Multi-layer microporous polyolefin membrane and battery separator
View Patent ↗A multi-layer, microporous polyolefin membrane having at least three layers, which comprises first microporous layers made of a polyethylene resin for constituting at least both surface layers, and at least one second microporous layer comprising a polyethylene resin and polypropylene and disposed between both surface layers, the heat of fusion (ΔH m ) of the polypropylene measured by differential scanning calorimetry being 90 J/g or more, and the polypropylene content in the second microporous layer being 50% or less by mass based on 100% by mass of the total of the polyethylene resin and the polypropylene.
1. A multi-layer, microporous polyolefin membrane having at least three layers, which comprises first microporous layers comprising a polyethylene resin for constituting at least both surface layers, and at least one second microporous layer comprising a polyethylene resin and polypropylene and disposed between both surface layers, the polyethylene resin in the first and second microporous layers having a melting point of 130° C. to 140° C., the heat of fusion (ΔH m ) of the polypropylene measured by differential scanning calorimetry being 90 J/g or more, and the polypropylene content in the second microporous layer being 3 to 45% by mass based on 100% by mass of the total of the polyethylene resin and the polypropylene.
2. A battery separator formed by a multi-layer, microporous polyolefin membrane having at least three layers, the multi-layer, microporous polyolefin membrane comprising first microporous layers comprising of a polyethylene resin for constituting at least both surface layers, and at least one second microporous layer comprising a polyethylene resin and polypropylene and disposed between both surface layers, the polyethylene resin in the first and second microporous layers having a melting point of 130° C. to 140° C., the heat of fusion (ΔH m ) of the polypropylene measured by differential scanning calorimetry being 90 J/g or more, the polypropylene content in the second microporous layer being 3 to 45% by mass based on 100% by mass of the total of the polyethylene resin and the polypropylene.
3. The multi-layer, microporous polyolefin membrane according to claim 1 , wherein said polyethylene resin is a composition of ultra-high-molecular-weight polyethylene having a mass-average molecular weight of 5×10 5 or more and high-density polyethylene having a mass-average molecular weight of 1×10 4 or more and less than 5×10 5 .
4. The battery separator according to claim 2 , wherein said polyethylene resin is a composition of ultra-high-molecular-weight polyethylene having a mass-average molecular weight of 5×10 5 or more and high-density polyethylene having a mass-average molecular weight of 1×10 4 or more and less than 5×10 5 .