Redispersible powder and its aqueous dispersion, preparation, process and use
View Patent ↗The invention relates to a redispersible powder obtainable by (co)polymerization, using a polymer with cationic functionality in an aqueous medium, optionally accompanied by the use of conventional additives, the polymer with cationic functionality being obtained by (co)polymerization in an aqueous medium of olefinically unsaturated (co)monomers, wherein at least one (co)monomer has a cationic functionality, further (co)monomers are added and polymerization takes place in the presence of suitable initiators, and by drying the aqueous dispersion obtained, the (co)polymerizate having one or more reactive groups. According to another embodiment, the polymer with cationic functionality is formed in situ in the presence of a seed. According to another embodiment, the process is controlled in such a way that a (co)polymerizate particle with heterogeneous morphology is formed. The invention also relates to the aqueous dispersions, a process for the preparation of the redispersible powder and the use thereof.
1. Process for preparing film-forming, redispersible polymer powder comprising the steps of:
polymerizing an aqueous medium of olefinically unsaturated monomers, the olefinically unsaturated monomers having at least one monomer with cationic functionality and at least one monomer with one or more reactive groups or at least one monomer with cationic functionality and one or more reactive groups, thereby obtaining at least one polymer with cationic functionality and one or more reactive groups,
polymerizing at least one comonomer with at least one initiator in an aqueous medium in the presence of the at least one polymer with cationic functionality and one or more reactive groups to form an aqueous polymer dispersion having particles with heterogeneous morphology and at least one polymer phase with a glass transition temperature below +50° C., and
drying the aqueous dispersion to obtain the redispersible polymer powder.
2. Process according to claim 1 wherein the olefinically unsaturated monomers further comprise at least one monomer with at least anionic functionality.
3. Process according to claim 1 wherein the at least one polymer with cationic functionality is polymerized in situ in the presence of a seed monomer.
4. Process according to claim 1 wherein the polymer powder comprises latex particles having core-shell morphology.
5. Process according to claim 4 wherein the latex particles have an average diameter of from 30 to 1000 nm.
6. Process according to claim 1 wherein the one or more reactive groups are chosen from hydroxyl, carboxyl, carboxyl ester, amino, ammonium, amide, silane, epoxide, carbonyl, formamide, acetamide, succinimide, epihalohydrin and mixtures thereof.
7. Process according to claim 1 wherein the at least one monomer with cationic functionality comprises 1 to 30 percent by weight of total monomer weight of the redispersible polymer powder.
8. Process according to claim 1 wherein the at least one polymer with cationic functionality is formed from 10 to 100 percent by weight of monomers having at least one reactive group.
9. Process according to claim 1 wherein the at least one monomer with cationic functionality comprises a quaternary ammonium group.
10. Process according to claim 1 further comprising adding the redispersible polymer powders to an aqueous medium forming an aqueous redispersion.
11. Process according to claim 1 wherein the reactive groups are activated by changing the pH of the aqueous dispersion.
12. Process according to claim 1 wherein the reactive groups comprise at least one protonated group able to be deprotonated by changing the pH of the aqueous dispersion.
13. Process according to claim 1 wherein the aqueous dispersion comprises less than 2.5% by weight of emulsifier.
14. Process according to claim 11 wherein the aqueous dispersion is free of emulsifier.
15. Process according to claim 1 wherein drying is by spray or freeze drying.