IP Library Granted Patent US 8,119,570
Granted Patent B1
US 8,119,570 · App. 11/975,990 · Granted Feb 21, 2012

3-biphenyl-substituted-3-substituted-4-ketolactam and ketolactone and their utilization as pesticide

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Quick Facts
Patent No.
US 8,119,570
App. No.
11/975,990
Granted
Feb 21, 2012
Kind
B1
Abstract

The present invention relates to novel 3-biphenyl-substituted, 3-substituted 4-keto-lactams and -lactones of the formula (I) in which A, B, Q, G, W, X, Y and Z are as defined in the disclosure, to processes for their preparation, and to their use as pesticides and/or microbicides and/or herbicides.

Claims (55)

1. A compound of formula (I)

in which

Q represents the group N-D,

W represents hydrogen, halogen, C 1 -C 6 -alkyl, or C 1 -C 6 -alkoxy,

X represents halogen, C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -haloalkoxy, cyano, or optionally halogen-, C 1 -C 6 -alkyl-, C 1 -C 6 -alkoxy-, C 1 -C 4 -haloalkyl-, C 1 -C 4 -haloalkoxy-, nitro-, or cyano-substituted phenyl,

Y represents one of the radicals

in which

V 1 represents hydrogen, halogen, C 1 -C 12 -alkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -alkylthio, C 1 -C 6 -alkylsulphinyl, C 1 -C 6 -alkylsulphonyl, C 1 -C 4 -haloalkyl, C 1 -C 4 -haloalkoxy, nitro, cyano, or phenyl that is optionally mono- or disubstituted by halogen, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy, C 1 -C 4 -haloalkyl, C 1 -C 4 -haloalkoxy, nitro, or cyano,

V 2 and V 3 independently of one another represent hydrogen, halogen, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy, C 1 -C 4 -haloalkyl, or C 1 -C 4 -haloalkoxy,

Z represents hydrogen, halogen, C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -haloalkoxy, nitro, or cyano,

A, B, and the carbon atom to which they are attached represent saturated C 3 -C 10 -cycloalkyl in which one ring member is optionally replaced by oxygen and that is optionally mono- or disubstituted by C 1 -C 8 -alkyl, C 3 -C 10 -cycloalkyl, C 1 -C 6 -haloalkyl, C 1 -C 8 -alkoxy, C 1 -C 8 -alkylthio, halogen, or phenyl;

D represents hydrogen; represents optionally halogen-substituted C 1 -C 12 -alkyl, C 3 -C 8 -alkenyl, C 3 -C 8 -alkynyl, C 1 -C 10 -alkoxy-C 2 -C 8 -alkyl, poly-C 1 -C 8 -alkoxy-C 2 -C 8 -alkyl, or C 1 -C 10 -alkylthio-C 2 -C 8 -alkyl; and

G represents chlorine, bromine or nitro.

2. A compound of formula (I) according to claim 1 , in which

Q represents the group N-D,

W represents hydrogen, chlorine, bromine, or C 1 -C 4 -alkyl,

X represents fluorine, chlorine, bromine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkyl, C 1 -C 4 -haloalkoxy, or cyano,

Y represents the radical

in which

V 1 represents hydrogen, fluorine, chlorine, bromine, C 1 -C 6 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -haloalkyl, C 1 -C 2 -haloalkoxy, nitro, or cyano; or represents phenyl that is optionally mono- or disubstituted by fluorine, chlorine, bromine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -haloalkyl, C 1 -C 2 -haloalkoxy, nitro, or cyano, and

V 2 represents hydrogen, fluorine, chlorine, bromine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -haloalkyl, or C 1 -C 2 -haloalkoxy,

Z represents hydrogen, fluorine, chlorine, bromine, C 1 -C 4 -alkyl, C 1 -C 2 -haloalkyl, C 1 -C 4 -alkoxy, or C 1 -C 2 -haloalkoxy,

A, B, and the carbon atom to which they are attached represent saturated C 3 -C 8 -cycloalkyl in which one ring member is optionally replaced by oxygen and that is optionally mono- or disubstituted by C 1 -C 6 -alkyl, C 5 -C 6 -cycloalkyl, C 1 -C 3 -haloalkyl, C 1 -C 6 -alkoxy, fluorine, chlorine, or phenyl,

D represents hydrogen or C 1 -C 4 -alkyl, and

G represents chlorine, bromine, or nitro.

3. A compound of formula (I) according to claim 1 , in which

Q represents the group N-D,

W represents hydrogen, chlorine, methyl, or ethyl,

X represents chlorine, methyl, ethyl, n-propyl, isopropyl, methoxy, ethoxy, n-propoxy, isopropoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy, or cyano,

Y represents the radical

in which

V 1 represents hydrogen, fluorine, chlorine, bromine, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, methoxy, ethoxy, n-propoxy, isopropoxy, trifluoromethyl, trifluoromethoxy, nitro, or cyano, and

V 2 represents hydrogen, fluorine, chlorine, methyl, ethyl, n-propyl, isopropyl, methoxy, ethoxy, trifluoromethyl, or trifluoromethoxy,

Z represents hydrogen, fluorine, chlorine, methyl, ethyl, n-propyl, or methoxy,

A, B, and the carbon atom to which they are attached represent saturated C 3 -C 8 -cycloalkyl in which one ring member is optionally replaced by oxygen and that is optionally monosubstituted by methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, trifluoromethyl, methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, or isobutoxy,

D represents hydrogen, methyl, ethyl, n-propyl, or isopropyl, and

G represents chlorine or nitro.

4. A compound of formula (I) according to claim 1 , in which

Q represents the group N-D,

W represents hydrogen, chlorine, or methyl,

X represents chlorine, methyl, or ethyl,

Y represents the radical

in which

V 1 represents chlorine or methyl, and

V 2 represents hydrogen or chlorine,

Z represents hydrogen or methyl,

A,B, and the carbon atom to which they are attached represent saturated C 3 -C 8 -cycloalkyl in which one ring member is optionally replaced by oxygen and that is optionally monosubstituted by methyl or, for C 6 -cycloalkyl, also by ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, trifluoromethyl, methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, or isobutoxy,

D represents hydrogen, and

G represents chlorine or nitro.

5. A pesticide comprising one or more compounds of formula (I) according to claim 1 and one or more extenders and/or surfactants.

6. A herbicide comprising one or more compounds of formula (I) according to claim 1 and one or more extenders and/or surfactants.

7. A fungicide comprising one or more compounds of formula (I) according to claim 1 and one or more extenders and/or surfactants.

8. A method for controlling animal pests comprising allowing an effective amount of a compound of formula (I) according to claim 1 to act on animal pests and/or their habitat.

9. A method for controlling unwanted vegetation comprising allowing an effective amount of a compound of formula (I) according to claim 1 to act on unwanted vegetation and/or its habitat.

10. A method for controlling fungi comprising allowing an effective amount of a compound of formula (I) according to claim 1 to act on fungi and/or their habitat.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 10, 2018
From: BAYER CROPSCIENCE AG
To: BAYER INTELLECTUAL PROPERTY GMBH
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