Metallic nanowire networks
View Patent ↗A metallic nanowire network synthesized using chemical reduction of a metal ion source by a reducing agent in the presence of a soft template comprising a tubular inverse micellar network. The network of interconnected polycrystalline nanowires has a very high surface-area/volume ratio, which makes it highly suitable for use in catalytic applications.
1. A metal nanowire network comprising:
a plurality of metal nanowire segments interconnected at nodes and having a shape that replicates a shape of an aqueous channel network of at least one of a micellar bicontinuous phase and a tubular inverse micelle, wherein the metal nanowire network is formed by the process of:
combining a surfactant, an organic solvent, and an aqueous solution of an ionic metal reactant;
forming a plurality of interconnecting aqueous channels in a network of at least one of swollen tubular inverse micelles and a micellar bicontinuous phase in an emulsion comprising the surfactant, the organic solvent, and water;
extracting the ionic metal reactant into the plurality of interconnecting aqueous channels; and
reducing the ionic metal reactant to an elemental metal within the plurality of aqueous channels, thereby forming a metal nanowire network.
2. The metal nanowire network of claim 1 , wherein the plurality of nanowire segments have a substantially uniform diameter.
3. The metal nanowire network of claim 2 , wherein the substantially uniform diameter is between approximately 1 nm and approximately 10 nm.
4. The metal nanowire network of claim 1 , wherein the metal nanowire network has a surface-to-volume ratio greater than approximately 1×10 8 /m.
5. The metal nanowire network of claim 1 , wherein a metal comprising the metal nanowire network is selected from the group consisting of Pt and Pd.
6. The metal nanowire network of claim 1 , wherein the metal nanowire network comprises polycrystalline metal.
7. The metal nanowire network of claim 1 , wherein the network of swollen tubular inverse micelles is a worm-like swollen tubular inverse micelle network.
8. A method for making a metal nanowire network, the method comprising:
combining a surfactant, an organic solvent, and an aqueous solution of an ionic metal reactant;
forming a plurality of interconnecting aqueous channels in a network of swollen tubular inverse micelles in an emulsion comprising the surfactant, the organic solvent, and water;
extracting the ionic metal reactant into the plurality of interconnecting aqueous channels; and
reducing the ionic metal reactant to an elemental metal within the plurality of aqueous channels, thereby forming a nanowire network comprising, a plurality of metal nanowire segments interconnected at nodes and having a shape that replicates a shape of an aqueous channel network of at least one of a micellar bicontinuous phase and a tubular inverse micelle.
9. The method of claim 8 , wherein the ionic metal reactant and headgroups of the surfactant have electrical charges of opposite sign.
10. The method of claim 8 , wherein the ionic metal reactant is derived from an ionic metal source species selected from the group consisting of H 2 PtCl 4 , H 2 PtCl 6 , H 2 PdCl 4 , H 2 PdCl 6 , salts of PtCl 4 2− , salts of PtCl 6 2− , salts of PdCl 4 2− , and salts of PdCl 6 2− .
11. The method of claim 8 , wherein the step of reducing employs a hydride reducing agent.
12. The method of claim 11 , wherein the hydride reducing agent is selected from the group consisting of NaBH 4 , LiBH 4 , LiAlH 4 , KBH 4 , NaH, KH, and CaH 2 .
13. The method of claim 8 , wherein the organic solvent is selected from the group consisting of chloroform, dichloromethane, chlorobenzene, carbon tetrachloride, an alkane that is liquid between approximately 0 and approximately 100° C. and between approximately 1 and approximately 10 atmospheres pressure, an alkene that is liquid between 0 and 100° C. and between 1 and 10 atmospheres pressure, toluene, benzene, and miscible mixtures thereof.
14. The method of claim 8 , wherein the surfactant comprises a cation of formula R 1 R 2 R 3 R 4 N + , wherein R 1 , R 2 , R 3 , and R 4 are alkyl groups wherein at least one of R 1 , R 2 , R 3 , and R 4 is an alkyl group comprising from 8 carbon atoms up to 18 carbon atoms, and wherein R 1 , R 2 , R 3 , and R 4 are selected from the group consisting of linear alkyl groups, branched alkyl groups, and cyclic alkyl groups.
15. The method of claim 8 , wherein the surfactant comprises a cation selected from the group consisting of cetyltrimethylammonium ion, (1-octyl)trimethylammonium ion, (1-decyl)trimethylammonium ion, dodecyltrimethylammonium ion, tetradecyltrimethylammonium ion, and octadecyltrimethylammonium ion.
16. The method of claim 8 , wherein the organic solvent is chloroform, the surfactant is cetyltrimethylammonium bromide, the ionic metal reactant is selected from the group consisting of PtCl 4 2− and PdCl 4 2− , and wherein the metal ionic reactant is reduced by sodium borohydride.