Stable aqueous dispersions of colour developer
View Patent ↗Storage-stable compositions comprising a color developer, an anionic dispersant and a thickening agent as well as heat-sensitive recording materials comprising such compositions, a process for its manufacture and its use.
1. A composition comprising a colour developer I:
, wherein
R 1 is phenyl or naphthyl, which can be unsubstituted or substituted by C 1 -C 8 alkyl, C 1 -C 8 -alkoxy or halogen; or C 1 -C 20 alkyl, which can be unsubstituted or substituted by C 1 -C 8 -alkoxy or halogen;
X is a group of the formula —C(═NH)—, —C(═S)— or —C(═O)—;
A is unsubstituted or substituted phenylene, naphthylene or C 1 -C 12 alkylene, or is an unsubstituted or substituted heterocyclic group;
B is a linking group of formula —O—SO 2 —, —SO 2 —O—, —NH—SO 2 —, —SO 2 —NH—, —S—SO 2 —, —O—CO—NH—, —NH—CO—, —NH—CO—O—, —S—CO—NH—, —S—CS—NH—, —CO—NH—SO 2 —, —O—CO—NH—SO 2 —, —NH═CH—, —CO—NH—CO—, —S—, —CO—, —O—, —SO 2 —NH—CO—, —O—CO—O— and —O—PO—(OR 2 ) 2 ; and
R 2 is aryl, which can be unsubstituted or substituted by C 1 -C 8 alkyl, halogen-substituted C 1 -C 8 alkoxy-substituted C 1 -C 8 alkoxy, halogen-substituted C 1 -C 8 alkoxy or halogen; or benzyl, which can be substituted by C 1 -C 8 alkyl, halogen-substituted C 1 -C 8 alkyl, C 1 -C 8 alkoxy-substituted C 1 -C 8 alkoxy, halogen-substituted C 1 -C 8 alkoxy or halogen;
or C 1 -C 20 alkyl, which can be unsubstituted or substituted by C 1 -C 8 alkoxy, halogen, phenyl or naphthyl; and
a) 0.1 to 5 dry parts by weight of an anionic dispersant per 100 dry parts of the colour developer I, wherein the anionic dispersant is an ammonium salt of naphthalene sulfonic acid formaldehyde condensate, a carboxylated polymer, a carboxylated acrylic copolymer, or a mixture thereof; and
b) 0.01 to 2.0 dry parts per weight of a thickening agent per 100 parts of the colour developer I.
2. The composition according to claim 1 , wherein
R 1 is phenyl, which is substituted by C 1 -C 4 alkyl;
X is a group of the formula —C(═O)—;
A is phenylene, which is unsubstituted or substituted by C 1 -C 4 alkyl or halogen;
B is a linking group of formula —O—SO 2 — or —O—; and
R 2 is phenyl, naphthyl or benzyl, which is unsubstituted or substituted by C 1 -C 4 alkyl or halogen.
3. The composition according to claim 1 , wherein the thickening agent is selected from the group consisting of xanthan gum, sodium alginate, water-soluble carboxylates, acrylamide polymers or copolymers, acrylic acid, ethyl acrylate, and methacrylic acid.
4. The composition according to claim 1 , further comprising a biocide.
5. The composition according to claim 1 comprising:
a) at least 50% by weight of the colour developer I;
b) the anionic dispersant, in an amount from 0.1 to 5 dry parts per a dry 100 parts of the colour developer I;
c) the thickening agent, in an amount from 0.01 to 2.0 dry parts per a dry 100 parts of the colour developer I;
d) optionally a biocide; and
e) water, which adds up to 100%.
6. A heat-sensitive recording material comprising:
a) a colour forming compound, and
b) the composition according claim 1 .
7. A process for the manufacturing of the composition according claim 1 , comprising:
a) mixing the colour developer I, the anionic dispersant, and water, optionally with a biocide to obtain a mixture;
b) milling the mixture to obtain a treated mixture having an average particle size in the range of from 0.2 to 2.0 μm; and
c) blending the treated mixture of step b) with the thickening agent.
8. Paper, wherein the composition according to claim 1 is coated onto the paper.