump velocity, and incoming water flow rate.

8. The method of claim 6 further comprising comparing the rate of brine consumption to a rate of brine consumption in a clean electrolytic cell.

9. The method of claim 1 wherein the cleaning step comprises using an ultrasonic device and/or using a magnetically actuated mechanical electrode cleaning device.

10. The method of claim 1 wherein the cleaning step comprises reversing a polarity of electrodes in the electrolytic cell, thereby lowering the pH at a cathode.

11. The method of claim 1 further comprising:

detecting a level of contaminant buildup; and

automatically stopping the brine supply after an upper contaminant threshold is detected.

12. The method of claim 11 wherein the step of subsequently automatically continuing to produce the one or more oxidants is performed after a lower contaminant threshold is detected.

13. The method of claim 1 wherein the cleaning step is performed periodically.

14. An apparatus for producing an oxidant, the apparatus comprising:

a brine supply;

an electrolytic cell;

an acid supply; and

a control system for automatically introducing acid from said acid supply into said electrolytic cell, thereby cleaning said electrolytic cell.

15. The apparatus of claim 14 wherein said acid supply comprises a second electrolytic cell.

16. The apparatus of claim 15 wherein said brine supply provides brine to said second electrolytic cell during a cleaning cycle.

17. The apparatus of claim 14 further comprising a variable speed brine pump.

18. The apparatus of claim 14 further comprising a carbonate detector.

19. The apparatus of claim 14 further comprising one or more thermowells for measuring a temperature of said electrolytic cell.

20. The apparatus of claim 14 further comprising one or more flowmeters for measuring a brine flow rate.

21. An apparatus for producing an oxidant, the apparatus comprising:

a brine supply;

an electrolytic cell;

a cleaning mechanism in said electrolytic cell; and

a control system for automatically activating said cleaning mechanism.

22. The apparatus of claim 21 wherein said cleaning mechanism is selected from the group consisting of ultrasonic horn, magnetically actuated electrode mechanical cleaning device, and acidic solution at a cathode surface.

23. The apparatus of claim 21 further comprising a device selected from the group consisting of a carbonate detector, at least one thermowell for measuring a temperature of said electrolytic cell, and a flowmeter for measuring a brine flow rate.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 9, 2019
From: JOHNSON MATTHEY PLC
To: DE NORA HOLDINGS US, INC
Reel/Frame 049701/0768 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 14, 2017
From: MIOX CORPORATION
To: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
Reel/Frame 041255/0674 →
RELEASE OF SECURITY INTEREST Recorded Apr 1, 2016
From: UNION BAY CAPTIAL PARTNERS I, LLC
To: MIOX CORPORATION
Reel/Frame 038176/0968 →
SECURITY INTEREST Recorded Dec 31, 2014
From: MIOX CORPORATION
To: UNION BAY CAPTIAL PARTNERS I, LLC
Reel/Frame 034609/0287 →