Two-part moisture-curable resin composition and adhesive, sealant and coating compositions based thereon
View Patent ↗This invention relates to moisture-curable resins generally and, more particularly, to two-part moisture-curable resin compositions the first part of which contains a moisture-curable silylated resin and the second part of which contains water. The invention further relates to adhesive, sealant and coating compositions based on such two-part moisture-curable resin compositions.
1. A two-part moisture-curable resin composition which comprises:
a) a first part substantially free of moisture comprising:
(1) moisture-curable silylated resin obtained by the silylation of at least one resin selected from the group consisting of polyether polyol (i), polyester polyol (ii), hydroxyl-terminated polybutadiene (iii), hydroxyl terminated or isocyanate-terminated polyurethane prepolymer (iv) derived from at least one of polyether polyol (i), polyester polyol (ii) or hydroxy-terminated polybutadiene (iii), amine-terminated or isocyanate-terminated polyurethane-polyurea prepolymer and/or polyurea prepolymer (v) derived from polyamine, and olefinically unsaturated resin (vi); and,
(2) optionally, one or more additional components selected from the group consisting of plasticizer, solvent, thixotropic agent, particulate material, moisture scavenger, isocyanate scavenger, crosslinker, adhesion promoter, U.V. stabilizer and antioxidant; and,
b) a second part comprising:
(1) water in an amount sufficient to cure moisture-curable silylated resin (a)(1);
(2) at least one plasticizer and/or particulate material,
(3) nonionic surfactant (b)(3) in an amount sufficient to provide a stable emulsion of plasticizer (b)(2), if present, and a stable suspension of particulate material (b)(2), if present, wherein non-ionic surfactant (b)(3) is selected from the group consisting of polyethylene glycol, polypropylene glycol, copolymer of ethylene oxide and propylene oxide, ethoxylated castor oil, oleic acid ethoxylate, alkylphenol ethoxylate, copolymer of silicone and polyether and mixtures of the foregoing; and
(4) optionally, one or more additional components selected from the group consisting of solvent, thixotropic agent, pH adjuster, U.V. stabilizer and antioxidant, provided, the first part and/or the second part further comprises catalyst (c) for the condensation reaction of hydrolyzed moisture-curable silylated resin (a)(1).
2. The two-part moisture-curable resin composition of claim 1 wherein moisture-curable silylated resin (a)(1) is obtained from at least one of polyether polyol (i), polyester polyol (ii), hydroxyl-terminated polybutadiene (iii), hydroxyl-terminated polyurethane prepolymer (iv) or amine-terminated polyurethane-polyurea prepolymer and/or amine-terminated polyurea prepolymer (v) by silylation with at least one isocyanatosilane, or from isocyanate-terminated polyurethane prepolymer (iv) or isocyanate-terminated polyurethane-polyurea prepolymer and/or isocyanate-terminated polyurea prepolymer (v) by silylation with at least one isocyanate-reactive silane selected from the group consisting of mercaptosilane, primary aminosilane, secondary aminosilane and mixtures thereof, or from olefinically unsaturated resin (vi) by hydrosilation with at least one hydridosilane.
3. The two-part moisture-curable resin composition of claim 2 formulated as an adhesive, sealant or coating.
4. The two-part moisture-curable resin composition of claim 1 wherein moisture-curable silylated resin (a)(1) is at least one silylated polyurethane prepolymer obtained from the silylation of hydroxyl-terminated or isocyanate-terminated polyurethane prepolymer (iv) derived from polyether dial (i) and diisocyanate.
5. The two-part moisture-curable resin composition of claim 4 wherein silylation of hydroxyl-terminated polyurethane prepolymer (iv) is carried out with at least one isocyanatosilane and silylation of isocyanate-terminated polyurethane prepolymer (iv) is carried out with at least one isocyanate-reactive silane selected from the group consisting of mercaptosilane, primary aminosilane, secondary aminosilane and mixtures thereof.
6. The two-part moisture-curable resin composition of claim 4 formulated as an adhesive, sealant or coating.
7. The two-part moisture-curable resin composition of claim 1 wherein first part (a) contains one or more additional components (a)(2).
8. The two-part moisture-curable resin composition of claim 7 wherein non-ionic surfactant (b)(3) is selected from the group consisting of polyethylene glycol, polypropylene glycol, copolymer of ethylene oxide and propylene oxide, ethoxylated castor oil, oleic acid ethoxylate, alkylphenol ethoxylate, copolymer of silicone and polyether and mixtures of the foregoing.
9. The two-part moisture-curable resin composition of claim 8 formulated as an adhesive, sealant or coating.
10. The two-part moisture-curable resin composition of claim 7 formulated as an adhesive, sealant or coating.
11. The two-part moisture-curable resin composition of claim 1 wherein second part (b) contains plasticizer (b)(2) and particulate material (b)(2), nonionic surfactant (b)(3) being present in second part (b) in an amount sufficient to provide a stable emulsion of plasticizer (b)(2) and a stable suspension of particulate material (b)(2).
12. The two-part moisture-curable resin composition of claim 11 wherein non-ionic surfactant (b)(3) is selected from the group consisting of polyethylene glycol, polypropylene glycol, copolymer of ethylene oxide and propylene oxide, ethoxylated castor oil, oleic acid ethoxylate, alkylphenol ethoxylate, copolymer of silicone and polyether and mixtures of the foregoing.
13. The two-part moisture-curable resin composition of claim 12 formulated as an adhesive, sealant or coating.
14. The two-part moisture-curable resin composition of claim 11 formulated as an adhesive, sealant or coating.
15. The two-part moisture-curable resin composition of claim 1 formulated as an adhesive, sealant or coating.