Extended-baking process for glass deposition tubes
View Patent ↗Disclosed is a method of heat treating quartz glass deposition tubes at between 900° C. and 1200° C. for at least 115 hours. The resulting deposition tubes are useful in forming optical preforms that can yield optical fibers having reduced added loss.
1. An extended-baking method for improving the optical properties of a glass deposition tube, comprising the step of subjecting the glass deposition tube to heat-treatment at about 900° C. or higher for at least about 115 hours.
2. A method according to claim 1 , wherein the step of subjecting the glass deposition tube to heat-treatment comprises subjecting the glass deposition tube to heat-treatment of between about 1000° C. and 1100° C. for at least about 125 hours.
3. A method according to claim 1 , wherein the step of subjecting the glass deposition tube to heat-treatment comprises subjecting the glass deposition tube to heat-treatment of between about 900° C. and 1200° C. under reduced pressure of less than about 100 millitorr for at least about 200 hours.
4. A method according to claim 1 , wherein the step of subjecting the glass deposition tube to heat-treatment comprises subjecting the glass deposition tube to heat-treatment at about 900° C. or more for at least about 400 hours.
5. A method according to claim 1 , wherein the step of subjecting the glass deposition tube to heat-treatment comprises subjecting the glass deposition tube to heat-treatment under reduced pressure of between about 10 millitorr and 100 millitorr.
6. A method according to claim 1 , wherein the step of subjecting the glass deposition tube to heat-treatment comprises subjecting the glass deposition tube to heat-treatment under reduced pressure of less than about 50 millitorr.
7. A method according to claim 1 , wherein the step of subjecting the glass deposition tube to heat-treatment comprises subjecting the glass deposition tube to heat-treatment under reduced pressure of less than 10 millitorr.
8. A method according to claim 1 , wherein the step of subjecting the glass deposition tube to heat-treatment comprises subjecting the glass deposition tube to heat-treatment in an inert-gas environment.
9. A method according to claim 1 , wherein the step of subjecting the glass deposition tube to heat-treatment comprises subjecting the glass deposition tube to heat-treatment in an environment that is substantially free of hydrogen and/or hydrogen-bearing species.
10. A method according to claim 1 , wherein the glass deposition tube possesses less than 100 ppm halogen.
11. A method according to claim 1 , wherein the glass deposition tube possesses less than 100 ppb iron and less than 100 ppm aluminum.
12. A method according to claim 1 , further comprising:
depositing a glass inner cladding layer and a glass core layer, respectively, into the interior of the heat-treated glass deposition tube; and
collapsing the heat-treated glass deposition tube to yield an optical preform.
13. A method according to claim 12 , further comprising the step of drawing an optical fiber from the optical preform.
14. A method for making an improved optical preform having reduced inner-cladding-to-core ratio and low attenuation, the method comprising:
providing a quartz glass deposition tube;
baking the quartz glass deposition tube for at least about 125 hours at about 900° C. or higher at a reduced pressure of less than about 100 millitorr;
depositing a glass inner cladding layer onto the interior surface of the quartz glass deposition tube;
depositing a glass core layer onto the glass cladding layer; and
thereafter collapsing the quartz glass deposition tube to yield an optical preform;
wherein the steps of depositing an inner cladding layer and depositing a core layer together comprise depositing glass layers in amounts sufficient to yield an optical preform having an inner-cladding-to-core ratio (b/a) of less than about 3.0.
15. A method for making an improved optical preform according to claim 14 , wherein the step of providing a quartz glass deposition tube comprises forming a quartz glass deposition tube via an electric fusion process to yield a quartz glass deposition tube having halogen content of less than about 100 ppm.
16. A method for making an improved optical preform according to claim 15 , wherein the step of forming a quartz glass deposition tube via an electric fusion process yields a quartz glass deposition tube having halogen content of less than about 10 ppm.
17. A method for making an improved optical preform according to claim 16 , wherein the step of forming a quartz glass deposition tube via an electric fusion process yields a quartz glass deposition tube having halogen content of less than about 1 ppm.
18. A method for making an improved optical preform according to claim 16 , further comprising the step of drawing the optical preform into an optical fiber having an attenuation of less than 0.20 dB/km at a wavelength of 1550 nanometers.
19. A method for making an improved optical preform according to claim 14 , further comprising the step of drawing the optical preform into an optical fiber having an inner-cladding-to-core ratio (b/a) of less than about 2.4 and additional attenuation of less than about 0.02 dB/km at a wavelength of 1550 nanometers.