Low temperature cure silicone release coatings containing branched silylhydrides

1 . A polyhydridosiloxane composition having the formula:

Q u T v D w D H x M H y M z   (1)

wherein:

each occurrence of Q is independently given by SiO 4/2 ;

each occurrence of T is independently given by R 1 SiO 3 /2 wherein each occurrence of R 1 is independently a monovalent hydrocarbon having 1 to 30 carbons;

each occurrence of D is independently given by R 2 R 3 SiO 2/2 wherein each occurrence of R 2 and R 3 is independently a monovalent hydrocarbon having 1 to 30 carbons;

each occurrence of D H is independently given by HR 4 SiO 2/2 wherein each occurrence of R 4 is independently a monovalent hydrocarbon having 1 to 30 carbons;

each occurrence of M is independently selected from the group consisting of R 5 R 6 R 7 SiO 1/2 , R 5 O 1/2 and HO 1/2 wherein each occurrence of R 5 , R 6 and R 7 is independently a monovalent hydrocarbon having 1 to 30 carbons; and

each occurrence of M H is independently given by HR 8 R 9 SiO 1/2 wherein each occurrence of R 8 and R 9 is independently a monovalent hydrocarbon having 1 to 30 carbons;

each occurrence of the subscripts u, v, w, x, y and z is independently an integer wherein u is from 0 to 10, v is from 0 to 10, w is from 0 to 100, x is from 1 to 100, y is from 1 to 10, and z is from 0 to 10 such that u+v equals 1 to 10, x+y equals 3 to 100, and y+z equals 3 to 10.

2 . The polyhydridosiloxane of claim 1 , wherein each R 1 , R 2 , R 3 , R 4 , R 5 , R 6, R 7 , R 8 and R 9 is a monovalent hydrocarbons of 1 to 20 carbon atoms; u is 0; v is from 1 to 5; w is from 0 to 50; x is from 1 to 50; y is from 3 to 8; and z is from 0 to 5.

3 . The polyhydridosiloxane of claim 1 wherein each R 1 , R 2 , R 3 , R 4 , R 5 , R 6, R 7 , R 8 and R 9 is a monovalent hydrocarbons of 1 to 20 carbon atoms; u is from 1 to 5; v is 0; w is from 0 to 50; x is from 1 to 50; y is from 4 to 9; and z is from 0 to 5.

4 . A crosslinkable silicone release coating composition comprising:

a) at least one polyhydridosiloxane having the formula:

Q u T v D w D H x M H y M z

wherein:

each occurrence of Q is independently given by SiO 4/2 ;

each occurrence of T is independently given by R 1 SiO 3 /2 wherein each occurrence of R 1 is independently a monovalent hydrocarbon having 1 to 30 carbons;

each occurrence of D is independently given by R 2 R 3 SiO 2/2 wherein each occurrence of R 2 and R 3 is independently a monovalent hydrocarbon having 1 to 30 carbons;

each occurrence of D H is independently given by HR 4 SiO 2/2 wherein each occurrence of R 4 is independently a monovalent hydrocarbon having 1 to 30 carbons;

each occurrence of M is independently selected from the group consisting of R 5 R 6 R 7 SiO 1/2 , R 5 O 1/2 and HO 1/2 wherein each occurrence of R 5 , R 6 and R 7 is independently a monovalent hydrocarbon having 1 to 30 carbons; and

each occurrence of M H is independently given by HR 8 R 9 SiO 1/2 wherein each occurrence of R 8 and R 9 is independently a monovalent hydrocarbon having 1 to 30 carbons;

each occurrence of the subscripts u, v, w, x, y and z is independently an integer wherein u is from 0 to 10, v is from 0 to 10, w is from 0 to 100, x is from 1 to 100, y is from 1 to 10, and z is from 0 to 10 such that u+v equals 1 to 10, x+y equals 3 to 100, and y+z equals 3 to 10;

b) at least one organosilicon compound containing at least two aliphatic carbon-carbon multiple bonds; and, c) a hydrosilylation catalyst which promotes the addition of Si-bonded hydrogen (Si—H) onto the aliphatic carbon-carbon multiple bond;

wherein hydrosilylation polymerization between the polyhydridosiloxane and the organosilicon compound occurs below the melt temperature of a heat-sensitive support.

5 . The silicone release coating composition of claim 4 wherein the organosilicon compound is a silicone polymer exhibiting, per molecule, at least two alkenyl groups bonded to silicon atoms.

6 . The silicone release coating composition of claim 4 wherein the organosilicon compound can exhibit a linear, branched or cyclic structure and its degree of polymerization is between 2 and 5000.

7 . The silicone release coating composition of claim 4 wherein the organosilicon compound is a organopolysiloxane having the formula:

X a R 10 3-a SiO(X b R 10 2-b SiO) m (R 10 2 SiO) n SiR 10 3-c X c

wherein:

each occurrence of R 10 is independently selected from the group consisting of a monovalent hydrocarbyl radical of from 1 to 20 carbon atoms and a monovalent heterocarbyl radical containing at least one halogen atom;

each occurrence of X is independently a monovalent hydrocarbyl radical of from 2 to 12 carbon atoms containing at least one carbon-carbon multiple bond;

each occurrence of the subscripts a, b, c, m and n is independently an integer wherein a is from 0 to 3; b is from 0 to 2; c is from 0 to 3, m is from 0 to 100, n is from 0 to 5000 with the proviso that a+mb+c equals to or greater than 2.

8 . The silicone release coating composition of claim 4 wherein the organosilicon is at least one selected from the group consisting of

(CH 3 ) 3 SiO[SiO(CH 3 ) 2 SiO] 100 [Si(CH 3 )(CH═CH 2 )O] 6 Si(CH 3 ) 3 ,

(CH 3 ) 3 SiO[SiO(CH 3 ) 2 SiO] 200 [Si(CH 3 )((CH 2 ) 4 CH═CH 2 ))O] 10 Si(CH 3 ) 3 ,

(CH 2 ═CH(CH 2 ) 4 )(CH 3 ) 2 SiO[(CH 3 ) 2 SiO] 80 Si(CH 3 ) 2 ((CH 2 ) 4 CH═CH 2 ),

(CH 2 ═CH)(CH 3 ) 2 SiO[(CH 3 ) 2 SiO] 150 Si(CH 3 ) 2 (CH═CH 2 ), and

(CH 2 ═CH)(CH 3 ) 2 SiO[Si(CH 3 ) 2 O] 100 [Si(CH 3 )(CH═CH 2 )O] 2 Si(CH 3 ) 2 (CH═CH 2 ).

9 . The compound resulting from the crosslinking of the silicone release coating composition of claim 4 .

10 . The silicone release coating composition of claim 4 applied to a surface of a polymeric substrate having a Tg of not greater than about 120° C.

11 . The polymeric substrate of claim 10 wherein the silicone release coating composition is crosslinked.

12 . The silicone release coating composition of claim 4 wherein the support to be coated is at least one made from the material selected from the group consisting of polyethylene (PE), polypropylene (PP), polypropylene coated Kraft paper (PPK), polyethylene coated Kraft paper (PEK) and multilayer laminate film made with temperature sensitive components.

13 . The silicone release coating composition of claim 4 wherein, for the crosslinking of the coating, the support is placed at a temperature of less than or equal to 120° C.

14 . The silicone release coating composition of claim 4 wherein the polyhydridosiloxane is present in the release coating composition in an amount that ranges form 0.5 to 20 weight percent of the total silicone release coating composition.

15 . The silicone release coating composition of claim 4 wherein the polyhydridosiloxane is present in the release coating composition in an amount that ranges form 3 to 10 weight percent of the total silicone release coating composition

16 . The silicone release coating composition of claim 4 wherein the organosilicon compound is present in an amount that ranges from 80 to 99 weight percent of the total silicone release coating composition.

17 . The silicone release coating composition of claim 4 wherein the organosilicon compound is present in an amount that ranges from 90 to 98 weight percent of the total silicone release coating composition.

18 . The silicone release coating composition of claim 4 wherein the polyhydridosiloxane exhibits an SiH to Si Vi molar ratio 0.8 to 10.

19 . The silicone release coating composition of claim 4 wherein the polyhydridosiloxane exhibits an SiH to Si Vi molar ratio 1.2 to 8.0.

20 . The silicone release coating composition of claim 4 wherein the catalyst is at least one selected from the group consisting of platinum, palladium, iridium, rhodium and ruthenium.

21 . The silicone release coating composition of claim 4 wherein the catalyst is present in an amount that ranges from 0.1 to 500 ppm.

22 . The silicone release coating composition of claim 4 further comprising at least one additional compound selected from the group consisting of adhesion-adjusting compounds; control release agents; anchorage to substrate compounds; buffering agents; surfactants; agent(s) for inhibiting hydrosilylation; bactericides; anti gelling agents; wetting agents; anti foaming agents; fillers; synthetic latexes; colorants; acidifying, rheology modifying and anchorage additive agents.

23 . A support that comprises the release coating obtained from the silicone release coating composition of claim 4 .

24 . The support of claim 23 wherein said support is selected from the group consisting of polyethylene (PE), polypropylene (PP), polypropylene coated Kraft paper (PPK), polyethylene coated Kraft paper (PEK) and multilayer laminate film made with temperature sensitive components.

25 . The silicone release coating composition claim 4 wherein the composition is solvent-free.