Polyamide housings for portable electronic devices
View Patent ↗Portable electronic device housings comprising polyamide compositions comprising fibrous reinforcing agents having non-circular cross sections.
1. A molded portable electronic device housing comprising a polyamide composition comprising a melt-mixed blend of (A) at least one thermoplastic polyamide and (B) at least one fibrous reinforcing agent having a non-circular cross section, wherein said at least one fibrous reinforcing agent comprises glass fiber; wherein said thermoplastic polyamide consist essentially of a polyamide selected from the group consisting of polyamide 10,10; polyamide 10,12; polyamide 10,13; polyamide 10,14; polyamide 12,10; polyamide 12,12; polyamide 12,13; and polyamide 12,14; said polyamide composition has a Notched Charpy impact strength of at least 12 kJ/m 2 , measured according to ISO 179 using test specimens prepared according to ISO 179-1/1eA; and said portable electronic device housing having a warpage of less than about 0.45, wherein the warpage is the absolute value of the percent shrinkage of said portable electronic device housing in a cross-flow direction minus the percent shrinkage in a flow direction upon molding.
2. The housing of claim 1 , wherein the thermoplastic polyamide (A) comprises about 25 to about 85 weight percent of the polyamide composition.
3. The housing of claim 1 , wherein the thermoplastic polyamide (A) comprises about 30 to about 75 weight percent of the polyamide composition.
4. The housing of claim 1 , wherein the fibrous reinforcing agent (B) comprises about 15 to about 75 weight percent of the polyamide composition.
5. The housing of claim 1 , wherein the fibrous reinforcing agent (B) comprises about 25 to about 70 weight percent of the polyamide composition.
6. The housing of claim 1 , wherein the fibrous reinforcing agent (B) has a cocoon-type cross-section.
7. The housing of claim 1 , wherein the fibrous reinforcing agent (B) has a rectangular cross-section.
8. The housing of claim 1 , wherein the fibrous reinforcing agent (B) has an elliptical cross-section.
9. The housing of claim 1 , wherein the polyamide composition further comprises up to about 20 weight percent of at least one impact modifier.
10. The housing of claim 9 , wherein the impact modifier is present in about 3 to about 20 weight percent, based on the total weight of the composition.
11. The housing of claim 9 wherein the impact modifier is an ethylene-propylene-diene polymer and/or a styrene-ethylene-butadiene-styrene polymer.
12. The housing of claim 11 , wherein the impact modifier has one or more carboxyl moieties attached thereto.
13. The housing of claim 9 , wherein the polyamide composition further comprises one or more additional reinforcing agents selected from the group consisting of fibrous reinforcing agents having a circular cross-section; flakey reinforcing agents; and particulate reinforcing agents.
14. The housing of claim 13 , wherein the additional reinforcing agents are selected from one or more of the group consisting of glass fibers, glass flakes, wollastonite, calcined clay, and kaolin.
15. The housing of claim 1 in the form of a mobile telephone housing.
16. The housing of claim 1 in the form of a laptop computer or tablet computer housing.
17. The housing of claim 1 in the form of a personal digital assistant housing.
18. he housing of claim 1 , in the form a radio, camera, watch calculator, music player, global positioning system receiver, portable game, or hard drive housing.