Negative active material composition for a rechargeable lithium battery, a negative electrode for a rechargeable lithium battery, and a rechargeable lithium battery including same
Negative active material compositions for rechargeable lithium batteries, negative electrodes for rechargeable lithium batteries, and rechargeable lithium batteries using the negative active material compositions are provided. The negative active material composition includes a negative active material, a polyimide precursor compound, and a highly flexible polymer. The negative active material composition prevents the electrode substrate from bending, thereby improving the capacity and cycle-life characteristics of the battery.
1. A negative active material composition for a rechargeable lithium battery, comprising:
a negative active material selected from the group consisting of Si, SiO, and SiO x , wherein 0<x<2;
4.95 to about 15 wt % of a polyamic acid; and
about 0.05 to about 3 wt % of a flexible polymer, wherein the flexible polymer is selected from the group consisting of polypropylene carbonate, polyethylene oxide, polypropylene oxide, polyvinylacetate, polyvinylidenefluoride, a polyvinylidene fluoride hexafluoropropylene copolymer, and combinations thereof.
2. The negative active material composition of claim 1 , wherein the flexible polymer has a glass transition temperature of less than about 50° C.
3. The negative active material composition of claim 1 , wherein the flexible polymer has a weight average molecular weight ranging from about 10,000 to about 1,000,000.
4. A negative electrode comprising:
a current collector; and
a negative active material layer on the current collector, the negative active material layer comprising a negative active material selected from the group consisting of Si, SiO, and SiO x , wherein 0<x<2, 4.95 to about 15 wt % of a polyamic acid, and about 0.05 to about 3 wt % of a flexible polymer, wherein the flexible polymer is selected from the group consisting of polypropylene carbonate, polyethylene oxide, polypropylene oxide, polyvinylacetate, polyvinylidenefluoride, a polyvinylidene fluoride hexafluoropropylene copolymer, and combinations thereof, the negative active material layer being loaded at 3.9 mg/cm 2 to 4.2 mg/cm 2 .
5. The negative electrode of claim 4 , wherein the flexible polymer has a glass transition temperature of less than about 50° C.
6. The negative electrode of claim 4 , wherein the flexible polymer has a weight average molecular weight ranging from about 10,000 to about 1,000,000.
7. A rechargeable lithium battery comprising:
a negative electrode comprising a negative active material layer on a current collector, the negative active material layer comprising a negative active material selected from the group consisting of Si, SiO, and SiO x , wherein 0<x<2, 4.95 to about 15 wt % of a polyamic acid; and about 0.05 to about 3 wt % of a flexible polymer, wherein the flexible polymer is selected from the group consisting of polypropylene carbonate, polyethylene oxide, polypropylene oxide, polyvinylacetate, polyvinylidenefluoride, a polyvinylidene fluoride hexafluoropropylene copolymer, and combinations thereof, the negative active material layer being loaded at 3.9 mg/cm 2 to 4.2 mg/cm 2 ; and
a positive electrode comprising a positive active material capable of reversibly intercalating and deintercalating lithium ions.
8. The rechargeable lithium battery of claim 7 , wherein the flexible polymer has a glass transition temperature of less than about 50° C.
9. The rechargeable lithium battery of claim 7 , wherein the flexible polymer has a weight average molecular weight ranging from about 10,000 to 1,000,000.