Propylene polymer composition
View Patent ↗A propylene polymer composition having a high impact strength and a high stiffness for the manufacture of parts having an excellent surface quality comprising A) 70 to 98 wt.-% of a heterophasic propylene copolymer with ethylene or an alpha-olefin with 4 to 12 carbon atoms, the propylene copolymer, which contains more than 60 wt.-% propylene, having a melt flow rate (MFR 2 ) of 0.5 to 50 g/10 min and a ratio between elastomer molecular weight and total molecular weight expressed as M w /M w (XCS) of more than 0.8, M w being the weight average molecular weight of the propylene copolymer and M w (XCS) being the weight average molecular weight of the propylene copolymer which is soluble in xylene at +23° C., and the propylene copolymer further containing a portion of 5 to 35 wt.-% soluble in xylene at +23° C. (XCS content), B) 2 to 30 wt.-% of a mineral filler, C) 0.0001 to 1.0 wt.-% of a β-nucleating agent promoting the β-modification of the propylene copolymer, said composition having a content of β-modification of more than 50% determined by differential scanning calorimetry (DSC) and an impact strength at −20° C. which is at least 50% higher than the impact strength of the propylene copolymer (A).
1. A propylene polymer composition comprising
A) 70 to 98 wt.-% of a heterophasic propylene copolymer with ethylene or an alpha-olefin with 4 to 12 carbon atoms, the propylene copolymer, which contains more than 60 wt.-% propylene, having a melt flow rate (MFR 2 ) of 0.5 to 50 g/10min and a ratio between elastomer molecular weight and total molecular weight expressed as M W /M W (XCS) of more than 0.8,
M W , being the weight average molecular weight of the propylene copolymer and M W (XCS) being the weight average molecular weight of the propylene copolymer which is soluble in xylene at +23° C., and
the propylene copolymer further containing a portion of 5 to 35 wt.-% soluble in xylene at +23° C. (XCS content),
B) 2 to 30 wt.-% of calcium carbonate,
C) 0.0001 to 1.0 wt.-% of a β-nucleating agent promoting the β-modification of the propylene copolymer,
said composition having a content of β-modification of more than 50% determined by differential scanning calorimetry (DSC) and an impact strength at −20° C. which is at least 50% higher than the impact strength of the propylene copolymer (A).
2. The propylene polymer composition according to claim 1 , wherein the heterophasic propylene copolymer (A) is a copolymer of propylene and ethylene containing less than 20 mol-% ethylene.
3. The propylene polymer composition according to claim 1 , wherein the melt flow rate (MFR 2 ) of the propylene copolymer (A) is less than 15 g/10 min.
4. The propylene polymer composition according to claim 1 , wherein the elastomer molecular weight and total molecular weight, M W /M W (XCS), ratio of propylene copolymer, is less than 5.
5. The propylene polymer composition according to claim 1 , wherein the propylene copolymer (A) having a propylene copolymer which is soluble in xylene (XCS) content of 25 wt.-% or less.
6. The propylene polymer composition according to claim 1 , wherein the mineral filler has an average particle size of 2 μm or less.
7. The propylene polymer composition according to claim 1 , wherein the mineral filler is coated with a β-nucleating agent.
8. The propylene polymer composition according to claim 1 , containing at least 0.001 wt.-% of the β-nucleating agent.
9. The propylene polymer composition according to claim 1 , wherein the β-nucleating agent is 5,12-dihydro-quino(2,3-b)acridine-7,14-dione with quino(2,3-b)acridine-6,7,13,14(5H, 12H)-tetrone, N,N′-dicyclohexyl-2,6-naphtalene dicarboxamide, a salt of dicarboxylic acids with at least 7 carbon atoms, or combination thereof.
10. A propylene polymer composition according to claim 9 , wherein the metal of the salt of the dicarboxylic acid is an earth alkaline metal.
11. The propylene polymer composition according to claim 9 , wherein the dicarboxylic acid is pimelate.
12. The propylene polymer composition according to claim 1 , having a content of β-modification of more than 80%.
13. The propylene polymer composition according to claim 1 having an impact strength at −20° C. which is at least 100% higher than the impact strength of the propylene copolymer (A).
14. The propylene polymer composition according to claim 1 having an impact strength at −20° C. of more than 4 kJ/m 2 .
15. The propylene polymer composition according to claim 1 , having a flexural modulus of at least 1000 MPa.
16. The propylene polymer composition according to claim 1 , wherein the sum of the percent increases of the impact strength at +23° C., the impact strength at −20° C. and the flexural modulus is at least 150% compared with propylene copolymer (A).
17. The propylene polymer composition according to claim 1 , further comprising one or more conventional additives and/or stabilizers.
18. Housings or other parts of household appliances or white goods comprising the propylene polymer composition according to claim 1 .