IP Library Granted Patent US 8,156,725
Granted Patent B2
US 8,156,725 · App. 11/962,959 · Granted Apr 17, 2012

CO

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Quick Facts
Patent No.
US 8,156,725
App. No.
11/962,959
Granted
Apr 17, 2012
Kind
B2
Abstract

A compressed air energy storage system and method of capturing CO 2 during compressed air energy storage the system and method including a gas inlet pipe, at least one air compressor stage attached to the gas inlet pipe and adapted for compression of a gas, a heat transfer system to cool the gas during or after compression, the heat being recycled throughout the system, at least one absorption bed for separating CO 2 from the compressed gas attached to the heat transfer system, at least one compressed gas reservoir having an inlet and an outlet, the reservoir attached at its inlet to the absorption bed, at least one preheater stage attached to the outlet of the compressed gas reservoir for heating a compressed gas after storage in the compressed gas reservoir, and at least one gas expander attached to the preheater stage and adapted for the expansion of the compressed gas.

Claims (35)

1. A compressed air energy storage system comprising: a gas inlet pipe;

at least one air compressor stage attached to and located downstream from the gas inlet pipe, the at least one air compressor stage being adapted for compression of a gas;

a heat transfer system linked to and located downstream from the at least one air compressor stage;

at least one absorption bed linked to and located directly downstream from the heat transfer system;

at least one compressed gas reservoir having an inlet and an outlet, the inlet of the compressed gas reservoir being attached to an outlet of the absorption bed;

at least one preheater that is attached to the outlet of the compressed gas reservoir, the at least one preheater adapted to heat a compressed gas before expansion but after storage in the compressed gas reservoir; and

at least one gas expander that is linked to and located directly downstream from the at least one preheater and is adapted for the expansion of the compressed gas,

wherein the heat transfer system being adapted (1) to remove at least a portion of heat from the gas during or after compression and (2) to recycle at least a portion of the removed heat to heat the at least one absorption bed, and/or to preheat a compressed gas prior to expansion with the removed heat, and/or to heat the expanded gas after each stage of expansion with the removed heat.

2. The compressed air energy system according to claim 1 , wherein the gas inlet pipe is attached to the exhaust stream of an oil fired power plant or a coal fired power plant or a gas turbine power plant.

3. The compressed air energy system according to claim 1 , further comprising a gas storage tank, wherein the gas storage tank is attached to the gas inlet pipe.

4. The compressed air energy system according to claim 1 , further comprising a dryer, wherein the inlet of the dryer is attached to and located directly downstream from the outlet of the at least one air compressor stage and the outlet of the dryer is attached to and located directly upstream from the heat transfer system, wherein the dryer contains a desiccant selected from the group consisting of activated alumina, silica gel and molecular sieve zeolites.

5. The compressed air energy storage system of claim 1 , wherein the heat transfer system comprises at least one heat exchanger that cools the gas during compression and heats the gas during expansion.

6. The compressed air energy system according to claim 1 , wherein the heat transfer system further comprises:

at least one heat accumulator for storing heat removed from the compressed gas.

7. The compressed air energy system according to claim 1 , wherein the at least one absorption bed is a pressure swing absorption bed, a temperature swing absorption bed, or a pressure and temperature swing absorption bed.

8. The compressed air energy system according to claim 1 , wherein the at least one absorption bed contains a CO 2 absorbent selected from the group consisting of monoethanolamine, diethanolamine, methyl-diethanolamine, zeolites, molecular sieves and metal-organic frameworks.

9. The compressed air energy system according to claim 1 , further comprising a storage reservoir or processing apparatus linked to and located directly downstream from the at least one absorption bed for the component absorbed from the gas.

10. The compressed air energy system according to claim 1 , wherein the compressed gas reservoir is selected from a group consisting of a cavern, a cave, an aquifer, a mine, and other geologic formations.

11. The compressed air energy system according to claim 1 , wherein the gas expander comprises a turbine.

12. The compressed air energy system according to claim 11 , wherein the at least one preheater comprises:

at least one heat exchanger for heating the compressed gas prior to entering the turbine, and for using the expanded gas to cool the at least one absorption bed.

13. A method of capturing CO 2 during compressed air energy storage, comprising:

compressing a gas in at least one compression stage;

removing at least a portion of heat from a compressed gas during or after the at least one compression stage;

separating CO 2 from the compressed gas using an absorption bed after the removal of heat through a heat transfer system linked to and located downstream from the at least one compression stage;

storing the compressed gas in a compressed gas reservoir after separating CO 2 from the compressed gas;

subsequently removing the stored gas from the compressed gas reservoir and then expanding the compressed gas while deriving work from the gas;

preheating the compressed gas prior to expansion by feeding the compressed gas through at least one heat exchanger; and

recycling at least a portion of the removed heat from the heat transfer system to preheat the compressed gas prior to expansion, and/or to heat the expanded gas after each stage of expansion with the removed heat, and/or to heat the absorption bed with the removed heat.

14. The method of capturing CO 2 during compressed air energy storage according to claim 13 , wherein the heat removed from the compressed gas is stored in a heat accumulator.

15. The method of capturing CO 2 during compressed air energy storage according to claim 13 , further comprising separating condensed water from the compressed gas after cooling the gas; wherein the condensed water is removed using a dryer.

16. The method of capturing CO 2 during compressed air energy storage according to claim 13 , wherein the CO 2 is separated using a pressure swing absorption bed, a temperature swing absorption bed, or a pressure and temperature swing absorption bed.

17. The method of capturing CO 2 during compressed air energy storage according to claim 13 , further comprising desorbing the CO 2 from the absorption bed, and storing or further processing the desorbed CO 2 .

18. The method of capturing CO 2 during compressed air energy storage according to claim 13 , wherein the compressed gas is expanded using a turbine.

19. The method of capturing CO 2 during compressed air energy storage of claim 13 , wherein the expanded gas is used to cool the absorption bed during CO 2 absorption and to extract heat from the compressed gas stream after compression.

Assignments (10)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 6, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073842/0479 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 064760/0389 Recorded Feb 13, 2024
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: XEROX CORPORATION
Reel/Frame 068261/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVAL OF US PATENTS 9356603, 10026651, 10626048 AND INCLUSION OF US PATENT 7167871 PREVIOUSLY RECORDED ON REEL 064038 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 28, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064161/0001 →
SECURITY INTEREST Recorded Jun 22, 2023
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 064760/0389 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064038/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 21, 2007
From: LITTAU, KARL A.; STUMPP, RAPHAEL
To: PALO ALTO RESEARCH CENTER INCORPORATED
Reel/Frame 020294/0283 →