Chelated plant micronutrients
The present invention relates to chelated plant micronutrients of the sodium, potassium, sodium/ammonium or potassium/ammonium salts of N-(1,2-dicarboxyethyl)-D,L-aspartic acid and their mixtures with metal ions selected from the group of the inorganic or organic zinc, manganese, iron(II), iron(III) or copper(II) compounds, and to a process for the preparation of these chelated micronutrient fertilizers.
1 . Chelated plant micronutrients including the reaction product of sodium and/or potassium salts of N-(1,2-dicarboxyethyl)-D,L-aspartic acid, and/or combinations thereof, as compounds of formula (A)
wherein
X represents potassium, sodium or hydrogen and the degree of substitution of potassium and/or sodium is in the range of from 3.5 to 4, and the degree of substitution for hydrogen is in the range of from 0 to 0.5, and a compound (B) comprising an inorganic and/or organic zinc, manganese, iron(II), Iron(III) or copper(II) compound.
2 . The micronutrients according to claim 1 , wherein the sodium salt comprises the tetra sodium salt of N-(1,2-dicarboxyethyl) D,L-aspartic acid.
3 . The micronutrient according to claim 1 , wherein the molar ratio between Compound (A) and Compound (B) is in the range of from 1.3:0.8 to 1.0:0.9.
4 . The micronutrient according to claim 1 , wherein the reaction product is present in liquid form and comprises 1.0 to 6.0% by weight of metal ions.
5 . The micronutrient according to claim 1 , wherein the reaction product is present in solid form and contains 5.0 to 14.0% by weight of metal ions.
6 . The micronutrient according to claim 1 , further comprising additional micronutrients.
7 . The micronutrient according to claim 6 wherein the additional micronutrients include magnesium, boron, molybdenum, calcium and/or cobalt.
8 . The micronutrient according to claim 1 , further comprising at least one additional complexing agent from compounds including animopolycarboxyl compounds, polyaminocarboxyl compounds, hydroxypolyaminocarboxyl compounds and/or hydroxypolycarboxyl compounds.
9 . The micronutrient according to claim 1 , further comprising NPK fertilizer.
10 . The micronutrient according to claim 9 , wherein fertilizer includes nitrogen, phosphorus, potash, and/or mixtures thereof.
11 . The micronutrient according to claim 9 , further comprising conventional wetting agents and/or adhesives.
12 . A method for providing plants with micronutrients in chelated form comprising:
a. applying to a plant the reaction product according to claim 1 .
13 . The method of claim 12 wherein the application comprises foliar spray, soil application, hydrophonics and fertigation.