Rare earth element-iron-boron alloy, and magnetically anisotropic permanent magnet powder and method for production thereof
View Patent ↗A method of making a magnetically anisotropic magnet powder according to the present invention includes the steps of preparing a master alloy by cooling a rare-earth-iron-boron based molten alloy and subjecting the master alloy to an HDDR process. The step of preparing the master alloy includes the step of forming a solidified alloy layer, including a plurality of R 2 Fe 14 B-type crystals (where R is at least one element selected from the group consisting of the rare-earth elements and yttrium) in which rare-earth-rich phases are dispersed, by cooling the molten alloy through contact with a cooling member.
1. A rare-earth-iron-boron based alloy comprising: a first texture layer having gaps; and a second texture layer on the first texture layer,
wherein the first texture layer accounts for less than 10 vol % of the overall alloy, the first texture layer consisting essentially of R 2 Fe 14 B crystals (where R is at least one element selected from the group consisting of the rare-earth elements and yttrium) with an average minor-axis size of less than 20 μm,
wherein the second texture layer comprises columnar R 2 Fe 14 B crystals, the columnar R 2 Fe 14 B crystals having an average minor-axis size of 20 μm to 110 μm, and
wherein rare-earth-rich phases are dispersed at an average interval of 50 μm or less in the columnar R 2 Fe 14 B crystals of the second texture layer.
2. The rare-earth-iron-boron based alloy of claim 1 , wherein an α-Fe phase concentration of the alloy is 5 vol % or less.
3. The rare-earth-iron-boron based alloy of claim 1 , wherein the rare-earth element has a concentration of 26 mass % to 32 mass %.
4. The rare-earth-iron-boron based alloy of claim 1 , wherein a Ga concentration of the alloy is 0.6 mass % or less.
5. A powder of the rare-earth-iron-boron based alloy of claim 1 , the powder having a mean particle size of 10 μm to 300 μm,
wherein the concentration of rare-earth elements in powder particles with sizes of 50 μm or less is not higher than that of rare-earth elements in powder particles of which the sizes exceed 50 μm.
6. The powder of claim 5 , wherein the powder is decrepitated by a hydrogen process.
7. A magnetically anisotropic rare-earth-iron-boron based alloy magnet powder including a rare-earth element at a concentration of 26 mass % to 32 mass %, an α-Fe phase at 5 vol % or less, and Ga at a concentration of 0.6 mass % or less, and wherein the magnetically anisotropic rare-earth-iron-boron based alloy magnet powder includes a fine texture produced by applying an HDDR process to the powder of claim 5 .
8. An anisotropic bonded magnet including the magnetically anisotropic rare-earth-iron-boron based alloy magnet powder of claim 7 .
9. A motor including the anisotropic bonded magnet of claim 8 .