Method for treatment of process waters using steam
View Patent ↗Systems and methods for treating water. Water containing one or more thermally destructible contaminants can be contacted with steam to provide an effluent containing essentially contaminant-free water and a recycle containing the steam and at least a portion of the one or more thermally destructible contaminants. The one or more thermally destructible contaminants in the recycle can be thermally destroyed using one or more combustion processes.
1. A method for treating water, comprising:
steam stripping a first effluent comprising water, one or more thermally destructible contaminants, and one or more thermally indestructible contaminants with a first steam supply to provide a second effluent comprising steam and at least a portion of the one or more thermally indestructible contaminants and an intermediate comprising the water and at least a portion of the one or more thermally destructible contaminants;
treating the second effluent within an acid recovery unit;
steam stripping the intermediate with a second steam supply to provide a third effluent comprising steam and at least a portion of the one or more thermally destructible contaminants and a fourth effluent comprising water; and
destructing the thermally destructible contaminants in the third effluent using one or more combustion processes.
2. The method of claim 1 , wherein the combustion process is a hydrocarbon gasification process.
3. The method of claim 1 , wherein the pressure of the first steam supply is about 200 kPa to about 1,500 kPa.
4. The method of claim 1 , wherein the pressure of the second steam supply is about 400 kPa to about 4,000 kPa.
5. The method of claim 1 , wherein the acid recovery process is an acid gas unit within a hydrocarbon gasification unit.
6. The method of claim 1 , wherein the first effluent comprises a mixture of a hydrocarbon gasification process condensate and a hydrocarbon gasification process contact cooling water.
7. The method of claim 1 , wherein a weight ratio of the first steam supply to the first effluent ranges from about 1:1 to about 20:1.
8. The method of claim 1 , wherein a weight ratio of the second steam supply to the intermediate ranges from about 1:1 to about 20:1.
9. The method of claim 1 , further comprising:
gasifying a feedstock comprising a polymer and coal to produce a raw syngas comprising the one or more thermally destructible contaminants, wherein the polymer comprises polyethylene, polypropylene, polystyrene, polyethylene terephthalate (PET., or any combination thereof, and
cooling the raw syngas by directly contacting the raw syngas with water to provide a cooled syngas and the first effluent.
10. The method of claim 1 , wherein the thermally indestructible contaminants comprise hydrogen sulfide, hydrogen chloride, carbonyl sulfide, or any combination thereof.
11. The method of claim 1 , wherein the thermally destructible contaminants comprise ammonia, and wherein the first effluent has an ammonia concentration of about 500 ppm to about 3 wt %.
12. The method of claim 1 , wherein the thermally indestructible contaminants comprise hydrogen sulfide, hydrogen chloride, carbonyl sulfide, or any combination thereof, wherein the thermally destructible contaminants comprise ammonia, wherein the first effluent has a concentration of thermally indestructible contaminants ranging from about 500 ppm to about 9 wt % and a concentration of thermally destructible contaminants ranging from about 500 ppm to about 3 wt %, and wherein the fourth. effluent has an ammonia concentration ranging from about 0.1 ppmw to about 50 ppmw.
13. A method for treating water, comprising:
gasifying a hydrocarbon using one or more gasifiers to provide a raw syngas comprising one or more thermally destructible contaminants and one or more thermally indestructible contaminants at an elevated temperature;
cooling the raw syngas using contact and non-contact cooling to provide a cooled syngas and a first effluent comprising water, one or more thermally indestructible contaminants, and one or more thermally destructible contaminants;
steam stripping the first effluent with a first steam supply to provide a second effluent comprising steam and at least a portion of the one or more thermally indestructible contaminants and an intermediate comprising the water and at least a portion of the one or more thermally destructible contaminants;
treating the second effluent using an acid recovery process;
steam stripping the intermediate with second supply to provide a third effluent comprising steam and at least a portion of the one or more thermally destructible contaminants and a fourth effluent comprising essentially contaminant-free water;
destructing the thermally destructible contaminants in the third cent using one or more combustion processes; and
treating the fourth effluent for reuse.
14. The method of claim 13 , further comprising:
combusting at least a portion of the cooled syngas to provide an exhaust gas; and
cooling the exhaust gas to provide the heat necessary to provide at least a portion of the first steam supply.
15. The method of claim 13 , wherein a weight ratio of the second steam supply to the intermediate ranges from about 1:1 to about 20:1.
16. The method of claim 13 , wherein a weight ratio of the first steam supply to the first effluent from about 1:1 to about 20:1.
17. The method of claim 13 , wherein the acid recovery process is an acid gas unit in a hydrocarbon gasification system.
18. The method of claim 13 , wherein the second steam supply pressure ranges from about 400 kPa to about 4,000 kPa.
19. The method of claim 13 , wherein the first steam supply pressure ranges from about 200 kPa to about 1,500 kPa.
20. The method of claim 13 , wherein the hydrocarbon comprises polyethylene, polypropylene, polystyrene, polyethylene terephthalate (PET), or any combination thereof.