Method of making glass including surface treatment with aluminum chloride using combustion deposition prior to deposition of antireflective coating
View Patent ↗This invention relates to a method of making glass. In certain example embodiments, a major surface(s) of the glass is treated with aluminum chloride (e.g., AlCl 3 ). This treating, or application of an aluminum chloride based layer on the glass substrate, may be performed using combustion deposition. The combustion deposition may be performed at or just prior to the annealing lehr in certain example embodiments, or at any other suitable location. The aluminum chloride barrier layer, applied at a desirable glass temperature, helps to reduce sodium leaching or diffusion from the glass during conditions such as high heat and/or humidity, thereby improving the durability and/or stability of the resulting product.
1. A method of making a coated article, the method comprising:
providing soda-lime-silica based glass comprising a base glass portion that includes:
Ingredient
wt. %
SiO 2
67-75%
Na 2 O
10-20%
CaO
5-15%
Al 2 O 3
0-7%
K 2 O
0-7%
using combustion deposition and at least one burner to deposit a barrier layer comprising aluminum chloride on a surface of the glass when the surface of the glass is at a temperature of at least about 400 degrees C., thereby forming the barrier layer comprising aluminum chloride on the glass;
forming an antireflective (AR) coating on the glass over at least the barrier layer comprising aluminum chloride.
2. The method of claim 1 , wherein the barrier layer comprising aluminum chloride is deposited on the glass, at or just prior to an annealing lehr of a float glass manufacturing apparatus, when the surface of the glass is at a temperature(s) of from about 540 degrees C. to 850 degrees C.
3. The method of claim 1 , further comprising, after forming the barrier layer comprising aluminum chloride on the glass, polishing down an opposite major surface of the glass opposite to a major surface to which the barrier layer was applied, in order to reduce a thickness of the coated glass.
4. The method of claim 1 , wherein the AR coating comprises silica and has a refractive index (n) of no more than about 1.6.
5. The method of claim 1 , wherein the AR coating is applied to the glass via a sol gel technique.
6. The method of claim 1 , wherein a mixture comprising AlCl 3 and at least one solvent comprising alcohol is provided to the burner in depositing the barrier layer comprising aluminum chloride on the surface of the glass.
7. The method of claim 6 , wherein the solvent comprises methanol.
8. The method of claim 6 , the mixture comprising AlCl 3 and the solvent is characterized by a AlCl 3 /solvent weight ratio of from about 1:8 to 1:40.
9. The method of claim 6 , the mixture comprising AlCl 3 and the solvent is characterized by a AlCl 3 /solvent weight ratio of from about 1:10 to 1:20.
10. A method of making a coated article, the method comprising:
providing a glass substrate;
using flame deposition and at least one burner to deposit a barrier layer comprising aluminum chloride on the glass substrate when at least part of the glass substrate is at a temperature of at least about 400 degrees C., thereby forming the barrier layer comprising aluminum chloride on, directly or indirectly, the glass substrate;
forming an antireflective (AR) coating, including one or multiple layers, on the glass substrate over at least the barrier layer comprising aluminum chloride.
11. The method of claim 10 , wherein the barrier layer comprising aluminum chloride is deposited on the glass, at or just prior to an annealing lehr of a float glass manufacturing apparatus, when the surface of the glass is at a temperature(s) of from about 540 degrees C. to 850 degrees C.
12. The method of claim 10 , further comprising, after forming the barrier layer comprising aluminum chloride on the glass, polishing down an opposite major surface of the glass opposite to a major surface to which the barrier layer was applied, in order to reduce a thickness of the coated glass.
13. The method of claim 10 , wherein the AR coating comprises silica and has a refractive index (n) of no more than about 1.6.
14. The method of claim 10 , wherein the AR coating is applied to the glass via a sol gel technique.
15. The method of claim 10 , wherein a mixture comprising AlCl 3 and at least one solvent comprising alcohol is provided to the burner in depositing the barrier layer comprising aluminum chloride on the surface of the glass.
16. The method of claim 15 , wherein the solvent comprises methanol.
17. The method of claim 15 , the mixture comprising AlCl 3 and the solvent is characterized by a AlCl 3 /solvent weight ratio of from about 1:8 to 1:40.
18. The method of claim 15 , the mixture comprising AlCl 3 and the solvent is characterized by a AlCl 3 /solvent weight ratio of from about 1:10 to 1:20.