Separating gas using ion exchange
View Patent ↗Carbon dioxide can be separated from gas streams using ion exchange, such as in an electrochemical cell. An anion exchange membrane can be configured to increase the efficiency of the system and to permit the flow of the carbon-containing ions within the system while reducing diffusion of protons and/or hydroxyl ions. A gas stream containing carbon dioxide can be introduced to the system on the cathode side, while a source of hydrogen-containing molecules can be introduced on the anode side. Operation of the system can separate the carbon dioxide from the gas stream and provide it at a separate outlet.
1. A system to separate carbon dioxide from a gas comprising:
a cathodic component and an anodic component with a region between them and structured such that, with oxygen and carbon dioxide at the cathodic component and hydrogen-containing molecules that can provide protons at the anodic component, reactions occur producing carbon-containing ions; the carbon-containing ions transporting from the cathodic component to the anodic component and reacting at the anodic component to form carbon dioxide; and
an ion exchange component comprising one or more ion exchange sites between the cathodic component and the anodic component, the ion exchange component comprising a polymer having at least one fixed charge, and at least one functional group chosen from at least one weak Lewis base capable of forming hydrogen bonds with hydroxyl ions,
the ion exchange sites being configured to permit transport of the carbon-containing ions between the cathodic component and the anodic component,
wherein the at least one fixed charge is sufficient to exclude or block ions of the same charge.
2. The system of claim 1 , wherein the ion exchange component includes one or more of an ion exchange membrane and an ion exchange polymer.
3. The system of claim 1 , wherein the ion exchange component comprises an anion exchange polymer.
4. The system of claim 3 , wherein the anion exchange polymer includes one or more primary, secondary, or tertiary coordinated amine group.
5. The system of claim 1 , further comprising an electrochemical cell, wherein the reactions produce a pH gradient between the cathodic component and the anodic component and the pH gradient has a natural decay rate.
6. The system of claim 5 , wherein the electrochemical cell includes a layered structure, the anodic and cathodic component are on opposite sides of the layered structure, and the membrane component is between the anodic and cathodic components.
7. The system of claim 6 , wherein the ion exchange component includes:
a membrane with first and second opposing sides;
first and second catalyst layers on the first and second opposing sides, respectively;
first and second gas diffusion layers over the first and second catalyst layers, respectively, each gas diffusion layer permitting gas diffusion to the catalyst; and
first and second porous conductor layers disposed over the first and second gas diffusion layers, respectively, the first and second porous conductor layers being electrically connectable to a load.
8. The system of claim 7 , wherein:
the membrane is an anion exchange membrane that includes coordinated amine groups;
the first and second catalyst layers are formed of platinum;
the first and second gas diffusion layers are formed of carbon paper infused with polytetrafluoroethylene; and
the first and second porous conductor layers are formed of wire mesh.
9. The system of claim 1 , wherein:
the ion exchange component comprises:
a membrane that includes:
a permeable support layer with first and second opposing surfaces and
one or more ion exchange sites within the support layer;
the anodic component includes a first catalyst layer on the first opposing surface and a first electrically conductive structure over the first catalyst layer; and
the cathodic component includes a second catalyst layer on the second opposing surface and a second electrically conductive surface over the second catalyst layer, each electrically conductive structure being electrically connectable to a load and permitting gas diffusion to the catalyst layers.
10. The system of claim 9 , further comprising circuitry to connect the first and second electrically conductive structures to the load.
11. The system of claim 9 , wherein the first catalyst layer and the first electrically conductive structure comprise an anodic component and the second catalyst layer and the second electrically conductive structure comprise a cathodic component.
12. The system of claim 10 further comprising an enclosure within which the membrane is sealed.
13. The system of claim 12 , and further comprising:
a source of gas containing a first amount of carbon dioxide and an outlet for gas containing an amount of carbon dioxide lower than the first amount near the cathodic component; and
a source of hydrogen gas and an outlet for carbon dioxide and unused hydrogen gas near the anodic component.
14. The system of claim 9 , wherein the support layer comprises a styrene/divinylbenzene copolymer matrix with benzyl trimethylammonium functional groups.
15. A method of separating carbon dioxide from a gas using the system of claim 1 , the method comprising:
reacting the gas at the cathodic component to form the carbon-containing ions;
transporting the carbon-containing ions through the ion exchange component that includes the ion exchange sites between the cathodic component and the anodic component; and
reacting the carbon-containing ions at the anodic component to form the carbon dioxide;
wherein the at least one fixed charge excludes or blocks transport of protons between the anodic component and the cathodic component, and the at least one functional group forms hydrogen bonds with hydroxyl ions transported between the cathodic component and the anodic component.
16. The method of claim 15 , further comprising reacting oxygen at the cathode and hydrogen-containing molecules that can provide protons at the anodic component, which reactions produce a pH gradient.
17. The method of claim 15 , wherein reacting the gas comprises reacting the gas with hydroxyl ions or water to produce the carbon-containing ions.
18. The method of claim 17 , wherein the reaction of the gas that includes carbon dioxide occurs on a first side of a membrane and the reaction of the carbon-containing ions occurs on a second side of a membrane; the method further comprising supplying oxygen gas to the first side of the membrane and hydrogen gas to the second side of the membrane.
19. The method of claim 17 , wherein the at least one fixed charge excludes or blocks transport of protons, and the at least one functional group forms hydrogen bonds with hydroxyl ions.