IP Library Granted Patent US 7,728,076
Granted Patent B2
US 7,728,076 · App. 11/983,850 · Granted Jun 1, 2010

Coating compositions

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Quick Facts
Patent No.
US 7,728,076
App. No.
11/983,850
Granted
Jun 1, 2010
Kind
B2
Abstract

The present invention relates to novel coating compositions comprising polyisocyanates, aliphatic oligocarbonate polyols, oligoester polyols and polyacrylate polyols, to a process for their production and to their use in the production of coatings.

Claims (25)

1. A coating composition comprising

A) a polyol component consisting of

a) from 5 to 40 wt. % of one or more aliphatic oligocarbonate polyols having a number-average molecular weight M n of from 200 to 5,000 g/mol,

b) from 20 to 60 wt. % of one or more oligoester polyols having a number-average molecular weight of from 200 to 5,000 g/mol, and

c) from 20 to 70 wt. % of one or more hydroxy-functional polyacrylate polyols,

the amounts of a), b) and c) totaling 100 wt. %, and

B) one or more polyisocyanate crosslinkers that are reactive towards OH groups and have a mean NCO functionality of ≧2.0.

2. A coating composition according to claim 1 , wherein the amount of component a) is from 10 to 35 wt. %, the amount of component b) is from 25 to 55 wt. % and the amount of component c) is from 25 to 65 wt. %.

3. A coating composition according to claim 1 , wherein component a) comprises one or more aliphatic oligocarbonate diols having a molecular weight of from 200 to 2,000 g/mol that are based on components selected from the group consisting of 1,4-butanediol, 1,6-hexanediol, 3-methyl-1,5-pentanediol, cyclohexane-1,4-dimethanol, trimethylolpropane, glycerol and mixtures thereof.

4. A coating composition according to claim 1 , wherein component b) comprises one or more aliphatic oligoester polyols having a molecular weight of from 200 to 2,000 g/mol that are based on components selected from the group consisting of ε-caprolactone and 1,4-butanediol, 1,6-hexanediol, 3-methyl-1,5-pentanediol, cyclohexane-1,4-dimethanol, trimethylolpropane, glycerol, pentaerythritol and mixtures of those alcohols.

5. A coating composition according to claim 1 , wherein component c) comprises one or more copolymers of

c1) from 0.4 to 5 wt. % of one or more optionally functional polybutadienes having a number-average molecular weight of from 750 to 3500 g/mol and having a content of 1,2-lateral vinyl double bonds of at least 40 mol %, based on all vinyl double bonds present in the polybutadiene,

c2) from 5 to 20 wt. % styrene,

c3) from 30 to 60 wt. % hydroxyethyl acrylate, hydroxyethyl methacrylate or mixtures thereof,

c4) from 0 to 15 wt. % of one or more compounds from the group consisting of isobornyl acrylate, isobornyl methacrylate, cyclohexyl (meth)acrylate, 3,5,5-trimethylcyclohexyl (meth)acrylate and 4-tert.-butylcyclohexyl (meth)acrylate,

c5) from 25 to 45 wt. % of one or more esters of acrylic or methacrylic acid and aliphatic C 1 to C 4 monoalcohols,

c6) from 0.3 to 2 wt. % acrylic acid, methacrylic acid or mixtures thereof, and

c7) from 0 to 15 wt. % of one or more compounds from the group consisting of hydroxypropyl (meth)acrylate, vinyl esters of aliphatic, optionally branched Cr to Cg-monocarboxylic acids, dialkyl or di(cyclo)alkyl esters of maleic or fumaric acid and C 3 to C 6 monoalcohols;

the amounts of c1) to c7) totaling 100 wt. %.

6. A coating composition according to claim 5 , wherein the copolymers used in c) have a non-homogeneity (Mw/Mn)≦2.5.

7. A coating composition according to claim 5 , wherein polyol component A) is prepared by polymerization of the corresponding monomers of the copolymer c) in the presence of the aliphatic oligocarbonate polyols a) and/or of the aliphatic oligoester polyols b).

8. A coating composition according to claim 1 , wherein component B) comprises polyisocyanates or polyisocyanate mixtures having an isocyanurate structure based on HDI, IPDI and/or 4,4′-diisocyanato-dicyclohexylmethane.

9. A coating composition according to claim 1 , wherein the NCO/OH ratio of the free and optionally blocked NCO groups to the isocyanate-reactive groups is from 0.5 to 1.2.

10. A coating obtained using the coating composition according to claim 1 .

11. A substrate coated with a coating according to claim 10 .

Assignments (2)
CHANGE OF NAME Recorded Mar 30, 2016
From: BAYER MATERIALSCIENCE AG
To: COVESTRO DEUTSCHLAND AG
Reel/Frame 038399/0306 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 6, 2008
From: WAMPRECHT, CHRISTIAN; MECHTEL, MARKUS; KLIMMASCH, THOMAS
To: BAYER MATERIALSCIENCE AG
Reel/Frame 020611/0593 →