Process for enhanced total organic carbon removal while maintaining optimum membrane filter performance
View Patent ↗One embodiment of a method to system for enhancing TOC removal while maintaining membrane filter performance is the implementation of a dual pH control system. This embodiment will enhance the ability to maximize TOC removal while maintaining optimum membrane filter performance. By adjusting pH, dosing a chemical coagulant and incorporating liquid-solids separation, a considerably higher degree of TOC removal is possible. By adjusting pH again after liquid-solids separation this embodiment can drastically increase the efficiency of the membrane microfiltration/ultrafiltration system. Thus pH control for soluble organic removal is critical. This pH level however may not be the ideal set point for minimizing membrane fouling which is the basis for this embodiment. An example: the pH set point for optimum soluble organic removal is designated to be 5.5. However, the optimum pH set point for optimum membrane performance is 7.0. This embodiment will show the reader that a two stage approach can accomplish the desired result. Stage 1 involves coagulant dosing, pH control, mixing and liquid-solids separation followed by Stage two which involves pH control, mixing and membrane filtration.
1. A membrane filtration system, comprising:
a first treatment stage, comprising:
a first mixing tank for holding a volume of water;
a first pH probe for measuring a pH level of said water in said first mixing tank;
a mechanism for dispersing a coagulant into said water in said first mixing tank;
a first mechanical mixing device configured to rapidly agitate water in a first zone of said first mixing tank;
a second mechanical mixing device configured to slowly agitate water in a second zone of said first mixing tank; and
a liquid-solid separator device in fluid communication downstream of said first mixing tank for receiving water from said first mixing tank;
a second treatment stage, comprising:
a second mixing tank for holding water, said second mixing tank in fluid communication downstream of said liquid-solid separator device for receiving water that has passed through said liquid-solid separator device;
a second pH probe for measuring a pH level of said water in said second mixing tank;
a third mechanical mixing device configured to rapidly agitate water in a first zone of said second mixing tank;
a fourth mechanical mixing device configured to slowly agitate water in a second zone of said second mixing tank; and
a membrane filter in fluid communication downstream of said second mixing tank for receiving water from said second mixing tank; and
a dual pH control system comprising:
a first pH set point controller in communication with the first pH probe and configured to adjust the pH level of said water in said first mixing tank to a first pH set point selected for optimum TOC removal in response to a signal from said first pH probe prior to said water being directed through said liquid-solid separator device; and
a second pH set point controller in communication with the second pH probe and configured to adjust the pH level of said water in said second mixing tank to a second pH set point selected for optimum performance of said membrane filter in response to a signal from said second pH probe prior to said water being directed through said membrane filter.
2. The membrane filtration system of claim 1 , wherein said first pH set point controller comprises a first acid/base dosing system in fluid communication with the first mixing tank and said second pH set point controller comprises a second acid/base dosing system in fluid communication with the second mixing tank.
3. The membrane filtration system of claim 1 , wherein said first treatment stage further comprises a flow meter for determining a flow rate of water flowing into said first mixing tank, and wherein the mechanism for dispersing the coagulant is a chemical metering system that is configured to determine an amount of coagulant to dose based upon the flow rate of said water flowing into said first mixing tank.
4. The membrane filtration system of claim 1 , wherein said liquid-solid separator device is selected from the group consisting of a plate separator, a sedimentation tank, a solids-contact clarifier, an ion exchange unit and a dissolved air flotation unit.
5. The membrane filtration system of claim 1 , wherein said coagulant is a metal based coagulant selected from the group consisting of aluminum sulfate, ferric chloride, ferric sulfate, poly aluminum chloride and aluminum chlorhydrate.
6. The membrane filtration system of claim 1 , wherein the second pH set point is higher than the first pH set point.
7. The membrane filtration system of claim 6 , wherein the first pH set point is about 5.0 to about 6.0.
8. The membrane filtration system of claim 6 , wherein the first pH set point is about 5.5.
9. The membrane filtration system of claim 6 , wherein the second pH set point is neutral or about 7.0 or higher.
10. The membrane filtration system of claim 1 , wherein said second treatment stage comprises no mechanism for dispersing a coagulant into said second mixing tank.
11. The membrane filtration system of claim 1 , wherein the membrane system comprises microfiltration or ultrafiltration membranes made of polymeric or ceramic materials.
12. The membrane filtration system of claim 1 , further comprising an ion exchange operation upstream of the first treatment stage.
13. The membrane filtration system of claim 1 , further comprising a disinfection or a granular activated carbon adsorption operation downstream of the second treatment stage.
14. The membrane filtration system of claim 1 , wherein the coagulant is an aluminum or iron metal salt based coagulant.