Carbon-fiber-reinforced SiC composite material and slide member
View Patent ↗A carbon-fiber-reinforced SiC composite having a high tensile strength is produced by impregnating a carbon-fiber-reinforced carbon composite with melted metal Si. The carbon-fiber-reinforced carbon composite includes carbon fibers that are pitch-based short carbon fibers. The pitch-based short carbon fibers are oriented in two-dimensional random directions. The carbon-fiber-reinforced carbon composite has a bulk density of 1.2 to 1.7 g/cm 3 , a porosity of 15 to 40 vol %, and a carbon fiber volume content of 20 to 50 vol %.
1. A carbon-fiber-reinforced SiC composite produced by impregnating a carbon-fiber-reinforced carbon composite with melted metal Si,
wherein the carbon-fiber-reinforced carbon composite includes pitch-based short carbon fibers prepared from a pitch-based carbon fiber oriented in two-dimensional random directions in the carbon-fiber-reinforced SiC composite, and
wherein the carbon-fiber-reinforced carbon composite includes a stack of sheets in which the pitch-based short carbon fibers are oriented in two-dimensional random directions.
2. The carbon-fiber-reinforced SiC composite according claim 1 , wherein the pitch-based short carbon fibers have a length of 10 to 50 mm.
3. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein each sheet contains the pitch-based short carbon fibers oriented in two-dimensional random directions by at least one of fiberizing and dispersing short fiber bundles.
4. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the sheet has a fiber areal weight of 10 to 500 g/m 2 .
5. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the stack is a preform prepared by stacking a plurality of the sheets impregnated with at least one of a resin and a pitch, subsequently performing pressure-forming on the stacked sheets, and then firing the pressure-formed sheets in an inert gas atmosphere.
6. The carbon-fiber-reinforced SiC composite according to claim 5 , wherein the carbon-fiber-reinforced carbon composite is prepared by performing at least one cycle of an impregnation carbonization process in which the preform is impregnated with at least one impregnant selected from the group consisting of resins, tars, and pitches and is then heated in an inert gas atmosphere to carbonize the impregnant.
7. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the carbon-fiber-reinforced carbon composite has a bulk density of 1.2 to 1.7 g/cm 3 before impregnation with melted metal Si.
8. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the carbon-fiber-reinforced carbon composite has a porosity of 15 to 40 vol% before impregnation with melted metal Si.
9. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the carbon-fiber-reinforced carbon composite has a carbon fiber volume content of 20 to 50 vol% before impregnation with melted metal Si.
10. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the carbon-fiber-reinforced carbon composite includes a matrix containing pitch-derived carbon before impregnation with melted metal Si.
11. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the carbon-fiber-reinforced SiC composite include a matrix containing carbon, silicon carbide, and silicon.
12. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the carbon-fiber-reinforced SiC composite has a tensile strength of 50 MPa or more.
13. A sliding member comprising the carbon-fiber-reinforced SiC composite as set forth in claim 1 .
14. The carbon-fiber-reinforced SiC composite according to claim 1 , further comprising at least one carbonized impregnant selected from the group consisting of a resin, a tar and a pitch.
15. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the Si metal is not reacted with the carbon of the pitch-based short carbon fibers.
16. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the pitch-based short carbon fibers are at least one of infusible, carbonized and graphitized.
17. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the pitch-based short carbon fibers are in the form of fiber bundles comprising 2,000 to 12,000 filaments and having a length of 20-40 mm.
18. The carbon-fiber-reinforced SiC composite according to claim 1 , wherein the pitch-based short carbon fibers are tangled with each other.
19. A carbon-fiber-reinforced SiC composite produced by impregnating a carbon-fiber-reinforced carbon composite with melted metal Si,
wherein the carbon-fiber-reinforced carbon composite includes pitch-based short carbon fibers prepared from a pitch-based carbon fiber oriented in two-dimensional random directions in the carbon-fiber-reinforced SiC composite, and
wherein the carbon-fiber-reinforced SiC composite has a tensile strength of 28.2-79.9 MPa.
20. The carbon-fiber-reinforced SiC composite according to claim 19 , wherein the carbon-fiber-reinforced carbon composite has a bulk density of 1.21-1.58 g/cm 3 .
21. The carbon-fiber-reinforced SiC composite according to claim 20 , wherein the carbon-fiber-reinforced carbon composite has a porosity of 17.1-38.0 vol%.
22. The carbon-fiber-reinforced SiC composite according to claim 21 , wherein the carbon-fiber-reinforced carbon composite has a porosity of 17.1-38.0 vol%.
23. The carbon-fiber-reinforced SiC composite according to claim 19 , wherein the carbon-fiber-reinforced carbon composite includes a stack of sheets in which the pitch-based short carbon fibers are oriented in two-dimensional random directions.