Method and apparatus of manufacturing negative electrode for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery using the negative electrode
View Patent ↗A method of manufacturing a negative electrode for a non-aqueous electrolyte secondary battery includes a step of imparting lithium to a precursor of the negative electrode capable of storing and releasing lithium, by a film forming method in a dry process. In this step, the precursor is brought into contact with a measuring terminal having a non-aqueous electrolyte and a counter electrode. The amount of lithium stored in the precursor is calculated from an open circuit potential of the precursor with respect to the counter electrode. Further, according to the calculated amount of stored lithium, the amount of lithium to be imparted to the precursor is controlled.
1. A method of processing a precursor of a negative electrode for a non-aqueous electrolyte secondary battery, the method including imparting lithium to the precursor of the negative electrode capable of storing and releasing lithium, by a film forming method in a dry process, the imparting lithium comprising:
(A) bringing the precursor into contact with a measuring terminal having a non-aqueous electrolyte and a counter electrode;
(B) calculating an amount of lithium stored in the precursor from an open circuit potential of the precursor with respect to the counter electrode; and
(C) controlling an amount of lithium to be imparted to the precursor according to the calculated amount of stored lithium.
2. The processing method according to claim 1 , wherein the film forming method is vacuum deposition.
3. The processing method according to claim 1 , wherein the non-aqueous electrolyte is a solid electrolyte.
4. The processing method according to claim 1 , wherein the precursor includes a silicon-containing material as an active material thereof.
5. The processing method according to claim 4 , wherein the silicon-containing material is a silicon oxide expressed by SiO x (0.3≦x≦1.3).
6. Apparatus of processing a negative electrode for a non-aqueous electrolyte secondary battery, comprising:
a film forming part in a dry process configured to impart lithium to a precursor of the negative electrode capable of storing and releasing lithium;
a measuring terminal to be brought into contact with the precursor and having a non-aqueous electrolyte and a counter electrode; and
a controller configured to calculate an amount of lithium stored in the precursor from an open circuit potential of the precursor with respect to the counter electrode, and control the film forming part according to the calculated amount of stored lithium so as to control an amount of lithium to be imparted to the precursor.
7. A method of manufacturing a negative electrode for a non-aqueous electrolyte secondary battery, the method comprising:
(i) fabricating a precursor of the negative electrode including an active material capable of storing and releasing lithium; and
(ii) imparting lithium to the precursor by a film forming method in a dry process, the imparting lithium comprising:
(A) bringing the precursor into contact with a measuring tetininal having a non-aqueous electrolyte and a counter electrode;
(B) calculating an amount of lithium stored in the precursor from an open circuit potential of the precursor with respect to the counter electrode; and
(C) controlling an amount of lithium to be imparted to the precursor according to the calculated amount of stored lithium.
8. The manufacturing method according to claim 7 , wherein the film forming method is vacuum deposition.
9. The manufacturing method according to claim 7 , wherein the non-aqueous electrolyte is a solid electrolyte.
10. The manufacturing method according to claim 7 , wherein the precursor includes a silicon-containing material as the active material.
11. The manufacturing method according to claim 10 , wherein the silicon-containing material is a silicon oxide expressed by SiO x (0.3≦x≦1.3).
12. Apparatus of manufacturing a negative electrode for a non-aqueous electrolyte secondary battery, comprising:
an active material layer forming part configured to fabricate a precursor of the negative electrode capable of storing and releasing lithium;
a film forming part in a dry process configured to impart lithium to a precursor of the negative electrode capable of storing and releasing lithium;
a measuring terminal to be brought into contact with the precursor and having a non-aqueous electrolyte and a counter electrode; and
a controller configured to calculate an amount of lithium stored in the precursor from an open circuit potential of the precursor with respect to the counter electrode, and control the film forming part according to the calculated amount of stored lithium so as to control an amount of lithium to be imparted to the precursor.